管道防腐层的失效及对策

介绍了管道防腐层失效的原因和方式。指出水和氧气是防腐层失效的原因,含水量和含氧量决定腐蚀程度,应采取有效措施对防腐层进行及时检查与修复。     

玻璃与金属封接用杜美丝

利用ＡＥＳ、ＷＤＳ和ｘ－射线衍射等方法，研究了杜美丝表面层、铁镍芯与覆铜层界面的微观结构与特性。结果表明：良好的表面层应由Ｃｕ２Ｏ和非晶态的硼砂构成；玻璃与杜美丝的润湿性决定于表面层的净化程度和构成及加热条件。     

船体水上防锈漆体系加速试验方法研究

根据船舶水线漆和船壳漆的使用环境和主要破坏因素，设计了一套以盐雾－人工加速老化（紫外光／冷凝）交替暴露和带人造缺陷样板的加速暴露试验方法为主，结合海水冲刷、附着力等主要力学性能测定的试验方案。对８种国内外船体水上部份防锈漆体系的性能进行综合评定，其结果采用数字量化评分。试验结果表明，该试验方法可在相当短的时间内对各类船体水上防锈漆体系的综合性能作出正确的评定。     

Optimisation of metallic pigments in coatings by an electrochemical technique and an investigation of manganese powder as pigment for metal rich primers

Zinc dust and manganese powder as pigments were incorporated in epoxy-polyamide and butyl titanate medium, with different pigment volume concentration (PVC) ranging from 20 to 74. These protective coatings were coated on sand blasted mild steel substrates and immersed in 3 wt.% sodium chloride solution and the corrosion current was measured by the Tafel extrapolation method. From the corrosion current produced by these primers, the optimum level of the pigments in these binders was identified. Thus the protective performance of optimised primers was evaluated on a sand blasted mild steel surface by the Tafel polarisation method in 3 wt.% sodium chloride solution, over different periods of time. The results were found to be comparable with the salt spray test and galvanic current measurements. The manganese powder used for this investigation showed that it could be used as an alternative to zinc powder for metal rich primers.     

提高涂层防腐性能评价技术的探讨

界面防腐技术是油气田三维大跨度的大型结构群体综合防护治理的主要方法之一，但我国现行的涂层检测方法还存在较大的局限性和失真度，不能反映实际工况下涂层的防护质量。文章指出了我国涂层与防护质量评价技术的现状和与国外的差距，介绍了80年代以来国外在涂层质量评价方面采用的一些新技术和先进的综合评价方法，最后提出了采用表面分析技术和电化学方法相结合的评价技术，以及对现行评价方法的再创造等建议。     

LASER CLADDED TiCN COATINGS ON THE SURFACE OF TTTANIUM

Laser cladded coatings of TiCN were produced on the surface of titanium. To obtain the optimal techniques, several conditions were tested by varying the laser scanning rate. The choice of shielding gas was also studied. The cladded coatings were then evaluated from the surface mechanics point of view based on their microhardness. The microstructure of some interesting samples was investigated by optical micrographs （OM）. The results showed that under the condition of fixed pulse frequency and pulse width, the laser scanning rate and the shielding gas are the main factors influencing the components of coatings. TiCN coatings were decompounded and oxidized during the cladding process in the condition of no shielding gas of N2. X-ray diffraction results indicated that the composite coatings composed of TiCN, TiC, Ti2N, and TiO2 were produced using appropriate techniques. The results indicated that the best condition in terms of the surface microhardness is obtained when the scanning rate is 1.5mm/s, the pulse frequency is 15Hz, the pulse width is 3.0ms, and N2 is chosen as the shielding gas. The microhardness of the composite coatings is about 1331kg · mm^-2, which is about 4 times that of the substrate. The optical micrographs indicated that the cladding zone is made up of TiCN, TiO2 and some interdendritic Ti, but the diffusion zone mainly consists of the dendrites phase, and the cladded depth is about 80μm, which is more than 2 times that of the laser nitrided sample. There were no microcracks or air bubbles in the cladded sample, which was cladded using the above optimal techniques.     

化学镀Ni-P-PTFE复合镀层的性能

本文对化学镀ＮｉＰＰＴＦＥ复合镀层的性能作了测定和评价。实验表明，用优化的镀液配方和工艺可获得含ＰＴＦＥ粒子２５～３０％ｖｏｌ的ＮｉＰＰＴＦＥ复合镀层。这种镀层具有优良的结合力和良好的耐蚀性，其硬度随ＰＴＦＥ含量增加而降低，其特别突出的性能是优异的减摩性和耐磨性，是一种具有自润滑功能的表面复合材料。     

Investigation of the stability of tablets prepared from sucrose and citric acid anhydride utilizing response surface methodology

Inversion of sucrose is a stability problem particularly of candies with acidic taste that contain sucrose and small amounts of organic acids such as citric acid, since the free d-fructose produced by hydrolysis is hygroscopic. The following possibilities were investigated for preventing the hydrolysis of sucrose in tablets containing sucrose and citric acid: Adding various amounts of tri-sodium citrate to the formulation to neutralize the citric acid, (Hot) melt coating of citric acid and tri-sodium citrate with a vegetable fat at different coating ratios, variation of the ratio of coated citric acid and tri-sodium citrate in formulations, and compressing the formulations with different compression forces. After tablet processing and storage of tablets, the concentration of d-fructose was determined on the basis of enzymatic reactions. A response surface central composite design was used. The above-mentioned variations were chosen as independent variables and the amount of d-fructose was chosen as response variable. The lowest rates of inversion could be achieved by increasing the content of tri-sodium citrate and the ratio of coating material and decreasing the ratio of coated citric acid and tri-sodium citrate in the tablet formulations. The compression force had no significant effect on the inversion of sucrose.     

转炉冶炼20管坯钢生产实践

介绍了20#管坯钢的生产试验工艺，采取了拉碳法脱碳、钢包底吹氩及喂丝、保护浇铸、合理控制拉速等有效措施，解决了生产中存在的质量问题，为下一步的生产提供了理论和实践依据。