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101.
Ionomeric composites based on sepiolite and hydrogenated poly(styrene butadiene) block copolymer were obtained and characterized from a microstructural and electrical point of view. Before blending, because of the high silanol group concentration in the sepiolite, the latter could be organophilized with suitable coupling agents. The resulting materials were easily processed into thin films or membranes 0.2–0.4 mm thick, their conductivity in some cases approaching 10?1 S/cm. Their suitability for film formation and good electrical properties indicate potential applications as electrolytes in polymer fuel cells. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3512–3519, 2002 相似文献
102.
Typical finite element formulations and models for unidirectional composite materials are reviewed. The application of micromechanical finite element analysis to the modelling of unidirectional fibre-reinforced metal-matrix composites is demonstrated by presenting some studies from recent publications. It is shown that while analytical models offer a simple tool for obtaining the overall response of composites, finite element analysis provides more accurate and detailed characterisation of composite properties for complicated geometries and constituent property variations. Various effects that influence the stress/strain response and fibre/matrix deformation of composites are studied through modelling. These effects include the fibre coating and reaction layer, fibre shape and distribution, metallurgical and environmental factors, stress distributions and damage. It is demonstrated that the properties and constituent phase interaction of metal-matrix composites are best modelled by finite element analysis. It is emphasized that in order to obtain good predictions, the models must be coupled with first-hand characterisations of the constituent phases and their interactions, including the thermal history of the specimens. 相似文献
103.
This paper concerns a study of the combined effects of curing conditions and environmental exposure on the ultimate properties of two commercial woven carbon/epoxy laminates. Curing parameters (heating rate and applied pressure) were varied so as to obtain six different conditions for each material. Moisture saturation was also achieved by exposing some of the cured samples to environmental conditions of 70°C and 95% relative humidity. Four different tests (tensile, impact, Mode I and Mode II interlaminar fracture resistance) were therefore performed, and the results obtained on the different materials before and after moisture saturation compared. Neither curing pressure nor heating rate nor moisture absorption were observed to have any practical effect on tensile and impact properties. On the contrary, one noticeable effect was the interlaminar fracture resistance of the laminates. The results are discussed and interpreted in terms of damage formation and stress intensification mechanisms. 相似文献
104.
A numerical simulation model for random large amplitude vibration control of composite plate using piezoelectric material is presented. The H∞ control design is employed to suppress the large amplitude vibrations of composites plates under random loading. The numerical simulation model is developed and based on the finite element method. The finite element governing equation includes fully coupled structural and electrical nodal degrees of freedom, and consider the von Karman large amplitude vibration. The modal reduction method using the structural modes is adopted to reduce the finite element equations into a set of modal equations with fewer degrees of freedom. The modal equations are then employed for controller design and time domain simulation. In the simulations without control, the value of the linear mode to the nonlinear deflection is quantified; and the minimum number of linear modes needed for accurate model is obtained. In the simulations with control, it is shown that the truncated modes, which are neglected in the control design, deteriorate the controller performance. Generally, the vibration reduction level is not monotonically increasing with the size of the piezoelectric actuator. The optimal piezoelectric actuator size depends on the excitation level. For higher excitation level, optimal actuator size is larger. The H∞ controller based on the linear finite element formulation gives better vibration reduction for small amplitude vibration, but it still gives reasonable performance for large amplitude vibration provided that the piezoelectric actuator is big and powerful enough. 相似文献
105.
Sun Linzhi Luo Yi Zhang Yanan Sun Ping Qin Xinjie Gong ZhenbangPrecision Machinery Institute Shanghai University Shanghai China 《机械工程学报(英文版)》2002,15(4):303-307
An experimental bimorph piezoelectric element (PZT) actuator for small pipe robot is developed. The robot can move in φ20 mm pipe, and can carry a CCD camera for detecting cracks or fine holes on inner surface of pipe. The velocity of the robot can reach 17~22 mm/s for vertical pipe up/down, respectively. Moving principle and its performance characteristics are presented. 相似文献
106.
