Synthesis and optimization of high-performance amine-based polymer for CO2 separation

Membrane technology features inspiring excellence from numerous separation technologies for CO₂ capture from post-combustion gas. Polyvinylamine (PVAm)-based facilitated transport membranes show significantly high separation performance, which has been proven promising for industrial scale-up. However, commercialized PVAm with low molecular weight and excessive crystallinity is not available to prepare high-performance membranes. Herein, the synthesis process of PVAm was optimized by regulating polymerization and acidic hydrolytic conditions. The membranes based on PVAm with a molecular weight of 154 kDa and crystallinity of 11.37% display high CO₂ permeance of 726 GPU and CO₂/N₂ selectivity of 55 at a feed gas pressure of 0.50 MPa. Furthermore, we established a PVAm synthesis reactor with an annual PVAm solution (1%(mass)) capacity of over 7000 kg and realized the scaled-up manufacture of both PVAm and composite membranes.     

蛋白粉和奶粉的鉴伪技术研究进展

蛋白粉和奶粉是孕妇和婴儿特别关注的一类食品,但其中的掺假现象十分严重,而且掺假方式多种多样,这严重威胁到消费者的人身健康。本文对其中非蛋白成分(三聚氰胺等)、异源蛋白(大豆蛋白等)、乳源性蛋白(乳清粉等)和非乳脂肪等掺假物质的检测方法进行重点总结,并对各种鉴伪方法的优劣进行对比。      

高效液相色谱法测定玉米浆干粉中维生素B6的含量

建立了高效液相色谱法测定玉米浆干粉中维生素B6含量的方法。色谱条件为Symmetry-C18柱（3.9mm×150mm,5μm）;流动相:A相为甲醇,B相为含0.05g/L EDTA和1.1g/L庚烷磺酸钠的2.5%乙酸溶液（pH3.40）,以A∶B为1∶6比例等度洗脱;流速为0.8mL/min;柱温为30℃;检测波长为280nm;样品分析时间为10min。结果表明,维生素B6的线性范围为0.10¹00.00μg/mL（r=0.9999）,日间和日内精密度均小于15%,低、中、高三种浓度下玉米浆干粉样品中维生素B6的提取回收率分别平均为93.66%±1.38%、95.60%±2.77%、93.52%±2.46%（n=4）。此法操作简便、快速、准确,可作为玉米浆干粉中维生素B6含量的检测方法。      

水分活度对全脂羊奶粉贮藏期间脂肪稳定性的影响

采用加速氧化的方法研究水分活度对全脂羊奶粉贮藏期间脂肪稳定性的影响。通过测定全脂羊奶粉的酸值、过氧化值、硫代巴比妥酸值(TBA)、颜色等指标评价全脂羊奶粉贮藏期间的氧化状况。结果表明,水分活度为0.32的全脂羊奶粉贮藏期间酸值、TBA值显著高于水分活度为0.11和0.23的全脂羊奶粉(p<0.05),且水分活度为0.32的全脂羊奶粉过氧化值变化速率较快(p<0.05),且褐变严重。因此,降低全脂羊奶粉的水分活度可以提高其贮藏稳定性。      

微胶囊化大豆粉末油脂包埋技术的研究

通过对单一包埋剂和复合包埋剂分别对大豆粉末油脂包埋效果的研究,优选出包埋效果好的包埋剂并通过包埋剂的复配提高了包埋效果,最后通过正交实验确定大豆粉末油脂的最优配方为:大豆一级油50%,酪蛋白酸钠2.5%,变性淀粉2.5%,乳化剂2.0%(单甘酯0.6%、糖酯1.4%)、麦芽糊精42.5%,加水配制物料浓度为40%,在该配方和工艺条件生产的大豆粉末油脂包埋率达到92%。      

Aminopeptidase N Inhibitors as Pointers for Overcoming Antitumor Treatment Resistance

