Fe—C—Mn—B合金奥氏体等温分解动力学及Mn的再分配

测定了不同含Mn量的Fe—C—Mn—B系合金的等温转变TTT曲线,结果表明,适量Mn加入Fe—C合金不但推迟转变,而且使TTT曲线形状发生较大改变而出现河湾形状。用能谱分析方法测定Mn在奥氏体、铁素体及相界处的分布规律表明,随转变温度的降低,Mn由再分配向无再分配转化,在其间存在一个温度范围、虽然无两相间的再分配,但在相界处有明显的Mn浓度峰,而且浓度峰最强的温度与TTT曲线上河湾温度相对应。说明TTT曲线形状的改变与合金元素再分配规律变化有关,河湾的出现归因于Mn在相界富集而产生的溶质拖曳与溶质类拖曳作用。     

基于MDT的汽车覆盖件反求研究

汽车工业是21世纪的主导产业,模具作为车身生产的基础工艺装备,将直接制约产品的质量和新产品的开发.文章以MDT软件为基础,利用三坐标测量仪的三维数据点通过圆率法完成了曲线曲面的光顺、拼接与合成,实现了汽车覆盖件的反求工程,从而为模具设计奠定了基础.     

湿型砂力学本质特征曲线的研究

用自制的型砂多项性能测试仪，获得了型砂抗压、松弛、抗剪和抗拉测试过程中的应力-应变本质特征曲线，并对它们进行了深入研究，在特征曲线上确定了反映型砂本质性能的8项性能参数，考察了膨润土含量和紧实率对型砂本质特征曲线和型砂性能参数的影响。型砂力学本质特征曲线决定于型砂的内部微观组织结构，反映出型砂的粘弹性和粘塑性等本质性能，体现出型砂在受力变形过程中的微变形本质特征。     

Preparation of a two-dimensional polymer film on passivated iron by modification of a carboxylate ion self-assembled monolayer with alkyltriethoxysilanes for preventing passive film breakdown

The effect of an ultrathin, regularly arranged polymer film on prevention of passive film breakdown on iron in the presence of chloride ion was investigated. The film of two-dimensional polymer was prepared by modification of a 16-hydroxyhexadecanoate ion self-assembled monolayer adsorbed on a passivated iron electrode with 1,2-bis(triethoxysilyl)ethane(C₂H₅O)₃Si(CH₂)₂Si(OC₂H₅)₃ and octyltriethoxysilane C₈H₁₇Si(OC₂H₅)₃. The pitting potentials of the passivated electrodes bare and covered with the polymer film were determined by anodic polarization measurements in a borate buffer solution containing 0.1 M of Cl⁻. The pitting potential of the coated electrode was higher than that of the uncoated one, indicating prevention of passive film breakdown. No breakdown was observed over the potential range in the passive and transpassive regions by covering the passive film with the well-arranged two-dimensional polymer film. The film was characterized by X-ray photoelectron and FTIR reflection spectroscopies and measurement of the contact angle with a drop of water.     

活塞异型截面曲线数控加工中的一种逼近方法

针对发动机活塞截面曲线的非标准性，提出了采用最少的圆弧段逼近加工曲线的方法，详细地分析了用圆弧段逼近非标准随圆曲线的过程，并对逼近误差进行分析，满足加工拟合曲线的要求。此种方法计算简单，精度较高。     

An investigation of chloride-substituted Schiff bases as corrosion inhibitors for steel

Polarization and impedance measurements were performed on steel in deaerated 5% HCl solution with and without Schiff base additives within the concentration range 1 × 10⁻⁴–5 × 10⁻³ mol/dm³. The Schiff base compounds used were salicylaldimine, R, N-(2-chlorophenyl)salicyaldimine, 2Cl-R, N-(3-chlorophenyl)salicyaldimine, 3Cl-R, and N-(4-chlorophenyl)salicyaldimine, 4Cl-R. It was found that when the concentration of the inhibitors were increased the inhibitor efficiencies, η, also increased with increasing surface coverage. The results indicated that the ortho-substituted (2Cl-R) compound had the highest inhibition efficiency. All the Schiff base additives studied obeyed the Langmuir isotherm.     

