Synthesis and Properties of Rare Earth Complexes with 3-Ferrocenyl-5-Phenyl-Pyrazoline-1-Dithiocarbamate

Sodium 3-ferrocenyl-5-phenyl-pyrazoline-1-dithiocarbamate (FPPD) reacts with anhydrousrare earth chlorides in absolute ethanol to give 14 new complexes.The results of elemental analysis show thatthe compositions of the complexes are RE(FPPD)_3·nH_2O(RE=La,Pr～Lu and Y;n=3).The ligand andits complexes have been characterized by infrared spectroscopy,UV-visible absorptionspectroscopy,~1H-NMR spectra,thermal analysis and molar conductivity measurement.     

对流方程的交替分组显示方法

提出了求解对流方程初边值问题绝对稳定的二阶精度交替分组显示方法.模型问题的数值结果表明,本方法忧于陈景良和陆金甫的分组显示方法.     

Yielding, authoritarianism, and authoritarian ideology regarding groups.

This investigation was prompted by Asch's (1952) discussion of the personal and social significance of yielding to group pressure. For the person, yielding requires the inhibition of overt and perhaps implicit responses to objective situational requirements. For the group, malignant processes may arise and develop, unchecked by those members in whom goals of personal security predominate over group goals. In the present study, the view was taken that both meanings of yielding are assigned positive value in two separate ideologies concerning the group-individual relation. One of these is termed "conformity" and the other is "rugged individualism." In the study, group pressure was simulated by announcing bogus group judgments to small groups of Ss whose apparent task was to match one of three lines of variable length with a standard line. Questionnaires were used to measure variables, which were: the ideology of conformity (IC), the ideology of rugged individualism (RI), ethnocentrism (E), and authoritarianism (F). The questionnaires were administered to 91 college students, both day school and evening. It was found that the correlation with the F scale was .48 (P     

稀土和碱土在热镀合金中应用的研究

研究了钢件热浸镀Fe-Al-RE(Sr)的工艺,测定了镀层的性能,分析了镀层结构与性能之间的关系     

官能化噻咯合成研究进展Ⅱ.交联法、取代法、硼化法与硅烷化法

官能化噻咯(silole音译)是一种重要的噻咯衍生物,不仅在有机金属合成领域占重要地位,也是建构新型π共轭体系的重要组成部分。本文介绍了官能化噻咯的几种重要合成方法,并对各种方法的特点及适用范围作了分析和总结。     

魅力型领导与团队学习:团队目标明确度的缓冲效应

本研究采用分组回归方法,以89支学生研究项目团队作为研究对象,考查魅力型领导与团队学习间的影响关系;并检验了团队目标的明确程度对魅力型领导和团队学习间关系所起的缓冲效应.结果表明,魅力型领导有助于团队学习;另一方面,当团队目标相对明确时,魅力型领导对团队学习的积极影响效应才较为显著;而当团队目标相对不明确时,魅力型领导...     

对一个群签名方案的分析与改进

分析了一个基于中国剩余定理的群签名方案,指出此方案并不安全：任何一个群成员或已被撤销的群成员都可以完全攻破此方案。针对该安全缺陷提出了一个改进的新方案。分析表明,该方案不仅可以在不改变其他群成员密钥的情况下有效地增加和撤销群成员,而且具有不可伪造性、防陷害攻击、抗联合攻击等性质。     

LaO_x(OH)_y supported platinum catalysts for CO oxidation:Deactivation by formation of lanthanum carbonate

Platinum catalyst for CO oxidation has been studied for decades,due to its high activity and good stability.In this work,we prepared three different lantha num oxide or hydroxide supports(LaO_x(OH)_y),and deposited platinum(Pt) with 0.5 at% via an impregnation approach to synthesize Pt/LaO_x(OH)_y catalysts.However,we find that these catalysts perform a poor stability for the CO oxidation reaction.The fresh and used samples were comprehensively characterized by multiple techniques including power X-ray diffraction(XRD),X-ray absorption fine structure(XAFS),transmission electron microscopy(TEM),temperature-programmed reduction by carbon monoxide(CO-TPR) and thermogravimetric analysis(TGA),to demonstrate that the oxidized platinum atoms or clusters,without any component of Pt-Pt metallic bond,are highly dispersed on the surface of LaO_x(OH)_y.Furthermore,the as-formed lanthanum carbonate(La₂O₂CO₃) during the exposure to ambient circumstances or in the reaction atmosphere of CO+O₂,severely impair the reactivity of Pt/LaO_x(OH)_y.On the basis of the obtained experimental results,we have drawn a conclusion that the oxidized P_tO_x atoms or PtxOy clusters are the active species for CO oxidation,while the formation of lanthanum carbonate is the origin of deactivation on reactivity.     

基于成组技术的电机制造CAPP系统

根据电机厂产品的特殊性及电机零件结构特点,自行设计了具有一定针对性的13位分类编码系统,通过工艺设计标准化、自动化过程,成功开发一套适合电机生产特点的DJ-1CAPP系统,解决电机生产过程中工艺设计的瓶颈问题。