High dielectric constant (high-k) polymer composites are of great interest for embedded capacitor applications. Previously,
we demonstrated that epoxy—aluminum composites are promising for embedded capacitor applications, because they have a high
dielectric constant and a low dielectric loss due to the core—shell structure of the self-passivated aluminum particles. In
this work, to further understand the dielectric behavior of aluminum composites, lower-loss polymers such as silicone, polyimide,
polynorbornene, and benzocyclobutene were explored as matrices for the aluminum composites. It is found that the polymer matrices
can significantly change the dielectric properties of the aluminum composites. A polymer matrix with a lower dielectric constant
generally results in a lower dielectric constant of its aluminum composites. In this regard, polymer—aluminum composites have
a similar dielectric characteristic as polymer—ceramic composites. Thermomechanical properties of aluminum composites were
characterized by a thermomechanical analyzer. 相似文献
107.
Analytical solution for the axisymmetric plane strain electroelastic dynamics of a special non-homogeneous piezoelectric hollow cylinder 总被引:1,自引:0,他引:1
By virtue of the introduction of a dependent variable and the separation of variables technique, the axisymmetric plane strain electroelastic dynamic problem of a special non-homogeneous piezoelectric hollow cylinder is transformed to a Volterra integral equation of the second kind about a function with respect to time, which can be solved successfully by means of the interpolation method. Then the solutions of displacements, stresses, electric displacements and electric potential are obtained. The present method is suitable for a piezoelectric hollow cylinder with an arbitrary thickness subjected to arbitrary mechanical and electrical loads. Numerical results are finally presented. 相似文献
108.
Thermochemical analyses of interfacial reactions in titanium, zirconium, and hafnium diboride reinforced oxidematrix composites have been carried out to evaluate the chemical compatibility. The chemical reactivity of these diborides with oxygen and the high volatility of B2 O3 ( l ) at reduced oxygen pressures are concerns during processing and operating conditions. The thermochemical stability and the vaporization behavior of B2 O3 ( l ) are discussed in terms of partial pressures of dominant gaseous species of the boron-oxygen system at 1700 and 2300 K. The TiB2 /ZrO2 and TiB2 /HfO2 systems are thermodynamically stable in a limited oxygen pressure range. The TiB2 /Al2 O3 system is stable, but the reactions in this system may apparently be accompanied by formation of gaseous products (B2 O3 , AlO, Al2 O, and lower boron oxides) in the presence of elemental oxygen. These thermochemical considerations are very useful in evaluating the effectiveness of oxides as diffusion barrier coatings on diboride reinforcements. 相似文献
109.
T. Chatterjee K. Yurekli V.G. Hadjiev R. Krishnamoorti 《Advanced functional materials》2005,15(11):1832-1838
Dispersions of single‐walled carbon nanotubes (SWNTs) in poly(ethylene oxide) (PEO) assisted by a lithium‐based anionic surfactant demonstrate an electrical percolation of 0.03 wt.‐% and a geometrical percolation, inferred from melt rheometry, of 0.09 wt.‐%. Both the melting temperature and the extent of crystallinity of the PEO crystals decrease with increasing SWNT loading. Raman spectroscopy of the nanocomposites indicates a down‐shift of the SWNT G‐modes and suggests that the nanotubes are subjected to tensile stress transfer from the polymer at room temperature. 相似文献
110.
Asbestos fibres, of the chrysotile variety, and chopped carbon fibres were pretreated by an in-situ polycondensation technique eventually resulting in a polyamide coating on the fibre surface. Ionomer based composites containing either carbon or asbestos fibres in random in plane fibre orientation were prepared, and the influence of this coating process on the tensile properties was investigated. It was found that for the asbestos-filled composites the presence of the nylon 6,6 interlayer improves the tensile performance, especially at moderate polyamide depositions. This is not the case with the pretreated carbon-filled composites for which carbon fibres with higher polyamide contents are preferred. Combinations of the treated asbestos fibres with carbon and/or aramid fibres may be used to reduce the asbestos content in asbestos-only based engineering plastics. 相似文献