全文获取类型
收费全文 | 77463篇 |
免费 | 8843篇 |
国内免费 | 8524篇 |
专业分类
电工技术 | 5929篇 |
技术理论 | 2篇 |
综合类 | 4974篇 |
化学工业 | 19549篇 |
金属工艺 | 3608篇 |
机械仪表 | 4435篇 |
建筑科学 | 3036篇 |
矿业工程 | 870篇 |
能源动力 | 2375篇 |
轻工业 | 4879篇 |
水利工程 | 886篇 |
石油天然气 | 1863篇 |
武器工业 | 608篇 |
无线电 | 12081篇 |
一般工业技术 | 8709篇 |
冶金工业 | 1953篇 |
原子能技术 | 2131篇 |
自动化技术 | 16942篇 |
出版年
2024年 | 369篇 |
2023年 | 1523篇 |
2022年 | 2287篇 |
2021年 | 2621篇 |
2020年 | 2682篇 |
2019年 | 2444篇 |
2018年 | 2154篇 |
2017年 | 3089篇 |
2016年 | 3153篇 |
2015年 | 3597篇 |
2014年 | 3677篇 |
2013年 | 4903篇 |
2012年 | 5835篇 |
2011年 | 4971篇 |
2010年 | 4375篇 |
2009年 | 4477篇 |
2008年 | 4700篇 |
2007年 | 5683篇 |
2006年 | 5503篇 |
2005年 | 4598篇 |
2004年 | 3884篇 |
2003年 | 3189篇 |
2002年 | 2570篇 |
2001年 | 2002篇 |
2000年 | 1753篇 |
1999年 | 1612篇 |
1998年 | 1285篇 |
1997年 | 1096篇 |
1996年 | 885篇 |
1995年 | 729篇 |
1994年 | 639篇 |
1993年 | 509篇 |
1992年 | 402篇 |
1991年 | 323篇 |
1990年 | 281篇 |
1989年 | 200篇 |
1988年 | 194篇 |
1987年 | 123篇 |
1986年 | 105篇 |
1985年 | 105篇 |
1984年 | 82篇 |
1983年 | 43篇 |
1982年 | 60篇 |
1981年 | 23篇 |
1980年 | 23篇 |
1979年 | 17篇 |
1978年 | 7篇 |
1977年 | 20篇 |
1976年 | 8篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 20 毫秒
991.
以固体超强酸SO2-4/TiO2 WO3为催化剂,通过丁酮和1,2 丙二醇反应合成了丁酮1,2 丙二醇缩酮。探讨了SO2-4/TiO2 WO3对缩酮反应的催化活性,研究了酮醇摩尔比、催化剂用量、反应时间对产品收率的影响。实验表明,在n(丁酮)∶n(1,2 丙二醇)=1∶1 5,催化剂用量为反应物料总质量的0 7%,环己烷为带水剂,反应时间1 0h的优化条件下,丁酮1,2 丙二醇缩酮的收率可达85 7%。 相似文献
992.
The corrosion and inhibition behavior of mild steel in 1 M HCl in the presence of poly(4-vinylpyridine)(P4VP) and potassium iodide (KI) was investigated using weight loss measurements, potentiodynamic polarization studies and impedance measurements. The inhibition efficiency increased with increasing P4VP concentration. The inhibiting action of P4VP is considerably enhanced by the addition of potassium iodide. The adsorption of this compound either alone or in combination with iodide ions on the metal surface is found to obey Lamgmir's adsorption isotherm. The experimental results suggest that the presence of iodide ions in the solution increases the surface coverage and, therefore, indicate the joint adsorption of P4VP and iodide ions. On the other hand, it was found that the inhibiting effect of P4VP and (P4VP + KI) increased with increasing temperature of the corrosion medium. The presence of these species in the solution decreases the double layer capacitance and increases the charge transfer resistance, both derived from Nyquist plots obtained from a.c. impedance studies. The variation of charge transfer resistance with time suggests that the inhibitive action of (P4VP + KI) depends mainly on the protective inhibitor film formed on the steel surface. 相似文献
993.
Chlorinated poly(vinyl chloride) (CPVC)/poly(vinyl pyrrolidone) (PVP) membranes were prepared by using the solvent system tetrahydrofuran (THF)/n‐butyl alcohol (n‐BA) to investigate the possibility of pore size and pore‐size distribution control. The coagulation of CPVC/PVP solution was induced by the exposure to water vapor at 25 (±0.5)°C. The average pore diameter, dp, and the size distribution of pores on the surface of the membrane were quantified through the image analyzer from the images visualized by field emission scanning electron microscope (FE‐SEM). Surface pore size and distribution of the prepared CPVC/PVP membrane were strongly affected by the relative humidity (RH) in the environment and the content of PVP used as an additive. Particularly, in the case of CPVC membrane without PVP, the mean pore size was 0.15–0.2 μm, depending on the RH. The pore distribution became broad with the increase of the RH. The membranes had open pores as confirmed by the hydraulic permeation experiment. In addition, the water flux and membrane resistance (Rm) were greatly affected by the composition of polymer solution and the RH. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1195–1202, 2002 相似文献
994.
