粉尘含碳球团还原方式及气氛对其还原挥发性能的影响

在1150℃和1250℃、0．1L／min和10L／min的气量下，对通人含不同CO2量的氮气影响粉尘含碳球团还原速度的实验研究表明：以滚动方式所造球团中，氧化物的还原完全以间接还原的方式进行，气氛中非还原气体流速（或流量）的增加对粉尘含碳球团氧化铁还原速度有显著的降低作用，但还原温度提高则对气量增加造成的氧化铁还原速度降低有显著的抵消作用．气氛对球团中锌的挥发速度影响很小，对铅的挥发速度几乎不产生影响．     

基于改进差别矩阵和专家知识的态势指标提取算法

针对常规粗糙集约简算法在应用中的样本指标提取困难和效率低下等问题,将粗糙集理论引入到态势指标提取中,基于差别矩阵压缩和分类选择实现态势指标决策表的信息约简,结合专家知识的指标重要性度量调整态势指标的选择,提出一种基于改进差别矩阵和专家知识的态势指标提取算法.在态势指标体系实例中进行分析和验证,实验表明该算法具有较好的态势指标约简效果,提取后的指标在网络安全评估中是合理的,因此该研究为态势指标的有效提取提供一种可行的解决途径.     

Reduction of NO by H2 on PdO-MoO3/γ-Al2O3 of low molybdena loading

The catalytic activity and selectivity of three PdO-MoO₃/-Al₂O₃ catalysts containing about 2% Pd and 2% Mo were studied for the reduction of NO by h₂ in the presence of varying amounts of oxygen at temperatures from 50 to 550 °C. The results are compared with those for PdO/-Al₂O₃, PdO-MoO₃/-Al₂O₃ containing 2% Pd and 20% Mo, and a commercial Pt-Rh catalyst. In the absence of oxygen, the conversion of NO to N₂ and N₂O is higher on the three catalysts than it is on PdO/-Al₂O₃ at 500 and 550 °C. In the presence of oxygen, the yields of N₂ and N₂O are generally lower on two of the PdO-MoO₃/-Al₂O₃ catalysts than on PdO/-Al₂O₃.     

Photocatalytic decoloration of water-soluble azo dyes by reduction based on bisulfite-mediated borohydride

Investigation of the photocatalytic decoloration of nine water-soluble anionic azo dyes widely used for the coloration of textiles was conducted in a photoreactor by a selected reduction based on bisulfite-mediated borohydride. The influence of the irradiation power on their decoloration was discussed in this work. The decoloration processes of two typical azo dyes, Reactive Red MS and C.I. Direct Blue 15 were examined with UV–vis measurement and their decoloration kinetics was also investigated. Moreover, identification of benzidine compounds released from the photoreduction of four direct dyestuffs was undertaken. The results indicated that the reduction of the dyes was significantly enhanced under the increasing irradiation. It was found that the overall degradation followed pseudo-first-order kinetics and two distinct stages were observed in the decoloration processes of Reactive Red MS and C.I. Direct Blue 15. The decay rates at first stage were slightly changed, but the decay rates at second stage were significantly affected by the light intensity. In addition, UV–vis spectra showed that the azo linkages in molecule structure of the dyes were destroyed during the decoloration. Finally, dimethoxyl benzidine or benzidine produced from the photoreduction of four direct dyes was identified as the decoloration products through a rapid spectrophotometric method.     

天然肉桂油臭氧化制取苯甲醛

利用天然肉桂油中富含的肉桂醛，经过臭氧化反应和还原反应制得了苯甲醛。由该法制得的苯甲醛在国际上可作为天然苯甲醛使用。     

Transformations of sulphur compounds in high-sulphur coals during reduction in the potassium/liquid ammonia system

The two types of high-sulphur coals Mequinenza and Illinois No. 6, in the initial form and subjected to potassium/liquid ammonia reduction, were analysed by atmospheric pressure-temperature programmed reduction (AP-TPR) method. It has been shown that preliminary demineralisation was beneficial for AP-TPR measurements because of the removal of calcium compounds. The reduction of sulphides and disulphides in the potassium/liquid ammonia system was found to lead to formation of aromatic and aliphatic thiols. The presence of the latter is better manifested in the AP-TPR kinetograms when the measurements are performed in the presence of a special reducing mixture. It has been shown that the coal reduction in the potassium/liquid ammonia system apart from transformations of non-thiophene sulphur groups also leads to breaking up of the C-S bonds in some thiophene systems.     

冶金过程对齿轮钢窄淬透性的影响与控制

采用电炉炼钢短流程生产20CrMnTiH工艺,对影响淬透性的冶金因素进行分析,发现工艺过程对化学成份控制精度的影响因素并进行研究优化,建立电炉短流程生产齿轮钢20CrMnTiH子钢号工艺模型,加强从加料到精炼全过程控制,确保产品成份。     

误差对无侧隙双滚子包络环面蜗杆传动啮合性能的影响研究

为了研究误差对无侧隙双滚子包络环面蜗杆传动啮合性能的影响规律,利用齿轮啮合原理首次建立了该蜗杆传动在误差状态下的啮合方程、润滑角方程和诱导法曲率方程,分析了蜗杆蜗轮轴交角误差、中心距误差、蜗杆轴向窜动误差、蜗轮滚子齿距角误差、蜗轮滚子偏距安装误差等对蜗杆润滑角、诱导法曲率的影响及变化规律。研究结果表明:蜗轮滚子偏距误差对蜗杆的润滑性能影响最大,轴交角误差对蜗杆接触性能影响最大,蜗杆中心距误差、蜗杆轴向窜动误差和蜗轮滚子齿距角误差对该蜗杆传动的接触性能影响较小,在制定加工工艺时应尽量减小齿距角误差和蜗杆蜗轮轴交角误差。本文的研究结果为制定合适的蜗杆加工工艺及进一步的相关研究奠定了理论基础。     

FCM聚类算法的改进

模糊C均值（FCM）算法广泛地应用于模式识别、图像分割等领域。根据FCM算法存在对初始解敏感且迭代过程中计算量大的问题,本文提出了一种改进的算法：先通过精简数据集,减少算法迭代的时间;再使用密度函数法得到FCM算法的初始聚类中心,以减少FCM算法收敛所需的迭代次数。实验结果表明,改进后的算法较好地解决了类中心的初值化问题,提高了算法的收敛速度和运行效率。     

驱动内置式高功率密度舰船舵机

针对目前传统舵机占据舱室空间大、隐蔽性差等问题,探讨了一种将驱动机构置于舵柄内的高功率密度舰船舵机.在对其结构分析的基础上,探讨了高功率密度舵机的工作原理、在舰船上的安装布置、主作用力的传递路线;从理论上分析了各设计参数对舵机转舵性能的影响;应用Hertz理论,建立了多参数对舵机滚珠传动副性能的影响模型,为高功率密度舵机的结构优化设计、性能改进提供了理论基础.通过和现有其他力矩放大传动装置传递功率能力比较,以及样机试验结果表明,驱动机构位于舵柄内的高功率密度舰船舵机满足现代船舶操纵系统对高性能舵机的要求,具有结构紧凑、功率密度大、材料利用率高、响应快、动态性能好等优点.