超强吸水性树脂的制备及吸水性能研究

合成了以丙三醇为交联剂的聚丙烯酸类高分子吸水剂,讨论了丙三醇作交联剂时,引发剂用量、 交联剂用量、中和度、反应温度及时间对树脂吸水能力的影响。所制树脂吸水率达800g/g。对0.9％食盐水吸水 率最大为70g/g。     

Preparation of zinc ferrite in the presence of carbon material and its application to hot-gas cleaning

In order to develop an efficient absorbent of H₂S in coal gasification, zinc ferrite (ZnFe₂O₄) was prepared in the presence of carbon materials such as activated carbon (AC), activated carbon fiber (ACF), and Yallourn coal (YL). The absorption behavior of absorbents for H₂S was examined using a fixed-bed flow type reactor equipped with a quadrupole mass spectrometer.Carbon material-supported ZnFe₂O₄ exhibited larger desulfurization capacity for H₂S than unsupported ferrites. They could efficiently remove H₂S from 4000 ppm levels in a simulated coal gasification gas to less than 1 ppm at 500 °C. The absorption capacity of H₂S with ZnFe₂O₄/AC, ZnFe₂O₄/ACF, and ZnFe₂O₄/YL exhibited nearly 100% of stoichiometric amount of loaded metal species. They could be regenerated by an air oxidation in O₂-Ar (50 vol%) at 450 °C for 30 min. The regenerated ferrite can be used for repeated absorption of H₂S with a very slight decrease in the absorption capacity.     

雷达吸波材料的研究现状及发展前景

首先阐述了吸波材料的研究意义,然后综合讨论了吸波材料的工作原理、类型以及研究现状, 最后介绍了吸波材料在军事方面的应用及未来的发展趋势。     

接枝淀粉共聚物的合成与应用

介绍了接枝淀粉共聚物的合成方法及应用领域，回顾了我国近年来在该领域所取得的可喜进展。     

改善高吸水树脂性能的主要技术方案

文章介绍了盐的存在对高吸水树脂吸水性能的影响，重点论述了提高高吸水树脂耐盐性、吸水速度和吸水后水凝胶强度的技术方案。     

Oil absorbents based on styrene–butadiene rubber

Four oil absorbents based on styrene–butadiene (SBR)—pure SBR (PS), 4‐tert‐butylstyrene–SBR (PBS), EPDM–SBR network (PES), and 4‐tert‐butylstyrene‐EPDM‐SBR (PBES)—were produced from crosslinking polymerization of uncured styrene–butadiene rubber (SBR), 4‐tert‐butylstyrene (tBS), and ethylene–propylene–diene terpolymer (EPDM). The reaction took place in toluene using benzoyl peroxide (BPO) as an initiator. Uncured SBR was used as both a prepolymer and a crosslink agent in this work, and the crosslinked polymer was identified by IR spectroscopy. The oil absorbency of the crosslinked polymer was evaluated with ASTM method F726‐81. The order of maximum oil absorbency was PBES > PBS > PES > PS. The maximum values of oil absorbency of PBES and PBS were 74.0 and 69.5 g/g, respectively. Gel fractions and swelling kinetic constants, however, had opposite sequences. The swelling kinetic constant of PS evaluated by an experimental equation was 49.97 × 10^?2 h^?1. The gel strength parameter, S, the relaxation exponent, n, and the fractal dimension, d_f, of the crosslinked polymer at the pseudo‐critical gel state were determined from oscillatory shear measurements by a dynamic rheometer. The morphologies and light resistance properties of the crosslinked polymers were observed, respectively, with a scanning electron microscope (SEM) and a color difference meter.     

利用玉米秸秆制备高吸水树脂

将玉米秸秆预处理后与丙烯酸接枝共聚制备高吸水性树脂,采用单因素实验确定了合成条件中各因素的最佳水平:θ=45℃,引发剂中过硫酸钾用量为单体质量的0.8%,交联剂N,N-亚甲基双丙烯酰胺(MBAM)用量为单体质量的0.6%,m(AA)∶m(玉米秸秆)=8∶1,丙烯酸中和度为70%,t=4 h。对最佳条件下制备的树脂进行了性能测试,对秸秆预处理前后及产物进行了扫描电镜分析。结果表明,该树脂具有良好的吸水、保水性能,吸水率最高达到291 g.g-1,吸盐水率达到49 g.g-1。     

基于SKO—KPCA和SVM的雷达目标HRRP特征提取与识别

将依赖数据变化的自适应SKO技术和迭代算法引入KPCA算法中,结合SVM分类技术,提出了基于SKO—IKPCA和SVM的雷达目标HRRP特征提取与识别方法。讨论了HRRP预处理、迭代KPCA算法和SKO／FKO技术的实现方法,将SKO／FKO技术应用到KPCA的核优化中,并用人工合成数据对其优化性能进行了测试与比较,应用该方法对su-27、F-16及M2000等三类飞机目标的实测HRRP数据进行了特征提取与识别实验。结果表明,所提方法具有较好的稳定性和可靠性,能有效地优化雷达目标主元特征的提取,提高目标的识别性能。     

吸收对准相位匹配线性电光效应的影响(英文)

研究吸收对准相位匹配线性电光效应的影响,得到适用于吸收介质的准相位匹配线性电光效应的耦合波方程及其解析解.计算结果表明,吸收不但削弱光的强度,且影响o光与e光之间的电光耦合.当o光与e光的吸收系数不同时,由于它们之间的电光耦合,总输出光强随外加电场变化而变化.研究结果可用于吸收介质的电光器件设计.