Preparation and characterization of metal-complex imprinted PVDF hollow fiber membranes

Using nickel-2,2′-dipyridyl complex as a template, N-vinyl-2-pyrrolidone as the metal coordination functional monomer, and ethylene glycol dimethacrylate as the crosslinker, polyvinylidene fluoride (PVDF) hollow fiber ultrafiltration membrane as the supported membrane, metal complex imprinted polymeric membranes were prepared. The association constant of template-monomer interaction in the prepolymerization solution was estimated to be 4.38 × 10⁴ (L/mol)² by spectrophotometric titration analysis. The attenuated total reflection Fourier transform infrared spectroscopy and scanning electron micrograph characterization indicated that the surface of the support PVDF membrane was completely coated by the imprinted polymer layer after modification. The imprinted membranes exhibited the selective permeability for the template in certain nickel acetate solution. The molecularly imprinted membranes gave higher permeation separation factors at about pH 6, whereas increasing pressure would lower the separation ability. The effects of ion concentration, cations and counterions, ligand selectivity, pH, and trans-membrane pressure were investigated and the permeation performances of the imprinted membranes could be regarded as facilitated transport mechanism. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Synthesis,characterization, and redox and electrochromic behaviors of poly(3-n-octyloxythiophene)

Poly(3-n-octyloxythiophene), a conjugated polymer, which possessed solubility in common organic solvents, was synthesized by electrochemical polymerization in the presence of lithium perchlorate as the supporting electrolyte and sodium dodecyl sulfate as the surfactant in an aqueous medium. Characterizations of the intermediate, monomer, and polymer were performed by NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, and gel permeation chromatography. The process of electrochemical polymerization and the electrochemical redox behaviors were investigated by cyclic voltammetry and the potentiostatic method. A poly(3-n-octyloxythiophene) film that was deposited on a platinum electrode was found to exhibit electrochromic behaviors, and it switched electrochemically between blue–green oxidized and dark red reduced states. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Hybrid numerical scheme for time-evolving wave fields

Many problems in geophysics, acoustics, elasticity theory, cancer treatment, food process control and electrodynamics involve study of wave field synthesis (WFS) in some form or another. In the present work, modelling of wave propagation phenomena is studied as a static problem, using finite element method and treating time as an additional spatial dimension. In particular, WFS problems are analysed using discrete methods. It is shown that a fully finite element-based scheme is very natural and effective method for the solution of such problems. Distributed WFS in the context of two-dimensional problems is outlined and incorporation of any geometric or material non-linearities is shown to be straightforward. This has significant implications for problems in geophysics or biological media, where material inhomogeneities are quite prevalent. Numerical results are presented for several problems referring to media with material inhomogeneities and predefined absorption profiles. The method can be extended to three-dimensional problems involving anisotropic media properties in a relatively straightforward manner. Copyright © 2006 John Wiley & Sons, Ltd.     

Formation Kinetics of Unsaturated (Ti, W)C Solid Solution

ＦｏｒｍａｔｉｏｎＫｉｎｅｔｉｃｓｏｆＵｎｓａｔｕｒａｔｅｄ（Ｔｉ，Ｗ）ＣＳｏｌｉｄＳｏｌｕｔｉｏｎＬｉｎＣｈｅｎ’ｇｕａｎｇ，ＤｅｎｇＦｅｎｇｘｉａｎｇ，ＨｅＣｏｎｇｘｕｎａｎｄＧａｏＺｈａｏｚｕ（林晨光）（邓凤翔）（贺从训）（高兆祖）（Ｇｅｎｅｒ...     

Recrystallisation of amorphous natural brannerite through annealing: The effect of radiation damage on the chemical durability of brannerite

An amorphous natural brannerite sample was chosen to study the annealing of the radiation damage through thermal recrystallisation, and subsequently to evaluate the effect of radiation damage on its aqueous durability. Microstructural characterisation of the natural brannerite revealed minor alteration along the rim of the crystal and within cracks. The formation of UO₂ particles and soluble Pb–Ca-rich aluminosilicate glass is responsible for the higher U and Pb releases from the recrystallised brannerite. In general, natural brannerite has been shown to be resistant to dissolution over geological time, therefore minor brannerite inclusions in ceramic formulations for immobilisation of actinide-rich radioactive wastes should not have a detrimental effect on the long-term chemical durability of the wasteforms.     

耦合模模型的峰峰值与有效值

介绍了峰峰值和有效值的偶合模方程,给出了峰峰值P矩阵和有效值P矩阵的表达式。利用峰峰值P矩阵和有效值P矩阵模拟了纵向耦合谐振结构以及阻抗元结构的声表面波滤波器的频响。对比两种P矩阵的模拟结果,说明了峰峰值耦合模方程和有效值耦合模方程分析频响的等效性。     

Stochastic analysis of file-swarming systems

File swarming (or file sharing) is one of the most important applications in P2P networks. In this paper, we propose a stochastic framework to analyze a file-swarming system under realistic setting: constraints in upload/download capacity, collaboration among peers and incentive for chunk exchange. We first extend the results in the coupon system [L. Massoulie, M. Vojnovic, Coupon replication systems, in: Proc. ACM SIGMETRICS, Banff, Alberta, Canada, 2005] by providing a tighter performance bound. Then we generalize the coupon system by considering peers with limited upload and download capacity. We illustrate the last-piece problem and show the effectiveness of using forward error-correction (FEC) code and/or multiple requests to improve the performance. Lastly, we propose a framework to analyze an incentive-based file-swarming system. The stochastic framework we propose can serve as a basis for other researchers to analyze and design more advanced features of file-swarming systems.     

Thermally and plastically induced residual strains in textured Zircaloy-2 plate

The residual intergranular strains in textured Zircaloy-2 plate samples induced by cooling from 823 K to ambient temperatures, by cold-rolling by 1.5% and 25% and by deforming in tension by 1.5% were measured by neutron diffraction. The strong rolling texture, which gives rise to two ideal orientations, permitted the interpretation of much of the data in terms of strain tensors for the two orientations. The experimental results were compared with calculations based on the elasto-plastic self-consistent model with no adjustable parameters. Close agreement was obtained for samples in the as-cooled state and deformation in tension by 1.5% but the agreement is less satisfactory for cold-rolling.     

A new alloy design concept for austenitic stainless steel with tungsten modification for bipolar plate application in PEMFC

The feasibility of a new alloy design concept utilizing the principle of ‘tungsten bronze effect’ is critically evaluated for the development of metallic bipolar plates for proton exchange membrane fuel cell (PEMFC). An austenitic stainless steel (ASS) is modified with W and La to improve the stability of the passive film in an acidic environment as well as to reduce the contact resistance by the tungsten bronze effect. The experimental ASS containing W and La was evaluated in a simulated PEMFC environment of H₃PO₄ and H₂SO₄ solutions at 80 °C, and the electrical property was evaluated by performing a contact resistance test. The test results show that the ASS modified with W and La has good passive film stability for corrosion resistance and low contact resistance. The X-ray photoelectron spectroscopy (XPS) analysis clearly suggests the possibility of the tungsten bronze effect from the change in valency state of W⁶⁺ to W⁵⁺ in the passive film formed on the modified ASS. The feasibility of a new alloy design concept utilizing the ‘tungsten bronze effect’ is well demonstrated; however, more study is highly required for the development of metallic bipolar plates of PEMFC.     

我国和奥地利普兰西公司的钨、钼产品及其差距

对奥地利普兰西公司作了简要介绍，并将我国的钨、钼产品标准和普兰百公司的钨、钼产品、规格进行了对比。根据差距提出了我国钨、钼产品今后的发展方向。