350MW超临界直流锅炉水冷壁H型鳍片开裂失效分析

采用宏观形貌分析、化学成分分析、显微组织分析和数值模拟等方法对某电厂350MW超临界直流锅炉水冷壁H型鳍片开裂原因进行分析。分析结果表明,该锅炉水冷壁H型鳍片开裂的主要原因是鳍片较宽且厚度设计过小,致使鳍片不能被有效冷却而造成严重老化和脱碳,在交变热应力的作用下产生热疲劳而开裂。通过分析计算,确定了鳍片的合理厚度供参考。     

热重法确定MMH微晶中各种水分的相对含量

借助热分析仪对MMH微晶进行了TG和DTG分析,研究了MMH微晶中各种水分的相对含量。提出MMH微晶中存在4种水分,即自由水、松散吸附水和紧密吸附水、结晶水和羟基水,给出了MMH微晶的完整表达式,即 MgAl_(0.965)(OH)_(4.75)Cl_(0.145·1.70)H_2O。     

长期高温高压氢暴露对Cr-Mo钢断裂韧性和裂纹行为的影响

选用Cr-Mo钢经400℃,20 MPa,10⁴ h氢暴露后进行拉伸、断裂韧性和疲劳试验.结果表明:Cr-Mo钢已经发生了氢腐蚀,氢蚀使Cr-Mo钢强度、塑性和断裂韧性均有所降低,也使断裂机制由韧窝型转变为解理脆性.氢蚀使疲劳裂纹扩展行为也发生了变化,疲劳裂纹扩展速率增加,ΔK_th降低.Cr-Mo钢氢蚀后,随应力比增加,疲劳裂纹扩展门槛值大幅度降低.     

Crystallisation process of Al80Fe10Ti10 amorphous phase

Abstract

In the present study, crystallisation behaviours of the Al₈₀Fe₁₀Ti₁₀ amorphous phase (prepared by mechanical alloying) has been investigated using X-ray diffraction and differential thermal analysis techniques. It was found that Al₈₀Fe₁₀Ti₁₀ amorphous phase exhibits one-stage crystallisation on heating [amorphous to Al₁₃Fe₄, Al(Fe,Ti) and Al₅Fe₂ intermetallic phases]. The activation energies for crystallisation of Al₈₀Fe₁₀Ti₁₀ amorphous phase were determined as 326, 322, 351 and 301 kJ mol^?1 by means of the Kissinger–Akahira–Sunose, Flynn–Wall–Ozawa, Friedman and Afify equations respectively. Kinetic parameters such as Avarmi exponent or reaction order n and frequency factor K_o were also discussed. The reaction orders obtained for the crystallisation was ～2·03, suggesting that a diffusion controlled crystallisation process with a decreasing nucleation rate was the crystallisation mechanism. The deduced K_o value for crystallisation peak was calculated to be 6·75×10¹⁰ s^?1.     

硅藻土涂料在热模法离心铸造球铁管中的应用

采用硅藻土为骨料配制的悬浊液作为涂料涂覆于管模内壁生产球铁管,论述了涂料原材料选择、涂料配制、性能及合适的施涂方式。试验表明,膨润土浆持续搅拌2h,再静止10h后配制涂料;硅藻土是涂料热模法中最合适的骨料;对于小管径的管模涂料,膨润土含量高一些,硅藻土与膨润土的质量比为(8～15):1;对于大口径管模涂料,膨润土含量稍低,硅藻土与膨润土质量比为(12～20):1,另外,有气喷涂是最佳的喷涂方式。     

Thermal comfort of patients: Objective and subjective measurements in patient rooms of a Belgian healthcare facility

In healthcare facilities, the prediction of mean thermal comfort perception of patients and staff is necessary to formulate requirements for the architectural and building systems design and control, and for establishing guidelines for the use of clothing and bedding systems.     

Experimental tile with phase change materials (PCM) for building use

The use of phase change materials (PCM) and their possible architectural integration is a path in the search for optimizing energy efficiency in construction. As part of this path, a pavement has been designed which, in combination with the PCM, serves as a passive thermal conditioning system (new patent n°. ES2333092 A1) [1]. The prototype has been tested experimentally and the results proved that it is a viable constructive solution improving the energy performance of sunny locals.     

Study of the geometry of a voided clay brick using non-rectangular perforations to optimise its thermal properties

This study seeks to improve the geometrical distribution of bricks to optimise the equivalent thermal transmittance of a wall built of Termoarcilla^® ECO 29 voided clay bricks, using calculations according to Spanish UNE [1], AENOR [10], European EN [6], [7], [8] and [9] and international ISO [11] and [12] standards.The objective is to study improvements in the wall's thermal conductivity, always remembering the limitations imposed by the manufacturing process. Simulations are made using a finite elements application [14].It is concluded that, within the possibilities allowed by the manufacturing process, with non-rectangular voids the heat flux has to cross a higher number of voids, which improves its thermal properties. A rhomboid layout of voids with the longer diagonal at right angles to the heat flux is the best internal void layout. If the internal perforations are also extended to the end of the tongue and groove, the direct thermal bridge in this type of brick is broken.Finally, a 290 mm wide brick with 25 rows is obtained with the geometrical properties described above which shows an improvement of almost 16% over the original ECO 29 brick, performing well in all climatic areas of Spain, with a full-bed mortar joint 30 mm thick.     

Synthesis of zirconium tungstate–zirconia core–shell composite particles

In this work, ZrW₂O₈–ZrO₂ core–shell composite particles were synthesized. ZrW₂O₈ that was used in the core is a material with negative coefficient of thermal expansion, and it was synthesized from a high-pH precursor based on use of tungstic acid and zirconium acetate. Shell layer was composed of ZrO₂ nanocrystallites and precipitated from an aqueous solution by urea hydrolysis. While volume of the shell was effectively controlled by the initial zirconium ion concentration in the solutions, the rate of precipitation was a function of the ratio of initial concentrations of urea to zirconium ions. It is hypothesized that isolation of the ZrW₂O₈ within a layer of ZrO₂, will be a key element in solving problems associated with reactivity of ZrW₂O₈ towards other components in sintering of ceramic–ceramic composites with tuned or zero thermal expansion coefficient.