Wet 2,4,6-trichloro[1,3,5]triazine (TCT) an efficient catalyst for synthesis of -bis(substituted-benzylidene) cycloalkanones under solvent-free conditions

An array of aromatic aldehydes undergo crossed aldol condensation with ketones in the presence of catalytic amounts of wet-TCT under solvent-free conditions to afford the corresponding α,α^′-bis(substituted-benzylidene) cycloalkanones in excellent yields. Contrary to the existing methods, which use classical Lewis acids a new catalyst (TCT) is employed. This method is also general with respect to all types of aromatic aldehydes and is an eco friendly procedure.     

Adsorption isotherm models for dye removal by cationized starch-based material in a single component system: error analysis

This article describes the adsorption of an anionic dye, namely C.I. Acid Blue 25 (AB 25), from aqueous solutions onto a cationized starch-based adsorbent. Temperature was varied to investigate its effect on the adsorption capacity. Equilibrium adsorption isotherms were measured for the single component system and the experimental data were analyzed by using Langmuir, Freundlich, Tempkin, Generalized, Redlich-Peterson, and Toth isotherm equations. Five error functions were used to determine the alternative single component parameters by non-linear regression due to the bias in using the correlation coefficient resulting from linearization. The error analysis showed that, compared with other models, the Langmuir model described best the dye adsorption data. Both linear regression method and non-linear error functions provided the best-fit to experimental data with the Langmuir model.     

Simulation of Microstructure Evolution of Ni75Al2.9V22.1 Alloy with Progressive Aging Mechanisms

The interrupted aging mechanisms were applied to Ni75Al2.9V22.1 alloy by using the microscopic phase-field simulation method. For the single phase region existing at high temperature, the low content alloy was used as the study object. With the progressive aging mechanisms, the metastable phase γ′ of high temperature can be obtained from the low temperature two phase regions, and the quantity of γ′ phase reduces with increasing temperature. The θ single phase morphology at high temperature regions will turn to be the γ′＋θ two phase morphology at low temperature with the interrupted aging method. Despite of the different precipitation paths of γ′ phase, the precipitation mechanisms are the same for the low temperature aging and high temperature interrupted aging.     

Using neighborhood-pixels-information and ANFIS for impulsive noise suppression

This paper introduces a novel approach for denoising the images corrupted by impulsive noise (IN) by using a new nonlinear IN suppression filter, entitled k-nearest neighborhood pixels-based Adaptive-Fuzzy Filter (k-AFF). The proposed filter is based on statistical impulse detection and nonlinear filtering which uses Adaptive-Network-Based Fuzzy Inference System (ANFIS) as a missed data interpolant over the k-nearest neighbor pixels of the corrupted pixels. The impulse detection is realized by using the well-known Kolmogorov–Smirnov-based goodness-of-fit test, which yields a decision about the impulsivity of each pixel. To demonstrate the capability of k-AFF, extensive simulations were realized revealing that the proposed filter achieves a better performance than the other filters mentioned in this paper in the cases of being effective in noise suppression and detail preservation, even when the images are highly corrupted by IN.     

Fe-25Mn-6Si-7Cr形状记忆合金在含沙多相流中的损伤行为

测量Fe-25Mn-6Si-7Cr形状记忆合金在含沙多相流中的损伤抗力,研究了失效机制和损伤抗力的控制因素,并与水轮机叶片用不锈钢0Cr13Ni5Mo进行了对比.结果表明,Fe-25Mn-6Si-7Cr形状记忆合金在含沙多相流中的失效机制主要是泥沙犁削,其损伤抗力因高的局域弹性和高的犁削抗力而优于不锈钢0Cr13Ni5Mo,局域弹性高是其损伤破坏速度效应低和空蚀与泥沙冲刷磨损交互作用小的根本原因.     

25MnVK钢奥氏体的连续冷却相变

采用THERMECMASTOR-Z热模拟试验机研究25MnVK钢变形奥氏体在连续冷却过程中的相变规律,用膨胀法结合金相组织以及硬度值测定该钢的连续冷却转变曲线(CCT).结果表明,该钢的奥氏体化温度为920 ℃.当连续冷却速度小于2 ℃/s时得到的组织为铁素体 珠光体,大于2 ℃/s时出现贝氏体,大于50 ℃/s出现马氏体组织,所以通过控制不同的冷速,可以得到适合的组织.为制定25MnVK钢加热制度和控冷工艺提供了基本条件.此外V的加入使得钢的组织转变得到明显的推迟,CCT曲线右移,钢的淬透性得到提高.     

Eisenbahntrasse; heranrückende Wohnbebauung; erforderliche Lärmschutzmaßnahmen; zulässige Einwendungen der Eisenbahntrassenbetreiberin

Mit der Widmung "Bauland-Wohngebiet" ist auch ein Schutz vor Immissionen, die von einer Eisenbahntrasse ausgehen, verbunden. Erteilt die Baubeh?rde eine Baubewilligung für ein Wohnhaus ohne Prüfung der Einwendungen der benachbarten Betreiberin einer Eisenbahntrasse (hier: in Bezug auf die Verpflichtung zu L?rmschutzma?nahmen), verletzt sie – wegen objektiver Willkür – den Gleichheitssatz.     

粉末冶金Ti-22Al-25Nb合金的放电等离子烧结工艺数值模拟与实验研究

选用Ti-22Al-25Nb预合金粉末为实验初始原料,采用放电等离子烧结工艺（SPS）制备组织致密的粉末冶金Ti-22Al-25Nb合金。采用MSC.Marc有限元软件对SPS过程中粉末的致密化过程进行了数值模拟,分析了烧结温度、保温时间和烧结压力对粉末致密化过程的影响,揭示了粉末相对密度随烧结温度、保温时间和烧结压力的变化规律。根据模拟结果,在950~1 200 ℃温度区间、50 MPa烧结压力和10~20 min保温时间的条件下,完成系列SPS烧结实验,制备获得Ti-22Al-25Nb合金。系统分析了50 MPa/10 min烧结条件下温度对Ti-22Al-25Nb合金的相对密度、显微组织和力学性能的影响,揭示了烧结合金的断裂机制。实验结果表明烧结合金在950 ℃/50 MPa/10 min条件下具有最优的综合力学性能,延伸率和屈服强度分别达到8.14%和691.04 MPa。     

表面施加含稀土氧化物薄膜对Fe25Cr高温氧化的"活性元素效应"

研究了表面施加含有不同量Y