Development of microstructure and mechanical properties of a Ni-base single-crystal superalloy by hot-isostatic pressing

Effects of the hot-isostatic pressing (HIP) process on microstructures and mechanical properties of Ni-base single crystal superalloy CMSX-4 were investigated. In the overall heat treatment process, the HIP treatment remarkably induced the healing behavior of micropores and decreased the pore size and porosity of superalloy CMSX-4 compared with normally treated specimens. The microstructure of γ′ phase after the HIP process showed rather a coarsening tendency and could be developed by the partially solution and aging treatment. Consequently, the elimination of cast micropores using the HIP step resulted in the inhibition of crack initiation in microstructure and improved the stress-rupture lives of Ni-base single crystal superalloy by 185%.     

An Optimization Method For Estimating Phase Compositions And Amounts In Two—Phase Nickel Base Superalloys

根据已知镍基合金成分和γ′相成分，运用分层宽容多目标优化法，分别计算了γ相成分及γ′相含量．优化测算过程的实现是通过建立使杠杆定律等式两端数值差最小和两相共格错配度最小的目标函数，并通过设置γ′相含量和基体相成分取值范围的约束条件而实现的．验证了该方法的可行性和准确性．     

Diffusion bonding between nickel-base superalloy K24 and heat-resisting steel 1Cr11Ni2W2MoV

IntroductionSLlperalloyandheat-resistingsteelarenowwidelyusedasstructurematerialsinaerospace,a\-lationalldshipbuildingindustries.Nickel-basesuperalloywasfirstlyrevealedasanengineeringmaterialduringtheearly1960swhenitwasrecognizedasbeingsuitableforllledium-temperaturegasturbinel'l.Now.nickel-basesuperalloyhasbeenpracticallyusedinhigheffectiveturbinestosatisfytheincreasingdemandsforhighertemperatureenvironmentsIZI.Insomeaerospaceengines,theimpellersshouldserveattemperatureof1000C~1100C,andala…     

Copolymerization of norbornene with norbornene terminated polystyrene macromonomer in the presence of Ni-based/MAO catalytic systems

Copolymerization of -norbornenyl polystyrene macromonomer (NBE-PS) with norbornene (NBE) using Ni-based catalysts in combination with methylaluminoxane (MAO) was investigated. The nature of the catalyst, the of the polystyrene macromonomer as well as the [NBE-PS]/[NBE] ratio have been shown to be important parameters to obtain graft copolymers with high NBE-PS incorporation (up to 43 wt%). The compatibilization ability of these graft copolymers has been checked for PS/PNBE blends. The length of the grafts was proved not to be an important parameter to consider compatibilization of the PS/PNBE blend.     

高温合金IN690管材挤压损伤模拟

采用有限元软件对高温合金IN690管材挤压损伤进行预测,研究挤压速度对损伤的影响规律,得到不同的挤压条件下的挤压阈值。不同挤压速度下损伤的变化随着挤压速度变化呈现先增大后减小的趋势。模拟摩擦系数为0.01、0.05、0.1、0.2条件下的损伤,在摩擦系数为0.01时,坯料表面比较光滑,损伤比较轻;摩擦系数为0.2时,表面凹凸不平,损伤严重。     

Monel-400合金板焊接温度场有限元分析

利用ANSYS有限元分析软件,根据钨极氩弧焊焊接特点,建立了高斯衰减热源模型,并在一定厚度、一定焊接工艺条件下对Monel-400合金板焊接温度场进行了模拟计算。模拟结果分析得到：利用高斯旋转热源在焊接过程中形成了长度为12 mm,宽度为7 mm,深度为5 mm的熔池。熔池上表面与下表面温度相差约620℃,热影响区节点温度随到焊缝中心距离的增加而不断减小。模拟结果表明改进后的热源模型与实际焊接较为吻合,有利于提高焊接温度场的模拟计算精度。     

K4104合金渗Al涂层抗高温氧化性能研究

采用料浆法在K4104合金表面进行热扩散渗铝,经1000℃×200h高温氧化性试验,用扫描电镜观察氧化后涂层的表面形貌。结果表明,渗Al涂层在氧化过程中已转变成连续致密的-αAl2O3氧化层和富铝的-βNiAl化合物层,使基体合金得到有效地保护,渗Al涂层具有良好的抗高温氧化性能。     

The Main Degradation Modes of an Aluminide Coating on a Co-Base Superalloy During High-Temperature Oxidation in Air

Degradation of aluminide coatings occurs by two ways, one by coating oxidation, and the other by interdiffusion of Al. In this paper, the structure variation and phase transformation are analyzed for the aluminide coating on a newly developed Co-base superalloy (DZ40M alloy) after oxidation at 900 and 1000°C in air. The results show that degradation of this coating was mainly by oxidation at 900°C, but principally by interdiffusion at 1000°C. The main degradation mode of the coating is primarily dependent on the oxidation temperature and the specific structure of the coating itself.     

Creep behavior and microstructure evolution of directionally solidified superalloy IC 10 at high temperature

The creep behavior of directionally solidified （DS） superalloy IC 10 was investigated under 192 MPa and 218 MPa at 980 ℃. Under the testing conditions, the marked creep characteristic of the superalloy is that the creep curve has a short primary and secondary stage and a long tertiary stage. Another creep characteristic is that the superalloy has excellent plasticity at high temperature. To study the creep behavior, the microstructure was observed by SEM and TEM. Different from other microstructure of Ni-base superalloys, superalloy IC10 forms incompletely rafted γ＇ phase during the creep processes. To understand the creep deformation mechanism of superalloy IC10, the movement of dislocations was analyzed. The results show that the dislocations moving in the γ matrix and climbing over the γ＇ precipitates is the main deformation mechanism under the experimental conditions.     

钴基高温合金的循环氧化行为研究

研究了钴基高温合金K40S在950℃和1000℃的循环氧化行为。发现合金在950℃400h以内的抗循环氧化性能较好，合金在1000℃氧化50h以后因为表面氧化膜剥落开始出现失重现象。在1000℃循环氧化初期的产物主要为Cr2O3，其次为CoCr2O4和少量的CoO,400h以后，Cr2O3基本剥落，合金表面由于Cr的损耗又生成Cr2WO6、NiCr2O4以及挥发性的WO3氧化产物。添加Si和Mn元素使K40S合金抗循环氧化性能明显地比不含Si和Mn元素的DZ40M钴基高温合金优越。