全文获取类型
收费全文 | 338篇 |
免费 | 21篇 |
国内免费 | 5篇 |
专业分类
综合类 | 7篇 |
化学工业 | 239篇 |
金属工艺 | 7篇 |
机械仪表 | 5篇 |
能源动力 | 7篇 |
轻工业 | 12篇 |
石油天然气 | 3篇 |
武器工业 | 1篇 |
无线电 | 4篇 |
一般工业技术 | 61篇 |
冶金工业 | 5篇 |
原子能技术 | 13篇 |
出版年
2024年 | 1篇 |
2023年 | 7篇 |
2022年 | 5篇 |
2021年 | 10篇 |
2020年 | 8篇 |
2019年 | 10篇 |
2018年 | 11篇 |
2017年 | 6篇 |
2016年 | 9篇 |
2015年 | 13篇 |
2014年 | 14篇 |
2013年 | 28篇 |
2012年 | 25篇 |
2011年 | 17篇 |
2010年 | 20篇 |
2009年 | 29篇 |
2008年 | 15篇 |
2007年 | 19篇 |
2006年 | 21篇 |
2005年 | 19篇 |
2004年 | 12篇 |
2003年 | 12篇 |
2002年 | 9篇 |
2001年 | 7篇 |
2000年 | 6篇 |
1999年 | 6篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1996年 | 4篇 |
1995年 | 4篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1989年 | 2篇 |
排序方式: 共有364条查询结果,搜索用时 15 毫秒
41.
采用一缩二乙二醇(DEG)修饰丙醇锆(Zr(OPr)4)的水解-缩聚过程,在乙醇(EtOH)介质中制备ZrO2基溶胶;借助小角X射线散射和激光动态光散射研究胶体微观结构对合成体系组成的依赖性。结果表明,DEG分子可以通过其端羟基与Zr(OPr)4发生亲核取代而形成稳定的配合中间体,有效抑制Zr(OPr)4的水解-缩聚过程,从而在很宽的组成范围内获得稳定的ZrO2基溶胶。此外,在稳定溶胶对应的组成范围内,随DEG引入量减少或反应H2O量增加,胶体粒子数量增大并形成团簇。受胶粒表面未水解的DEG配体残留的影响,胶粒之间通过表面羟基缩合迅速长大的几率很小。 相似文献
42.
Ag nanoparticles were synthesized in the interlamellar space of a layered kaolinite. Disaggregation of the lamellae of the nonswelling kaolinite was achieved by the intercalation of dimethyl sulfoxide (DMSO). The kaolinite was suspended in aqueous AgNO3 solution and the adsorbed Ag+ ions were reduced on the surface of kaolinite lamellae with NaBH4 or UV light irradiation. The silver nanoparticles formed were characterized by X-ray diffraction (XRD), small angle X-ray scattering (SAXS), and transmission electron microscopy (TEM). We studied the effects of the two reduction methods on the size and the size distribution of Ag nanoparticles and how clay mineral structure is altered as a consequence of particle formation. It was established that the size of Ag nanoparticles depends on both silver content and the reduction method. Photoreduction of silver led to the formation of relatively large Ag nanoparticles (diameter 8–14 nm). 相似文献
43.
Structural Evolution of UHMWPE Fibers during Prestretching Far and Near Melting Temperature: An In Situ Synchrotron Radiation Small‐ and Wide‐Angle X‐Ray Scattering Study 下载免费PDF全文
Combining a homemade extension apparatus and the in situ synchrotron radiation small‐ and wide‐angle X‐ray scattering methods for measurement, the structural evolutions of gel‐spun ultrahigh molecular weight polyethylene (UHMWPE) fibers during prestretching at temperatures of 25 and 100 °C are investigated, respectively. Lamellar rotation toward the stretching direction occurs before strain hardening, while the folded‐chain crystal destruction and extended‐chain fibril formation processes occur in the strain hardening zone at 25 °C. While at 100 °C, stretching induced crystal melting before the stress plateau region and formation of fibrous crystals at the onset of the stress plateau are observed. Further stretching results in shear displacement of crystal blocks and, finally, destruction of the folded‐chain crystals and formation of extended‐chain fibrils. Prestretching UHMWPE fibers at 100 °C within a certain strain range can produce highly oriented fibrous crystals, which may provide an ideal precursor structure for the poststretching process. 相似文献
44.
