Improvement of the optical properties of electrodeposited CuInSe2 thin films by thermal and chemical treatments

Cu, In and Se have been codeposited in thin films by potentiostatic one-step electrodeposition. The as-deposited material has shown direct optical transitions attributable to the CuInSe₂ semiconductor, but also additional absorption corresponding to another semimetallic phase. The secondary phases are selenium and copper selenide compounds which have been determined by composition measurements. In order to eliminate the semimetallic phases and to improve the semiconductor behaviour of the electrodeposited material, thermal and chemical treatments have been performed. After heat-treatment of the samples at 400°C in flowing argon, elemental selenium loss has been detected together with an enhancement of the allowed direct optical transition. The subsequent chemical etching of the layers in a KCN solution has showed to be successful in eliminating the copper selenide phases which were responsible of the remaining sub-bandgap absorption.     

13SiMnNiCrMoV钢切口疲劳裂纹萌生门槛值

本文研究在13SiMnNiCrMoV 结构钢中用尖裂纹的应力强度因子来反映三点弯曲缺口试样的疲劳裂纹萌生规律。当 R=0.1,f=100Hz,试样尺寸 B×W×L=12.5×25×117mm 时,缺口名义应力幅的门槛值为Δσ_(th)=3315ρ~(0.352) MPa,0.5mm≤ρ≤5mmΔK_(th)=250ρ~(0.352) MPam~(1/2)门槛值与ρ有关。同时得到缺口裂纹萌生的循环次数 N_i 与名义应力幅Δσ、缺口曲率半径ρ的定量关系是N_i=3.98×10~(22)ρ~(1.62)/Δσ~(4.85),N_i≤10~(5.5)并讨论了(ΔK_1/ρ~(1/2))_(th)与ρ无关的结论。     

柔性纤维混凝土的疲劳特性研究

将柔性纤维掺入水泥混凝土可以大幅度提高混凝土的弯曲疲劳等路用性能,并通过试验建立了柔性纤维混凝土的疲劳方程.结果表明,柔性纤维不但能使混凝土的强度提高,更主要的是可以在重交通条件下,可成倍地提高混凝土的弯曲疲劳寿命.     

Comparative analysis of urban reflectance and surface temperature

Urban environmental conditions are strongly dependent on the biophysical properties and radiant thermal field of the land cover elements in the urban mosaic. Observations of urban reflectance and surface temperature provide valuable constraints on the physical properties that are determinants of mass and energy fluxes in the urban environment. Consistencies in the covariation of surface temperature with reflectance properties can be parameterized to represent characteristics of the surface energy flux associated with different land covers and physical conditions. Linear mixture models can accurately represent Landsat ETM+ reflectances as fractions of generic spectral endmembers that correspond to land surface materials with distinct physical properties. Modeling heterogeneous land cover as mixtures of rock and/or soil Substrate, Vegetation and non-reflective Dark surface (SVD) generic endmembers makes it possible to quantify the dependence of aggregate surface temperature on the relative abundance of each physical component of the land cover, thereby distinguishing the effects of vegetation abundance, soil exposure, albedo and shadowing. Comparing these covariations in a wide variety of urban settings and physical environments provides a more robust indication of the global variability in these parameter spaces than could be inferred from a single study area. A comparative analysis of 24 urban areas and their non-urban peripheries illustrates the variability in the urban thermal fields and its dependence on biophysical land surface components. Contrary to expectation, moderate resolution intra-urban variations in surface temperature are generally as large as regional surface heat island signatures in these urban areas. Many of the non-temperate urban areas did not have surface heat island signatures at all. However, the multivariate distributions of surface temperature and generic endmember fractions reveal consistent patterns of thermal fraction covariation resulting from land cover characteristics. The Thermal-Vegetation (TV) fraction space illustrates the considerable variability in the well-known inverse correlation between surface temperature and vegetation fraction at moderate (< 100 m) spatial resolutions. The Thermal-Substrate (TS) fraction space reveals energetic thresholds where competing effects of albedo, illumination and soil moisture determine the covariation of maximum and minimum temperature with illuminated substrate fraction. The dark surface endmember fraction represents a fundamental ambiguity in the radiance signal because it can correspond to either absorptive (e.g. low albedo asphalt), transmissive (e.g. deep clear water) or shadowed (e.g. tree canopy shadow) surfaces. However, in areas where dark surface composition can be inferred from spatial context, the different responses of these surfaces may still allow them to be distinguished in the thermal fraction space.     

疲劳裂纹的灰色残差预测

借助灰色理论，建立了预测疲劳裂纹扩展的灰色残差预测模型，并应用此模型预测了某不锈钢构件腐蚀疲劳裂纹的扩展，得到了较高精度的预测结果，为疲劳裂纹预测提供了一种简易而可靠的新途径。     

GCr15轴承钢的热变形模拟试验研究

利用先进的Gleeble-2000热模拟试验机，对GCr15轴承钢某一轧制过程进行模拟试验，测定出GCr15轴承钢动态CCT曲线，并结合微观组织分析，制定合理的GCr15轴承钢轧后控制冷却工艺，以期达到提高GCr15轴承钢质量的最终目的。     

Thermal Expansion Behavior of La1—xSrxMn1—yCoyO3—δ Perovskites

The thermal expansion behavior of La1-xSrxMn1-yCoyO3-δ (x=0.2-0.4, y=0.1-0.3) perovskites in air has been investigated. The average linear thermal expansion coefficients increased with increasing Sr content up to 40 mole fraction or Co content up to 30 mole fraction. The expansion is generally attributed to an increase in the average cation radius as some of the cations in the perovskite are reduced in valence when oxygen ions are removed from the structure.     

在役钢筋混凝土结构基于可靠性的疲劳寿命分析

本文以结构的极限疲劳循环次数作为随机变量,基于可靠性理论提出了在役结构疲劳剩余寿命的预测方法,分析了多种工况下结构在未来服役期内的疲劳可靠性和疲劳剩余寿命。算例表明,通过对在役结构疲劳寿命及可靠性的分析,不仅可以预测在目标可靠度下的疲劳寿命,而且可以根据需要确定合适的交变荷载的频率、服役时间以及相应的疲劳可靠指标,从而为结构的合理利用起指导性作用。     

The concept of an endurance limit for adhesive joints

The effect of cyclic stressing on the strength of single lap adhesive joints has been studied and a considerable reduction in strength observed when the maximum stress exceeds about 40% of the ultimate tensile strength, but whether or not a true endurance limit exists is not proven. Fallacies are shown in some of the techniques which have been proposed for studying the fatigue behaviour of adhesive joints.     

Effect of powder painting procedures on the filiform corrosion of aluminium profiles

In this work, the filiform corrosion behaviour of powder painted aluminium profiles was studied, and the coating barrier properties together with adhesion to the substrate were analysed. Samples coated with a traditional painting procedure (one powder layer application followed by curing), and other samples coated using a special cycle to obtain wood grain effect were compared using accelerated filiform corrosion tests. Moreover, in order to better understand the degradation mechanisms of painted metal substrates, thermal stresses were applied to accelerate the natural weathering. The effects of the thermal aging were analysed by electrochemical impedance spectroscopy.