烧结NdFeB永磁材料的沿晶断裂分析

测试了烧结NdFeB永磁材料的抗弯强度和断裂韧性,分别为399.2MPa和4.72MPa·m1/2。抗弯测试结果显示NdFeB合金为脆性断裂。对弯曲断口进行宏观观察与SEM观察,对压痕裂纹源处的晶间破坏区域进行场发射扫描电镜观察。研究结果表明,试样断裂的微观机制主要为由试样原始晶体缺陷的长大和扩展引起的沿晶断裂。烧结NdFeB永磁材料的断裂机制可分为两个阶段———损伤积聚阶段和裂纹扩展阶段。     

Oriented linear cutting fiber sintered felt as an innovative catalyst support for methanol steam reforming

A kind of oriented linear cutting fiber sintered felt as an innovative catalyst support for methanol steam reforming was proposed. Multiple long copper fibers fabricated by cutting method were arranged in parallel and then sintered together in a mold pressing equipment under the condition of high temperature and protective gas atmosphere. The characteristics of oriented linear cutting fiber sintered felt coated with Cu/Zn/Al/Zr catalyst for methanol steam reforming were experimental investigated under different GHSVs and reaction temperatures. Results indicated that the structure of sintered felt was the key influencing factor for the reaction performances on the condition of low GHSV or reaction temperature whereas the structure of sintered felt showed little influences with high GHSV or reaction temperature. By the analysis of SEM image and ultrasonic vibration testing method, it was found that the coarse surface pattern of cutting fiber could effectively enhance the adhesion intensity between the catalyst and the copper fibers, as well as present relatively large specific surface area in the microchannels. And hence the oriented linear cutting fiber sintered felt present better performances of methanol steam reforming than the oriented linear copper wire sintered felt on the condition of low GHSV or reaction temperature.     

Preparation of Ni–Co alloy coating on sintered NdFeB magnet by potentiodynamic electrodeposition

A protective Ni–Co alloy coating was successfully prepared on sintered neodymium–iron–boron (NdFeB) magnet via potentiodynamic electrodeposition in this paper. The microstructure and surface morphology analysis of Ni–Co alloy coating showed that the surface morphologies were quite compact and more uniform than that prepared by direct current (DC) electrodeposition; significantly, the chemical composition analysis indicated that the content of Co in the alloy coatings amounted to 33–34?wt-%. Potentiodynamic polarisation and long term immersion test results revealed that the Ni–Co alloy coating could supply excellent corrosion protection for NdFeB substrate in 3.5?wt-% NaCl solution. Overall, the Ni–Co alloy coating with higher Co content prepared by potentiodynamic electrodeposition exhibited better corrosion protection for sintered NdFeB magnet compared with that prepared by DC electrodeposition.     

新型燃气轮机用热障涂层研究

本文旨在开发新型的具有低的导热系数及高的使用寿命的大气等离子喷涂热障涂层。使用了工业上广泛应用的等离子喷枪制备出系列涂层体系。通过改变涂层材料的化学特性,如使用高纯度材料以提高抗烧结能力,使用镝稳定的氧化锆粉末和预含孔隙结构的粉末。同时,团聚烧结（A＆S）与空心球形粉末（HOSP）被运用以期获得有益的微观结构。最终,使...     

铝土矿的烧结与均化烧结

采用荧光-能谱分析和场发射扫描电镜研究了4种D-K型铝土矿及其烧结块料的化学-矿物组成和显微结构,并对比分析了4种市售均化料的显微结构。结果表明:致密的水铝石质原料可获得致密化烧结,少量结构疏松的水铝石质原料不易获得致密化烧结;由水铝石和高岭石两矿物构成的铝土矿结构复杂,其中的致密、均匀者可获得均匀的刚玉-莫来石组合;有些烧结料的相分布不均匀,或疏松或玻璃相胶结刚玉。均化烧结料中局部富集的少量SiO2和杂质被均化并生成液相,致使刚玉晶体被液相胶结,从而降低了固-固相结合率,反映在宏观性质上却是显气孔率和吸水率极低而体积密度并不高,这是因为形成了较多的封闭式气孔。相比之下,A l2O3含量较低的刚玉-莫来石两相组合的均化料,既可实现均化又能获得含玻璃相很少的致密料。     

The effect of consolidation parameters on the mechanical properties of binderless tungsten carbide

This paper discusses the effect of the process parameters on the mechanical properties of binderless pure tungsten carbide during a GPS (gas protection sintering) process. The result of experiments reveal that the mechanical properties of the material increases with raising the sintering temperature and extending the retention time; however a decreased hardness was observed as a result of abnormal grain growth under higher sintering temperatures. The results of XRD and EDS analyses confirmed the absence of brittle phases such as W₂C or impurity phases in the microstructure. The optimized process parameters for GPS process are identified as: a mean particle size of 1.03 μm, a sintering temperature of 1860 °C and a retention time of 60 min; the resulting mechanical properties are: a relative density of 95.1%, a micro-hardness of 1718 kgf/mm² and a fracture toughness of 5.97 MPa m^1/2. The width of particles size distribution has a significant effect on the density and hardness of the sintered material however the width of particles size distribution is dependent on the original particle size. Finally, ultra-fine particles increase the chance of conglomeration and sub-micron structures. The conglomeration of ultra-fine particles hinders the filling of porosities during sintering and lowers the density and hardness of the material.     

烧结耐火材料的超声检测

在烧结耐火材料的超声检测中,采用以判断声速为主的综合判断方法对烧结耐火砖的缺陷情况和内部结构特点进行检测判断,结果与机械化破坏后观察到的情况吻合。     

Sm(Co_(0.74)Cu_(0.12)Fe_(0.1)Zr_(0.04))_(7.5)纳米晶烧结磁体的结构和磁性能

采用放电等离子烧结技术制备了致密纳米晶SmCoCuFeZr烧结磁体,研究了磁体的结构和磁性能.X衍射结果表明,烧结磁体具有TbCu_7结构.TEM观察显示,烧结磁体平均晶粒尺寸为35nm.室温时磁体的剩磁为0.49T,矫顽力高达1.42T,而剩磁比Mr/Ms为0.63,表明在纳米晶之间存在晶间交换耦合作用.     

Mechanical properties and fracture mechanism study of sintered Nd–Fe–B alloy

The mechanical properties including bending strength (σ_bb) and fracture toughness (K_IC) of sintered Nd–Fe–B magnets have been examined in this paper. Alloyed magnet with Dy, Co, Nb additions shows the higher magnetic properties and bending strength but the lower fracture toughness than the ternary magnet. The zero plastic energy in bending procedure presents the purely brittle nature of Nd–Fe–B magnet. Fracture mechanism has been discussed on the base of the in situ SEM observation of micro-crack nucleation and FE-SEM (field emission scanning electron microscope) observation of indentation cracks. The fracture mechanism of sintered Nd–Fe–B alloy is concluded as two stages: the damage-accumulating stage and the crack-propagating stage. Some suggestions for improving toughness of sintered Nd–Fe–B magnets are mentioned.     

硅灰石型烧结微晶玻璃及其应用前景

简要介绍了硅灰石型烧结微晶玻璃的工艺原理,生产工艺,着重分析和读者论论其生产现状及存在的问题,并阐述其应用现状及前景。