“镍”催化酰氯和有机锡试剂交叉偶联反应的研究

镍络合物催化酰氯与有机锡试剂交叉偶联合成有机酮的反应,其反应选择性强,反应彻底,转化率高,工艺简单。在有机锡过量的情况下,对不同催化剂的催化活性和包括投料比,反应温度,反应时间,反应溶剂等反应条件进行了考察。     

非晶硅基薄膜的等离子体刻蚀光发射谱检测

本文研究了采用锁定放大相干检测技术的等离子体光发射谱检测系统。用该系统检测了仅用CF4作为刻蚀气体刻蚀非晶硅基薄膜的等离子体光发射谱。分析了检测结果和刻蚀机理。     

Ca,Mg对镍基高温合金力学性能和热塑性的影响

本文研究了单加或同时添加微量Ca和Mg对变形及铸态镍基高温合金力学性能和热塑性的影响。试验表明,适量的Mg或Ca、Mg对提高合金的持久断裂寿命、高温拉伸塑性以及改善热塑性都取得良好效果。     

基于双秘钥的高强度公钥密码体制的研究

该文研究双秘钥公开钥密码体制,它不同于一般的只有一个秘密密钥的公开钥密钥体制,而是使用两个秘密密钥。要攻破它必须同时解决两个数学难题(素因子分解和求离散对数),从而大大增加了破译难度。     

Pure perceptual-based sequence learning.

Learning a sequence of target locations when the sequence is uncorrelated with a sequence of responses and target location is not the response dimension (pure perceptual-based sequence learning) was examined. Using probabilistic sequences of target locations, the author shows that such learning can be implicit, is unaffected by distance between target locations, and is mostly limited to first-order transition probabilities. Moreover, the mechanism underlying learning affords processing of information at anticipated target locations and appears to be attention based. Implications for hypotheses of implicit sequence learning are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Thermal—Mechanical Fatigue Behavior and Life Analysis of Cast Ni—base Superalloy K417

In-phase(IP) and out-of-phase(OP)thermal-mechanical fatigue(TMF) behavior of cast Ni-base superalloy K417 was studied.All experiments were carried out under total strain control with temperature cycling between 400-850℃.Both in-phase and out-of-phase TMF specimens exhibited cyclic hardening followed by cyclic softening at the minimum temperature.Besides,they cyclically hardened in the early stage of life followed by cyclic softening at the minimum temperature.Besides,they cyclically hardened in the early stage of life followed by cyclic softening at the maximum temperature.OP TMF life was longer than of IP TMF.Various damage mechanisms operating in different controlled strain ranges and phasing were discussed.A few life prediction methods for isothermal fatigue were used to handle TMF fatigue and their applicability to superalloy K417 was evaluated.The SEM analysis of the fracture surface showed that transgranular fracture was the principal cracking mode for both IP and OP TMF.Oxidation was the main damage mechanism in causing shorter fatigue life for IP TMF compared with OP TMF.     

铜基催化剂孔隙率对气体有效扩散系数的影响

研究了18种具有不同孔结构参数的粒状铜基甲醇合成催化剂孔隙率对有效扩散系数的影响。结果发现，催化剂微孔孔隙率增大，曲节因子亦增大，扩散阻力增加。将孔隙率与催化剂曲节因子关联，得到了半经验方程，用它可估算催化剂的曲节因子。     

Detection of multiple cracks using frequency measurements

A method for detection of multiple open cracks in a slender Euler-Bernoulli beams is presented based on frequency measurements. The method is based on the approach given by Hu and Liang [J. Franklin Inst. 330 (5) (1993) 841], transverse vibration modelling through transfer matrix method and representation of a crack by rotational spring. The beam is virtually divided into a number of segments, which can be decided by the analyst, and each of them is considered to be associated with a damage parameter. The procedure gives a linear relationship explicitly between the changes in natural frequencies of the beam and the damage parameters. These parameters are determined from the knowledge of changes in the natural frequencies. After obtaining them, each is treated in turn to exactly pinpoint the crack location in the segment and determine its size. The forward, or natural frequency determination, problems are examined in the passing. The method is approximate, but it can handle segmented beams, any boundary conditions, intermediate spring or rigid supports, etc. It eliminates the need for any symbolic computation which is envisaged by Hu and Liang [J. Franklin Inst. 330 (5) (1993) 841] to obtain mode shapes of the corresponding uncracked beams. The proposed method gives a clear insight into the whole analysis. Case studies (numerical) are presented to demonstrate the method effectiveness for two simultaneous cracks of size 10% and more of section depth. The differences between the actual and predicted crack locations and sizes are less than 10% and 15% respectively. The numbers of segments into which the beam is virtually divided limits the maximum number of cracks that can be handled. The difference in the forward problem is less than 5%.     

In situ regeneration of the Ni-based catalytic reformer of a 5 kW PEMFC system

The paper reports the results of on-site regeneration catalytic bed of the natural gas reformer in a 5 kW PEM fuel cell system. The Ni catalyst previously poisoned by sulphur from the available natural gas, could be re-activated by injection of pure water steam, following the method developed for industrial reformers using the same metal catalyst: this method was shown to be perfectly efficient, provided no natural gas was fed during the operation. Results of the tests conducted are presented and discussed in relation to published data on S-sorption on Ni surfaces.