Crosslinked acrylic pressure sensitive adhesives. 3. Effect of adherend on film formation

The reaction of isocyanate in pressure sensitive adhesive (PSA) films adhered on to various adherends having different surface tensions was monitored by depth profiling using attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy.In the latter stages of crosslinking reaction, unreacted isocyanate and its derivatives exist more in the bulk of the PSA than in the interfaces between PSA and adherends which are Teflon sheet and PE film having relatively lower surface tensions. In the case of using stainless steel having relatively higher surface tension as adherend, opposite segregation was observed compared to Teflon and PE.From X-ray photoelectron spectroscopy (XPS), it was revealed that N atoms exist more in surface than in bulk when stainless steel is used as adherend. We conclude that polyisocyanates migrate in the PSA film in order to minimize the magnitude of interfacial free energy between the PSA and the adherend, which leads to the change of surface tension of PSA film.     

HYSTERESIS OF GAS-LIQUID MASS TRANSFER IN A TRICKLE BED REACTOR

1 INTRODUCTIONTrickle bed reactors are widely used in the process industry,particularly in petroleumhydroprocessing operations,and have been extensively studied by chemical engineers.In atrickle bed reactor,the gas and liquid flow cocurrently down through the packed bedand undergo chemical reactions.However,there exist multiple hydrodynamic stateswhich correspond to either uniform or,in most cases,nonuniform radial distributionof the gas and liquid flows in the packed section.Moreover,the hydrodynamic state is     

薄壁压力容器筒体纵焊缝角变形对应力的影响

提出压力容器简体纵焊缝产生角变形的模型。用简明的解析方法和有限元方法,探讨由变形引起的应力集中系数K_(ta)。结果表明,利用应力集中系数估算焊缝棱角对应力的影响是较合实际的,其公式为:K_(ta)=1+6E/S,式中E为棱角度,S为筒体壁厚。     

椭圆形钢铅耗能器性能及振动台试验

针对工字型钢铅组合耗能器直角区域容易应力集中、过早屈服断裂退出工作的问题,提出一种由钢和铅两种材料组成的椭圆形钢铅耗能器,这种耗能器加工简便且水平两个方向都具有良好耗能性能.首先,对椭圆形钢铅耗能器中钢板的平面应力进行分析.其次,对椭圆形钢铅耗能器进行力学性能试验;利用有限元分析软件ANSYS建立椭圆形钢铅耗能器的非线性计算模型进行数值分析并与性能试验结果进行对比.最后,对一个安装和不安装椭圆形钢铅耗能器的六层钢框架结构模型进行振动台对比试验.研究结果表明:数值分析结果与性能试验结果吻合良好,本文建立椭圆形钢铅耗能器数值计算模型的方法正确;椭圆形钢铅耗能器滞回曲线饱满,具有良好耗能能力;椭圆形钢铅耗能器对多层结构的地震反应具有较好减震效果.     

液烃干燥器改造分析

通过对现有液烃干燥器排液,泄压操作运行状态研究分析,提出可行改造方案,优化液烃干燥器排放,泄压操作,达到液烃干燥器长周期运行,丙烯产品水含量合格,降低生产运行成本,节省能耗。     

A new design of foaming agent mixing device for a pneumatic foaming system used for mine dust suppression

To overcome the drawbacks of the conventional foam technology used for dust suppression,including large pressure loss,high water pressure and low driving pressure,a new pneumatic foaming system is introduced.Then an original design of foaming agent mixing device is proposed,and its performance is investigated and evaluated under different pressure compensations.Experimental results show that the maximum absorption amount increases by 2.9-6.7 times at a pressure compensation of 0.04-0.2 MPa compared with no pressure compensation.The pressure loss and pressure fluctuation both reduce significantly with increasing pressure compensation.The critical outlet pressure increases by30.4-240%.Field application indicates that the proposed mixing device ensures the reliable addition of foaming agent used for foam dust suppression.The effect of foam on dust suppression is remarkable,and the economic cost of foam is low.Therefore,there is reason to believe that the new mixing device will greatly promote foam technology to be widely used for suppressing dust in underground coal mines.     

天然气超深井井底压力计算与应用

钻井液喷空后的井底压力可以精确计算,为正确地保证井底压力大于或等于地层压力提供了科学的数据。钻井液喷空后的深井超深井的天然气井,关井后的静气柱压力不是很小。井内有钻井液(或修井液)井底进入天然气时,井底压力在合理地处理井内天然气在井内的运移(体积法放压法)与二次循环法压井循环出进入井内的天然气是相同的,为钻井井控现场为避免压裂套管鞋处或地层压力低的地层提供了可靠的依据。     

气体热载体干馏炉内压力降的研究

油页岩在气体热载体干馏炉内干馏过程中,由于块状堆料之间存在不同的空隙,导致气体在空隙中通过,由于阻力的作用,压力会产生损失,行成一定的压降。本研究采用散料层阻力损失计算公式和Ergun方程两种方法对干馏炉的压力降进行计算,并与实际压降进行比较,结果发现这两种方法所得理论值与实际值比较接近,而且变化趋势与实际值基本一致,利用Ergun方程更适用于工程运行。     

丝网编织金属橡胶的静态力学性能研究

针对沉孔型金属橡胶制品展开研究,采取了控制变量和对比分析的2种研究方法,对金属橡胶制品的静态压缩和剪切性能进行了系统全面的实验研究。通过实验结果给出了在不同结构参数下金属橡胶制品静态性能的变化关系,同时得到了金属橡胶制品在压缩过程中的线性-软特性-硬特性的变化过程。针对不同状态下的减振耗能情况对金属橡胶减振的机理进行深入的剖析,进而得知相对密度与变形幅值是影响金属橡胶减振器减振能力的2个重要参数。     

优化鼓冷工艺稳定焦炉炭化室压力

通过优化鼓风冷凝单元的工艺和操作等措施,稳定初冷器前煤气吸力和改善循环氨水质量等手段,保证7.63m焦炉炭化室PROven压力调节系统的正常运行,确保在结焦全过程炭化室内的压力基本保持恒定。