固相接枝聚丙烯的晶态结构和热行为

采用广角Ｘ射线衍射（ＷＡＸＤ）和差示扫描量热法（ＤＳＣ），研究固相接枝反应对聚丙烯晶态结构和热行为的影响。结果表明聚丙烯用马来酸酐固相接枝后，晶面间距基本不变，微晶尺寸增大，熔点降低，结晶度略有提高。     

聚丙烯反应釜控制系统

主要介绍了聚丙烯反应釜自动控制系统的软、硬件结构设计。着重阐述了此控制系统相应控制方案的实用性和可行性，给出了实现其控制方案的系统组态思想及相应的程序框图。并讨论了ＳＬＰＣ可编程调节器在分程控制系统中具体应用。     

改性聚丙烯纤维砼在隧洞衬护中的应用

聚丙烯纤维混凝土具有比普通挂网喷砼更独特的工程特性,用于替代传统的挂网喷砼对水工隧洞的衬护,具有施工简单方便,技术经济性能良好的优点.介绍了龙泉岩樟溪一级电站引水发电隧洞应用聚丙烯纤维砼衬护,取得了良好技术经济效果的成功经验.     

矿山物资供应管理信息系统的开发

针对我国矿山物资供应管理的状况和存在的问题进行了分析和探讨 ,并结合矿山现场工作的实际需求 ,采用可视化程序设计 ,开发了矿山物资供应管理信息系统 ,其开发模式对企业物资管理的动态决策具有普遍的借鉴和推广意义。     

塑编袋工艺参数的优选

本文采用方差分析原理，优选了生产塑料编袋的工艺参数，同时改变其原料配比，使塑编袋重量在确保产品质量的产提下有了明显降低，大幅度降低了生产成本。     

浅析聚丙烯粉料中晶点的生成与预防

结合小本体聚丙烯的生产，对聚丙烯粉料中存在的晶点按生成原因从晶点料，高温料和碎料等不同的情况进行了分析，并提出预防措施。     

Effects of polyoxyethylene nonylphenol on dynamic mechanical properties and crystallization of polypropylene

Polypropylene (PP) was blended with polyoxyethylene nonylphenol (PN) in a twin-screw extruder and injection moulded. The dynamic mechanical properties of PP/PN blends were characterized by dynamic mechanical analyser (DMA). The glass transition temperature (T_g) of PP showed a slight decrease with incorporation of PN. Differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD) and polarized optical microscopy (POM) were employed to investigate the effects of PN on crystallization of PP. In a study of nonisothermal crystallization of PP and PP/PN blends, crystallization parameter analysis showed the addition of PN reduced the peak temperature of crystallization. β-form crystals of PP coexisted with α-form crystals in PP/PN blends, and oriented on the surface layer of injection moulded bar as revealed by WAXD. The degree of orientation was determined using Hermans orientation function. The thermal stability of β-form crystals was evaluated using high temperature WAXD and POM.     

用于发泡成型的高熔体强度聚丙烯的研究

在同向双螺杆挤出机上,对聚丙烯(PP)进行硅烷交联,制得高熔体强度聚丙烯(HMSPP),然后制备高发泡倍率的PP制品。分析了改性剂用量对PP熔体流动速率、熔体黏度、熔体强度、凝胶含量、力学性能、热性能和发泡性能的影响。结果表明:自制HMSPP的熔体强度和熔体黏度分别是纯PP的5.01倍和1.52倍,力学性能和耐热性与纯PP相比均有较大提高,可用于成型高发泡倍率制品。     

Studies of the positron lifetime and Doppler-broadened annihilation radiation of polypropylene-polystyrene alloys

Positron annihilation lifetime spectroscopy and Doppler-broadened annihilation radiation (DBAR) experiments were performed on polypropylene-polystyrene (PP-PS) alloys (0-100% styrene) prepared by in situ polymerisation of styrene in a PP host matrix. The mean size of free-volume holes estimated from the ortho-positronium lifetime τ₃ shows a continuous decrease from 0.119 nm³ in PP to 0.095 nm³ in PS. The intensity of the o-Ps component, I₃, the average positron lifetime τ_av, the curve-shape parameter S and the peak height H of the DBAR spectra increase linearly with the styrene concentration. This is attributed to a linear superposition of the Ps yields of PP and PS in the PP-PS alloys. The DBAR spectra were fitted by a sum of three Gaussians, the narrowest of them is attributed to self-annihilation of para-positronium confined within holes. After its subtraction, a ‘broad component’ is obtained which represents the momentum distribution of electrons bound to molecules. Its normalised peak height does not show any change with the composition which reflects the fact that both constituents of the PP-PS alloys contain only hydrogen and carbon atoms in their chemical units. Immersing of PP into styrene liquid leads to a very pronounced increases in the lifetime parameters which is attributed to the plasticisation of PP.     

PPR管材专用料的结构与性能

采用核磁共振(NMR)、X衍射仪、差示扫描量热法(DSC)、凝胶渗透色谱(GPC)等分析技术对无规共聚聚丙烯(PPR)管材专用料的结构和性能进行研究,并且与国外料进行了对比。结果表明,PPR管材专用料具有典型的无规共聚物序列结构,PPE和PEP含量高,EEE含量低;乙烯较均匀地分布在共聚物链上,乙烯含量高的共聚物相对分子质量小,乙烯含量低的共聚物相对分子质量大,相对分子量分布宽;乙烯在丙烯聚合时无规插入,使无规共聚物结晶尺寸变小,结晶度、结晶速率和熔点均降低。使PPR管材专用料具有冲击韧性高、脆化温度低、化学稳定性强和优良的成型加工等宏观性能,其结构和性能指标与国外料相当。