1-(5-乙基-1,3,4-噻二唑基)-3-苯基硫脲的合成及生物活性 总被引:12,自引:0,他引:12
研究了 1 - ( 5 -乙基 - 1 ,3,4-噻二唑基 ) - 3-苯基硫脲的合成及抗菌活性。以 5 -乙基 - 2 -氨基 - 1 ,3,4-噻二唑和异硫氰酸苯酯为原料 ,在十六烷基三甲基溴化铵催化下 ,合成 1 - ( 5 -乙基 - 1 ,3,4-噻二唑基 ) - 3-苯基硫脲 ,找到了较好的合成工艺条件 ,结果表明 :5 -乙基 - 2 -氨基 - 1 ,3,4-噻二唑和异硫氰酸苯酯的摩尔比为 1∶ 1 .8,乙腈为溶剂 ,水浴加热回流 4.0 h,十六烷基三甲基溴化铵为 2 g,1 - ( 5 -乙基 - 1 ,3,4-噻二唑基 ) - 3-苯基硫脲的产率为 5 9.76%。同时发现 1 - ( 5 -乙基 - 1 ,3,4-噻二唑基 ) - 3-苯基硫脲有较强的抗菌活性 相似文献
995.
Highly Efficient Overall Water Splitting Through Optimization of Preparation and Operation Conditions of Layered Perovskite Photocatalysts 总被引:1,自引:0,他引:1
Jindo Kim Dong Won Hwang Hyun Gyu Kim Sang Won Bae Jae Sung Lee Wei Li Se Hyuk Oh 《Topics in Catalysis》2005,35(3-4):295-303
The layered perovskite materials were found to give the high photocatalytic activity in water splitting reaction under UV
irradiation, where the electronic structure of perovskite slab constructing the layered structure (the total cation valency)
was the most crucial factor to the high photocatalytic activity. Both the excessive cation valency and the layered structure
were required for active photocatalysts, while the slab thickness of layered perovskites had an insignificant effect on water-splitting
activity. In order to identify key variables that affected photocatalytic activity and to optimize the performance of (110)
layered perovskite, La2Ti2O7 was modified by various methods. The optimum amount of loaded nickel had a great effect and the amount depended on the surface
area of the perovskite phase. When an alkaline-earth element such as Ba, Sr, and Ca was doped on La2Ti2O7, the photocatalytic activity was enhanced markedly. Introduction of an alkaline hydroxide into the reaction system as an
external additive enhanced the activity further showing extremely high quantum yields close to 50%. 相似文献
996.
997.
Dong Shu Jinghua Zhang Chun He Yuezhong Meng Hongyu Chen Yongsheng Zhang Mianping Zheng 《Journal of Applied Electrochemistry》2006,36(12):1427-1431
High electrocatalytic activity of an electropolymerized film of poly(3-methoxythiophene) (PMOT) is reported toward the redox reaction of 2,5-dimercapto-1,3,4-thiadiazole (DMcT) as a promising cathode material for the lithium ion battery. Cyclic voltammetry showed improved electrochemical performance of DMcT on PMOT-coated Pt electrode, indicating accelerated redox kinetics. Moreover, charge-discharge tests exhibited higher discharge capacity and slower capacity fading of the PMOT-doped DMcT composite cathode compared with pure DMcT. 相似文献
998.
Analysis of the polyethylene glycol glucosides and FA esters thereof by atmospheric-pressure ionization MS 总被引:1,自引:0,他引:1
Xin?Jin Jinzong?YangEmail author Bingtao?Tang Minggui?Zhu Ning?Yu Yi?Liu 《Journal of the American Oil Chemists' Society》2003,80(6):519-524
Polyethylene glycol (PEG) glucosides (PEGG) and the PEGG esters of lauric acid were analyzed by atmospheric-pressure ionization
MS (API-MS) with electrospray ionization. Straightforward mass characterization of the complex mixtures could be achieved
without prior chromatographic separation. The constituents were identified on the basis of quasi-molecular ions. Individual
components could be observed as protonated molecular ions [M+H]+ and/or as their NH4
+, Na+, or K+ adducts in positive ion mode. The mass spectrometric investigation showed that mixtures of PEGG consisted of monoglucoside,
diglucoside, polyglucoside, and free PEG. The esterification product is a mixture of two types of nonionic surfactants: PEG-laurates
and PEGG-laurates. The reasons for distortion of the quasi-molecular ion intensities and the stabilization of adduct ions
were discussed. The rapid and highly sensitive API-MS analysis technique proposed here is well suited for direct characterization
of complex mixtures and suitable for development as a routine analytical method. 相似文献
999.
涤纶废产物用于制备聚氨酯泡沫塑料 总被引:2,自引:0,他引:2
将涤纶废产物用二甘醇和三元醇经酯基转移合成齐聚酯多元醇,并用其制备聚氨酯硬质泡沫塑料。该泡沫塑料具有良好的力学性能,且随着齐聚酯多元醇平均官能度的影响,力学性能随之提高;由于齐聚酯多元醇中芳香族基团含量高,泡沫塑料的铖一明显高于普通聚氨酯泡沫塑料。 相似文献
1000.
Nucleating activity of the quinacridone and phthalocyanine pigments in polypropylene crystallization
Jan Broda 《应用聚合物科学杂志》2003,90(14):3957-3964
The nucleating ability of two organic pigments, quinacridone and phthalocyanine, in nonisothermal polypropylene (PP) crystallization was investigated. The investigations were carried out using DSC and polarizing microscopy. The efficiency of pigments in the nucleation process was determined in a simple test comparing the crystallization temperature of the PP‐containing pigments with respect to the pure polymer. Both pigments revealed good nucleating activity. In the presence of pigments the increment of the crystallization temperature and the increase of nucleation rate were observed. The nucleating efficiency of pigments was confirmed in investigations of the obtained structure. The nucleating activity of pigments was explained by their features fulfilling several requirements for good nucleating agents. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3957–3964, 2003 相似文献