Carbon Free and Noble Metal Free Ni2Mo6S8 Electrocatalyst for Selective Electrosynthesis of H2O2

Electrocatalytic two-electron reduction of oxygen is a promising method for producing sustainable H₂O₂ but lacks low-cost and selective electrocatalysts. Here, the Chevrel phase chalcogenide Ni₂Mo₆S₈ is presented as a novel active motif for reducing oxygen to H₂O₂ in an aqueous electrolyte. Although it has a low surface area, the Ni₂Mo₆S₈ catalyst exhibits exceptional activity for H₂O₂ synthesis with >90% H₂O₂ molar selectivity across a wide potential range. Chemical titration verified successful generation of H₂O₂ and confirmed rates as high as 90 mmol H₂O₂ g_cat⁻¹ h⁻¹. The outstanding activities are attributed to the ligand and ensemble effects of Ni that promote H₂O dissociation and proton-coupled reduction of O₂ to HOO*, and the spatial effect of the Chevrel phase structure that isolates Ni active sites to inhibit O O cleavage. The synergy of these effects delivers fast and selective production of H₂O₂ with high turn-over frequencies of ≈30 s⁻¹. In addition, the Ni₂Mo₆S₈ catalyst has a stable crystal structure that is resistive for oxidation and delivers good catalyst stability for continuous H₂O₂ production. The described Ni-Mo₆S₈ active motif can unlock new opportunities for designing Earth-abundant electrocatalysts to tune oxygen reduction for practical H₂O₂ production.     

新型稀土6063铝材热加工性能研究

采用高温拉伸、高温压缩试验方法,对新型稀土6063铝合金半连续铸造锭坯材进行热变形加工性能研究。通过拉伸变形抗力、伸长率、压缩变形量、冲击速度的测量比较,以及两类试验试样的形貌、形态观察对比,确定新型稀土6063铝合金半连续铸造锭坯材最佳热挤压加工温度区间为450~480℃;实施大变形、高速挤压与在线连续淬火工艺,最佳热挤压温度区间应控制在430~480℃。     

硫化锌薄膜的微结构剖析

用Ｘ射线衍射和Ｘ射线光电子能谱技术,对分舟热蒸发法研制的掺铒（Ｅｒ）硫化锌直流电致发光薄膜及硫化锌粉料进行剖析,获得薄膜表面及粉料的构态信息,讨论了影响微晶薄膜质量的主要因素。     

锡铅稀土钎料合金高温蠕变性能试验研究

文中对比分析了Ｓｎ６０Ｐｂ４０和Ｓｎ－Ｐｂ－０．０５Ｒｅ两种钎料合金在多轴应力状态下的蠕变断裂规律,初步探讨了主控两种钎料复合金为断裂的力学因素,并从金属学角度初步探讨了两种钎料合金的蠕变断裂方式,着重分析了混合稀土对锡铅秆料合金蠕变性能的影响。     

Transport and interface states in high-κ LaSiOx dielectric

The paper presents the results of capacitance-voltage, conductance-frequency and current-voltage characterization in the wide temperature range (140-300 K) as well as results of low temperature (5-20 K) thermally stimulated currents (TSC) measurements of metal-oxide-semiconductor (MOS) structures with a high-κ LaSiO_x dielectric deposited on p- and n-type Si(1 0 0) substrate. Interface states (D_it) distribution determined by several techniques show consistent result and demonstrates the adequacy of techniques used. Typical maxima of interface states density were found as 4.6 × 10¹¹ eV⁻¹cm⁻² at 0.2 eV and 7.9 × 10¹¹ eV⁻¹cm⁻² at 0.77 eV from the silicon valence band. The result of admittance spectroscopy showed the presence of local states in bandgap with activation energy E_a = 0.38 eV from silicon conductance band, which is in accord with interface states profile acquired by conductance method. Low-temperature TSC spectra show the presence of shallow traps at the interface with activation energies ranging from 15 to 32 meV. The charge carrier transport through the dielectric film was found to occur via Poole-Frenkel mechanism at forward bias.     

稀土元素对铂的室温强度和电阻率之影响

添加微量稀土元素使纯Pt的再结晶温度提高200～300℃,硬度和抗拉强度增高2～3倍。含重稀土铂合金的强度一般高于轻稀土铂合金。Eu和Yb与Pt组成的合金的强度很高。微量稀土元素使铂的电阻率增加很少,当含量增加到1wt%时,电阻率明显升高,而硬度和抗拉强度反而降低。     

Microstructural modifications and properties of Sn-Ag-Cu solder joints induced by alloying

Slow cooling (1–3°C/sec) of Sn-Ag-Cu and Sn-Ag-Cu-X (X = Fe, Co) solder-joint specimens, made by hand soldering, simulated reflow in a surface-mount assembly to achieve similar as-solidified joint microstructures for realistic shear-strength testing, using Sn-3.5Ag (wt.%) as a baseline. Consistent with predictions from a recent Sn-Ag-Cu ternary phase-diagram study, either Sn dendrites, Ag₃Sn primary phase, or Cu₆Sn₅ primary phase were formed during solidification of joint samples made from the selected near-eutectic Sn-Ag-Cu alloys. Minor substitution of Co for Cu in Sn-3.7Ag-0.9Cu refined the joint-matrix microstructure by an apparent catalysis effect on the Cu₆Sn₅ phase, whereas Fe substitution promoted extreme refinement of the Sn-dendritic phase. Ambient-temperature shear strength was reduced by Sn dendrites in the joint microstructure, especially coarse dendrites in solute poor Sn-Ag-Cu, e.g., Sn-3.0Ag-0.5Cu, while Sn-3.7Ag-0.9Cu with Co and Fe additions have increased shear strength. At elevated (150°C) temperature, no significant difference exists between the maximum shear-strength values of all of the alloys studied.     

掺杂Sc和Sb的Mg2Si基热电材料的电性能研究

采用机械合金化-电场激活压力辅助合成(MA-FAPAS)技术,快速合成Sc,Sb掺杂的Mg2Si基热电材料,并对其进行电性能的测试与分析。结果表明:掺杂摩尔分数为0.47%Sb的Mg2Si试样在测试温度范围内,电导率和Seebeck系数均优于未掺杂试样,其平均电功率因子约为后者的2.2～2.3倍;电导率比采用熔融-热压法制备的同类试样有所提高;在低温阶段,掺杂摩尔分数为0.43%Sc的Mg2Si试样Seebeck系数约为307 K,达未掺杂试样的2.03倍;电功率因子在温度低于550 K时高于未掺杂试样,最大值与Sb掺杂试样相当。     

不同品种异戊橡胶的性能对比

对不同品种的异戊橡胶(IR)进行性能对比。结果表明:各种IR胶料的物理性能基本相当,中国石化北京化工研究院燕山分院钛系IR(YS-TiIR)的动态力学性能更为均衡;YS-TiIR以一定比例等量替代天然橡胶(NR)用于载重轮胎胎面胶,胶料的综合性能与俄罗斯SKI-3等量替代NR胎面胶基本相当,其中以30份Ti-IR等量替代NR后,胶料的加工性能和物理性能变化最小。     

YF3:Eu3+的水热合成和发光性质

采用水热法合成了Eu3+单掺YF3荧光粉.分析了样品的结构与形貌,结果表明,所合成的样品为单相,颗粒粒度分布均匀.测定了YF3:Eu3+的激发和发射光谱,结果显示,激发光谱峰值分别为320,365,386,397,418和467 nm,激发主峰峰值位于397 nm;发射光谱由位于591 nm(5D0→F1)和612 n...