Nitrogen incorporated diamond-like carbon films by microwave surface wave plasma CVD

Nitrogen incorporated diamond like carbon films have been deposited by microwave surface wave plasma chemical vapor deposition (MW-SWP-CVD), using methane (CH₄) as the source of carbon and with different nitrogen flow rates (N₂ / CH₄ flow ratios between 0 and 3). The influence of the nitrogen incorporation on the optical, structural properties and surface morphology of the carbon films were investigated using different spectroscopic techniques. The nitrogen has been incorporated into DLC:N films which was confirmed by the X-ray photoelectron spectroscopy (XPS) measurement. Moreover, the nitrogen incorporation was accompanied by a variation in the optical gap, which was attributed to the removal or creation of band tail states.     

NDN-1型氮氧化物脱除催化剂的评价及应用

对NDN-1型氮氧化物脱除催化剂进行了实验室性能评价,并与进口催化剂A及国产催化剂B进行了比较,结果表明,NDN-1型催化剂的化学组成、结构、性能均优于进口催化剂A。介绍了该催化剂在南京帝斯曼东方化工有限公司工业应用的情况。     

The roles of nitrogen,phosphorus and Potassium in the production of sugarcane in South Africa

The amounts of N and K fertilizers used in the South African sugar industry have increased dramatically in the past four decades, due partly to an increase in the area under sugarcane but also to large increases in the amounts of N and K fertilizers applied per hectare. There has also been an increase in the amount of P fertilizer used but this has been more gradual. The main fertilizer carriers for cane and their relative efficiency are discussed. During this period there has been considerable research into the nutrient requirements of sugarcane. Correlations established between soil and leaf analysis and crop responses to N, P and K fertilizers, and their effects on cane quality, are reviewed. While fertilizer recommendations based on soil and leaf analysis have provided a useful guide for determining the nutrient requirements of cane, they are continually being modified in the light of current research.     

用MH-81′状态方程模拟液氮洗涤塔

本文采用MH-81′状态方程和与密度无关的局部组成型混合法则,从二元汽-液平衡数据得到的二元相互作用参数,预测了部分液氮洗过程中的二元体系的混合焓,结果满意。采用三对角矩阵方法,对两种不同工况的液氮洗涤塔进行了模拟,计算结果与设计值和实测值符合较好。     

The effect of nitrogenous fertilizers on the nitrification of forest soils

The effect of fertilization with urea and ammonium nitrate on nitrogen mineralization was studied in a series of laboratory incubation experiments. The samples (humus layer) were collected from field experiments with different applications of fertilizers during a period of 11–14 years. The nitrogen fertilization influenced some chemical properties of the humus layer such as pH, N-Kjeldahl content and the content of inorganic nitrogen, especially in the samples from North Sweden. Nitrate nitrogen was formed in humus samples classified as non-nitrifying in several cases, usually after urea fertilization.     

The fate of fuel-nitrogen during gasification of biomass in a pressurised fluidised bed gasifier

The distribution of fuel-nitrogen in gases, tar and char from gasification of biomass in a pressurised fluidised bed gasifier was investigated. Four species of biomass: birch, Salix, Miscanthus and Reed canary grass were gasified at 0.4 MPa and 900 °C. Oxygen-enriched nitrogen was used as fluidising agent. As a reference, gasification of Daw Mill coal was also carried out under the same experimental conditions. The experimental results illustrate that both the nature of the original fuels and the chemical structure of the nitrogen in the fuel have influence on the distribution of fuel-nitrogen in gases (NH₃, HCN, NO), tar and char under the employed experimental conditions. The present work also shows that the types of nitrogen heterocyclic compounds (NHCs) in the tar from different kinds of biomass are the same and the major compound is pyridine. However, the distribution of the various NHCs in the tar from the four species of biomass varies: the higher the content of fuel-nitrogen, the higher the concentration of two-ring NHCs in the tar. An effective method for extracting NHCs from the acidic absorption of the product gas was introduced in the present work. The method makes use of solid phase extraction (SPE) by a silica-based C₁₈ tube to extract the NHCs which subsequently were analysed by gas chromatography (GC) with flame ionisation detection (FID). The recovery and reproducibility of the SPE technique for NHCs is discussed.     

高温环境下侧向弹性约束对钢柱稳定长度的影响

基于结构弹性稳定理论原理,导出了高温环境下钢柱在轴向荷载作用时具有弹性支座的稳定长度计算式,分析了弹簧刚度、耐火保护层、温度等参数对钢柱稳定长度的影响,进一步提出了在实际工程中应采取的有关措施。     

基于虚拟弹簧的欠驱动手指的动力学建模和控制

采用虚拟弹簧对2关节欠驱动手指进行了动力学建模。并使用该方法建立实际的3关节欠驱动手指的动力学模型,通过动态控制实验验证了动力学模型的正确性。该方法不仅避免了求解微分几何方程,并且直接派生出可解耦的动力学模型。可直接进行逆动力学分析、仿真和实时控制。同时,建立了基于动力学模型的速度观测器,用于轨迹跟踪,弥补了欠驱动手没有速度传感器的缺点,补偿了欠驱动环节造成的不确定因素。与PID或计算力矩法相比较,其轨迹跟踪误差更小,动态控制效果更好。     

高渗透稠油油藏氮气泡沫驱现场实践与认识

八面河油田面14区沙河街组沙三上段属于高孔高渗透普通稠油油藏,受储层非均质性,注水、边水推进等原因,在油田开发过程中表现出含水上升快,产量自然递减快,采出程度低的开发特点。针对高渗透稠油油藏特高含水开发初期稳油控水,2007年开展了整体氮气泡沫驱现场试验,取得了显著的控水增油效果,投入产出比为1∶7.0。研究结果对于同类油田氮气驱提高采收率具有一定的借鉴意义。     

物理填加法回收利用泡沫塑料边角废料

介绍了物理填加法回收利用泡沫塑料边角废料,其中重点介绍了用物理填加法回收利用软质泡沫塑料边角废料的生产工艺及设备,并对填加废料与不填加废料生产的经济性进行比较。