Pitting corrosion behaviour of PM austenitic stainless steels sintered in nitrogen-hydrogen atmosphere

PM 304L and 316L stainless steel have been compacted at 400, 600 and 800 MPa and sintered in vacuum and in nitrogen-hydrogen atmosphere. Postsintered heat treatments (annealing solution and ageing at 375, 675 and 875 °C) have been applied. Pitting corrosion resistance has been studied using anodic polarization measurements and the ferric chloride test. Anodic polarization curves reveal that densities and atmospheres are relevant on anodic behaviour. Pitting resistance is higher for PM 316L and for higher densities and vacuum as sintered atmosphere. Ageing heat treatments at medium and high temperatures are detrimental to passivity although susceptibility to pitting corrosion barely changes. But heat treatments at 375 °C even show certain improvement in pitting corrosion resistance. The results were correlated to the presence of precipitates and mainly to the lamellar constituent which appears in some samples sintered in nitrogen-hydrogen atmosphere. The role of nitrogen on the samples sintered under nitrogen-hydrogen atmosphere and its relation to the microstructural features was described.     

直角密集台阶轧齐曲线

本文在分析具有密集性质的直角台阶轧齐问题中，提出里台阶轧齐曲线相对独立，外台阶轧齐曲线受里台阶影响，并形成某种叠加的基本设想。逐个分析了密集台阶存在的四种状态，推导出各种状态下每个台阶的轧齐曲线方程，并给出了各种状态的判别式及各方程的区间。文章最后以简图方式汇总了各种状态，并用例题归纳了计算步骤。     

石英砂热膨胀性的研究

以大林砂、围场砂、平潭砂等为研究对象,采用自制的铸造用砂热膨胀性测定仪,分别对不同产地的铸造用砂的随温热膨胀和等温热膨胀进行了测试,对其热膨胀特性进行了研究.结果发现,石英砂的膨胀以热膨胀为主,相变膨胀为辅.膨胀量受加热温度、砂子粒度以及SiO2含量的影响.经700 ℃热再生的石英砂的热膨胀性低于同类新砂.     

稀土对A572 Gr.65钢电化学腐蚀行为的影响

目的提高A572 Gr.65钢的耐蚀性能。方法通过向A572 Gr.65钢中添加La和Ce的混合稀土,得到不同稀土含量的A572 Gr.65钢。以3.5%NaCl溶液为腐蚀介质,借助电化学工作站、XRD和SEM等手段分析表征了不同稀土含量的A572 Gr.65钢的电化学腐蚀行为。结果稀土能使A572 Gr.65钢腐蚀电位正移,腐蚀电流减小。当稀土质量分数为0.0047%时,腐蚀电位最正,为-0.50V,腐蚀电流密度最小,为2.77×10-6 A/cm2,极化曲线的阳极部分存在明显的活化-钝化过渡区,有明显的钝化过程。不同稀土含量的A572Gr.65钢的阻抗谱均由单一的容抗弧组成,容抗弧半径代表着对电荷传输的阻碍能力,稀土质量分数为0.0047%时,容抗弧半径最大,对电荷传输的阻碍能力最大。稀土可以使钢中的夹杂物变性,使夹杂物由Ca S和Al2O3-Ca O变为稀土的氧硫化物,夹杂物尺寸由5μm变为2μm,减小腐蚀发生的活性区。此外,稀土离子可以提高阴极极化率,使腐蚀产物中不稳定的γ-Fe OOH含量减少,增强锈层的稳定性、致密性和附着能力,增大电荷转移的阻力,有效阻碍侵蚀性Cl-的侵入。结论稀土的添加能有效提高A572Gr.65钢的耐蚀性,稀土质量分数为0.0047%时,试验钢的耐蚀性最好。腐蚀过程中,由点蚀逐渐转变为均匀腐蚀,活性点的形成和阳极溶解速度为整个腐蚀过程中的限制性环节。