Aminopeptidase N (APN), also known as CD13 antigen or membrane alanyl aminopeptidase, belongs to the M1 family of the MA clan of zinc metallopeptidases. In cancer cells, the inhibition of aminopeptidases including APN causes the phenomenon termed the amino acid deprivation response (AADR), a stress response characterized by the upregulation of amino acid transporters and synthetic enzymes and activation of stress-related pathways such as nuclear factor kB (NFkB) and other pro-apoptotic regulators, which leads to cancer cell death by apoptosis. Recently, APN inhibition has been shown to augment DR4-induced tumor cell death and thus overcome resistance to cancer treatment with DR4-ligand TRAIL, which is available as a recombinant soluble form dulanermin. This implies that APN inhibitors could serve as potential weapons for overcoming cancer treatment resistance. In this study, a series of basically substituted acetamidophenones and the semicarbazones and thiosemicarbazones derived from them were prepared, for which APN inhibitory activity was determined. In addition, a selective anti-proliferative activity against cancer cells expressing APN was demonstrated. Our semicarbazones and thiosemicarbazones are the first compounds of these structural types of Schiff bases that were reported to inhibit not only a zinc-dependent aminopeptidase of the M1 family but also a metalloenzyme.     

赤泥综合利用研究现状及分析

为了解决制铝工业中排放的赤泥废弃料难题,为了探究赤泥矿粉替代量对沥青混合料抗水损坏性能的影响,提高废弃物资源的再利用率,采用“干法改性”方案,利用赤泥等质量代替沥青混合料中的石灰岩矿粉制成赤泥沥青胶浆和赤泥沥青混合料,通过赤泥沥青胶浆的吸持性能实验和赤泥沥青混合料的浸水马歇尔实验、冻融循环劈裂实验、浸水车辙实验来测试不同替代量赤泥沥青胶浆的粘附性能和赤泥沥青混合料的抗水损坏性能。结果表明：赤泥替代沥青混合料中的石灰岩矿粉能有效地改善沥青胶浆的粘附性能和沥青混合料的抗水损坏性能。而且通过对赤泥沥青胶浆粘附性能和沥青混合料抗水损坏的机理分析 揭示了赤泥沥青混合料抗水损坏性能的原因,得出赤泥替代量为50%时沥青混合料性能较佳的结论。     

超微粉碎对菠萝蜜超微全粉品质的影响

为了明确超微粉碎工艺对菠萝蜜粉品质的影响,本文以真空冷冻-变温压差膨化联合干燥的菠萝蜜粗粉为原料,研究了超微粉碎时间对菠萝蜜超微全粉的各项理化和营养品质的影响。实验结果表明,超微粉碎时间对菠萝蜜的粒径的影响较小,经5min粉碎后即可达到超微粉的要求;菠萝蜜粉的溶解性指数和持水力与超微粉碎时间呈上升趋势,类胡萝卜素和维生素C含量与超微粉碎时间呈下降趋势;通过真空冷冻-变温压差膨化联合干燥方法干燥法获得的菠萝蜜粉的流动性可满足实际生产的需要,产品的吸湿性较小,不易粘结。      

微粉化对豌豆粉理化性质的影响

研究了微粉化处理对豌豆粉理化和功能特性的影响。对5个不同粒径大小的豌豆粉进行粒径大小、粒径分布、微观形貌、基本成分含量、持水力、膨胀力、水溶性测定。结果表明:随着微粉化程度的增加,豌豆粉平均粒径逐渐减小,粒径分布范围逐渐变窄,比表面积增大,粉体更加均匀;豌豆普通粉经微粉碎后,粉体粒径减小,水分含量降低,损伤淀粉含量增加,持水力、膨胀力降低,但仍保持了一定的吸附水分的功能特性,水溶性呈先增强后减弱的趋势。      

湿热物理改性红小豆全粉的添加量对火腿肠质构和色度的影响

应用TA.XT2质构仪、感官评价和Hunterlab色度仪,研究了湿热物理改性红小豆全粉的添加量对火腿肠质构和色度的影响。结果表明:随着红小豆全粉的添加量增加(2%~6%),火腿肠的硬度、弹性和咀嚼性显著增加(p<0.05),而火腿肠的胶粘性无明显变化;Hunterlab测定的L*值和a*值随着红小豆全粉添加量的增加而显著增加(p<0.05),而b*值变化很小。感官评价的T测验结果表明,添加6.0%红小豆全粉火腿肠的风味、香气、色泽、总体接受性方面优于无添加红小豆全粉的火腿肠。