《核技术(英文版)》2016,(5):1-5
X-ray scattering is widely used in material structural characterizations.The weak scattering nature,however,makes it susceptible to background noise and can consequently render the final results unreliable.In this paper,we report an iterative method to determine X-ray scattering background and demonstrate its feasibility by small angle X-ray scattering on gold nanoparticles.This method solely relies on the correct structural modeling of the sample to separate scattering signal from background in data fitting processes,which allows them to be immune from experimental uncertainties.The importance of accurate determination of the scaling factor for background subtraction is also illustrated. 相似文献
45.
Rangaswamy Subramanian Sosaku Ichikawa Mitsutoshi Nakajima Toshinori Kimura Takaaki Maekawa 《European Journal of Lipid Science and Technology》2001,103(2):93-97
Studies were conducted to determine the critical micelle concentration (CMC) of phospholipids in vegetable oils and the size of reverse micelles to understand their rejection phenomenon in the membrane process. The CMC values of phosphatidylcholine (PC) in triolein and phospholipids in crude soybean oil were determined to be 440 and 1020 mg/kg, respectively, by using TCNQ (7,7,8,8‐tetracyano‐quinodimethane) solubilization technique. The surface tension measurements of these samples gave similar values of CMC. From small‐angle X‐ray scattering (SAXS) analysis, the size of the PC micelles was determined to be in the range of 3.56 to 4.70 nm. The characterization of reverse micelles formed in the oil system was found useful in enhancing the understanding of the possible rejection phenomenon of phospholipids by non‐porous polymeric composite membranes used in our earlier studies on vegetable oils and in suggesting suitable types of membranes for the same. 相似文献
46.
Segment and domain orientation behaviors of a series of poly(butylene succinate) (PBS) –poly(tetramethylene glycol) (PTMG) segmented block copolymers containing different amounts of hard segment were studied with synchrotron small‐angle X‐ray scattering (SAXS) and infrared dichroic methods. Copolymers used in this work consist of PBS as a hard segment, and poly(tetramethylene oxide) (PTMO) of molecular weight 2000g/mol as a soft segment. As hard‐segment content increased, phase‐separated morphology changed from a phase of continuous soft matrix containing isolated hard domain to one of continuous hard matrix. Upon stretching, domains responded differently depending on their initial orientation. Based on SAXS results, two major domain deformation modes, that is, lamellar separation and shear compression, were suggested. The orientation behavior of the hard and soft segments was examined with infrared dichroic method. Upon drawing, the orientation function of the crystalline hard segment decreased at low‐draw ratios. It was interpreted in terms of rotation of long axis of hard domain along the stretching direction. The lowest value of the orientation function of PBS30 was approximately −0.5, that is, theoretical minimum. This result seems to indicate that for PBS30 containing about 30% hard segment, rotation of hard domain occurs without appreciable interdomain interaction, which is consistent with the morphological model suggested on the basis of SAXS results. Plastic deformation of the hard domain due to domain breakup was found to occur at low‐draw ratios for the sample containing higher hard‐segment content. Domain mechanical stability was tested by drawing a sample up to three different maximum draw ratios. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 699–709, 2000 相似文献
47.
The fibrillar and the lamellar structures in a range of poly(ethylene terephthalate) fibers were studied by small-angle X-ray scattering. The intensity maxima in the lamellar peaks lie on a curve that can be described as an ellipse. Therefore, the two-dimensional images were analyzed in elliptical coordinates. The dimensions of the coherently diffracting lamellar stack, the dimensions of the fibrils, the interfibrillar spacing, and the orientation of the lamellar surfaces were measured in addition to the lamellar spacing. The orientation of the lamellar planes and the size of the lamellar stacks had a better correlation with mechanical properties of the fibers than did the lamellar spacing. In particular, longer and wider lamellar stacks reduced fiber shrinkage, as did the closer alignment of the lamellar normal to the fiber axis. These structural features were also associated with lower tenacity. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 70: 2527–2538, 1998 相似文献
48.
