Characterization of FeS2-pyrite thin films synthesized by sulphuration of amorphous iron oxide films pre-deposited by spray pyrolysis

FeS₂-thin films with good crystallinity were synthesized by a simple method which consists of sulphuration, under vacuum, of amorphous iron oxide thin films pre-deposited by spray pyrolysis of FeCl₃·6H₂O (0.03 M)-based aqueous solution onto glass substrates heated at 350 °C. At optimum sulphuration temperature (450 °C) and duration (6 h), black green layers having granular structure and high absorption coefficient (5.10⁴ cm⁻¹) were obtained. The study of the electrical properties of the as-prepared films vs. the temperature variations showed three temperature domain dependence of the conductivity behaviour. The first one corresponds to the high temperature range (330 K–550 K) for which an Arrhenius plot type was obtained. The activation energy value was estimated at about 61.47 meV. The second domain corresponding to the intermediate temperature range (80 K–330 K) showed a variable activation energy between the grain boundaries. The barrier height, q¯, was estimated to 27±0.5 meV, and the standard deviation, qσ, was evaluated at about 14±0.5 meV. We found that at lower temperatures (20 K–80 K), the conductivity is governed by two conduction types. The density of localised states, was about 2.45×10²⁰ eV⁻¹ cm⁻³.     

Thermal and structural properties of spray pyrolysed CdS thin film

Using photo acoustic technique, the thermal properties of CdS thin films grown by spray pyrolysis are measured. Thermal diffusivity and conductivity in these films decrease at least two orders compared with bulk. These results are compared with our study on nano CdS and the other available literature. The comparison is good. The dependence of thermal diffusivity on the thickness of the layer or the size of the particles on the glass substrate are analysed from the present measurement and discussed. The dependence of thermal diffusivity on the thickness of the layer on the glass substrate is discussed.     

蒸发式冷凝器结构特点及工程应用

本文对蒸发式冷凝器的结构、工作原理及安装、使用过程中应注意的问题作一下介绍.并结合工程实例,对蒸发式冷凝器和水冷式冷凝器作综合比较.     

Cr3C2-25%NiCr料浆中分散剂含量对其喷雾干燥粉末性能的影响

通过添加高分子分散剂配制Cr3C2-25%NiCr料浆,喷雾干燥制备出高球形化的Cr3C2-25%NiCr复合粉末。利用SEM研究了分散剂含量对喷雾干燥制备的Cr3C2-25%NiCr复合粉末性能的影响,结果表明:分散剂能够调节料浆性能,粉末的流动性及松装密度明显提高,其中0.04%含量的分散剂所制备的Cr3C2-25%NiCr粉末具有最佳的物理性能。     

泉港区广播电视大楼消防设计

介绍泉州市泉港区广播电视大楼消防设计。结合实例探讨消防水池合理储水容积的确定 ;室内消火栓的正确布置 ;自动喷水灭火系统结合保护对象的不同特点 ,分别设计为闭式系统、雨淋系统、水喷雾系统 ;探讨消防系统的控制方式 ;自动喷水灭火系统管道的连接方式 ;气体消防灭火剂的选择等需要注意的几个问题     

面向直纹组合曲面的喷涂机器人喷枪轨迹优化与算法

针对复杂自由曲面中直纹组合曲面上喷涂机器人喷枪轨迹优化及轨迹连接问题,基于曲面面片造型与智能算法理论,建立了喷枪轨迹优化数学模型,提出一种满足直纹曲面上喷枪轨迹首尾衔接的算法程序。首先,通过曲面特征定义直纹曲面,并对直纹曲面造型处理后建立复合喷涂直纹圆弧面片的喷枪数学模型;其次,选择直纹组合面片交界处的喷枪轨迹为优化对象,依据该模型对直纹曲面及直纹组合面片上的喷枪轨迹进行优化,验证了该模型的有效性;最后,依据轨迹优化模型,设计算法程序并通过仿真实验,验证了该算法程序的可行性与优越性,实现了对直纹组合曲面的连续性喷涂。     

高洁净MCrAlY合金粉末的制备及涂层性能

采用VIGA 16真空氩气雾化设备制取MCrAlY粉末,制取的粉末经处理后,用LPPS-TF工艺喷涂制备高性能涂层。结果表明,真空氩气制取的粉末氧、氮、氢含量较低,且以球形为主,具有良好的流动性,杂质碳、氮、氢含量低等特征。原料全部为新料时可制备出氧含量最低达125×10~(-6)的粉末,经过处理后,粉末中的陶瓷夹杂总数在3个/(100g)以下。用LPPS-TF工艺制取的涂层结构致密,氧含量低,涂层与基体结合达到81.3MPa。     

Production and Properties of Spray-dried Amaranthus Betacyanin Pigments

ABSTRACT: Amaranthus betacyanin extracts were spray-dried using a range of maltodextrins [10-25 dextrose equivalent (DE)] and starches (native/modified) as carrier and coating agents at 5 inlet/outlet air temperatures and 4 feed solid contents. Higher inlet/outlet air temperatures caused greater betacyanin loss during spray drying, and affected slightly the pigment stability during storage. Adding maltodextrins and starches significantly reduced the hygroscopicity of the betacyanin extracts and enhanced storage stability. The 25 DE/10 DE mixed powders provided a longer predicted half-life (63.6 wk) compared to the 25 DE and the 10 DE powders separately. The best dried pigment-containing powder made was superior to commercial red beet powder in physical properties.     

Microstructure and Tensile Properties of Spray Deposited Al-2.15Li-1.28Mg-1.26Cu-0.10Zr Alloy

0INTRODUCTIONSinceDuwezproducedfirstlyglassyAu-Sialloybyrapidquenchingtechniqueinl96o['],rapidsolidificationtechnologyhasmadegreatprogress.Nowadaysanumberofrapidsolidificationmethodshavebeenusedtopro-ducerapidlysolidifiedmaterialssuchaspow-der,ribbon,foilandwirel'].ThesetechniquesareabletoachievecoolingratetotheorderoflO'~lO't/s,yieldingexcellentlyrefinedandhomogeneousmicrostrllcturewithre-sultantoutstandingmechanifPl,physicalandchemicalpropertiesl"'].Althoughprominentimprovementsinprop…     

Homogeneous dispersion of boron nitride nanoplatelets in powder feedstocks for plasma spraying

Hexagonal Boron nitride nanoplatelet (BNNP) with the combination of excellent mechanical properties, high-temperature thermal stability, and self-lubrication is a promising strengthening agent in plasma-sprayed composite coatings. However, it is a significant challenge to produce plasma sprayable feedstocks with homogeneously dispersed BNNPs owing to the intrinsic agglomeration of BNNPs. In this research, three powder preparation processes (electrostatic interaction, ball milling, and shear mixing) were employed to disperse BNNPs in Ni-Cr-Cr₂O₃ (NCCO) powders. The shear mixing process presents a competitive advantage in powder preparation, providing stable shear force and achieving exfoliated BNNPs homogeneous distribution in the composite powders. The spray drying technique was finally utilized to obtain spherical agglomerated BNNP-NCCO feedstocks with characteristics of relatively smooth surface and uniform size distribution. Hence, shear mixing and spray drying processes are expected to produce large-scale spherical composite powders with a homogeneous distribution of 2D layered nanomaterials for industrial application.