Markus Antonietti Hans‐Peter Hentze Bernd Smarsly Matthias Lffler Roman Morschhuser 《大分子材料与工程》2002,287(3):195-202
The aggregation behavior of the hydrophobically modified polyelectrolytes which act in the interplay with special surfactant mixtures as a thickener is examined by replication of the different soft matter nanostructures into silica gels. The inorganic solidified replicas can be easily microtomed and analyzed by gas sorption measurements, quantitative small angle X‐ray scattering and transmission electron microscopy. The bare hydrophobically modified polyelectrolytes show a very homogeneous structure, free of larger aggregated moieties. In addition, a transition between a weakly‐ or unaggregated structure and an aggregated structure of the bare copolymer with hydrophobic moieties of ca. 3 nm diameter was found which depends on the degree of hydrophobic substitution, the concentration, and the salt content. The simultaneous presence of surfactant in the polymer solution leads to nanocasting of both spherical (ionic surfactant) and worm‐like (zwitterionic surfactant) micelles, which are essentially unperturbed by the incorporate the hydrophobic moieties of the polymer. Optimal thickening efficiency is obtained when each of those micelles is coupled to at least two of the polymers. The resulting sterical demands are best met by the presence of worm‐like surfactant micelles. 相似文献
49.
Aleksandra Turkovi? Pavo Dub?ekMario Raki? Martin Lon?ari?Bo?idar Etlinger Sigrid Bernstorff 《Vacuum》2012,86(6):750-753
Nanostructured polymer electrolytes are very attractive materials for components of batteries and opto-electronic devices. (PEO)8ZnCl2 polymer electrolytes and nanocomposites were prepared using Poly(ethylene oxide) (PEO) γ-irradiated with a selected dose of 529 kGy and with an addition of 10% of TiO2 nanograins. The influence of the added nanosize TiO2 grains on the polymer electrolytes and the effect of the γ-radiation from a Co-60 source were studied by small-angle X-ray scattering (SAXS) simultaneously recorded with differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD) at the synchrotron ELETTRA. Infrared (IR) and impedance spectroscopy (IS) were also performed [1]. It was shown by previously performed IS that the room temperature conductivity of the nanocomposite polymer electrolyte increased more than two times above 65 °C, relative to pure composites of PEO and salts. We observed all changes between 20 °C and 100 °C for treated and as prepared polymer electrolyte in the SAXS, DSC and WAXD spectra and especially during the phase transition to the super-ionic phase at 65 °C [2] and [3]. The SAXS/DSC measurements yielded insight into the temperature-dependent changes of the grains of the electrolyte as well as into the differences due to different heating and cooling rates. The crystal structure and the melting and crystallization temperatures of the nanosize grains were revealed by the simultaneous WAXD measurements. 相似文献
50.
《Journal of Experimental Nanoscience》2013,8(2):165-176
The structural and physicochemical properties of novel cationic lipid-based DNA complexes have been investigated for the purpose of designing micro/nano-scale self-assembling delivery systems for cutaneous gene therapy. DNA/gemini surfactant (spacer n?=?3–16; chain m?=?12 or 16) complexes (1?:?10 charge ratio), with or without dioleoylphosphatidyl-ethanolamine (DOPE), designed for cellular transfection, were generally in the range of 100–200?nm as demonstrated by atomic force microscopy and particle size analysis. Small-angle X-ray scattering measurements indicated that the DNA/gemini complexes lacked long-range order, whereas DNA/gemini/DOPE complexes exhibited lamellar and polymorphic phases other than hexagonal. Correlation studies using transfection efficiency data in PAM 212 keratinocytes and in vitro skin absorption indicated that formulations containing gemini surfactants having the ability to induce structures other than lamellar in the resulting complexes, generally exhibited greater transfection activity and cutaneous absorption. 相似文献