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81.
Ni59Zr20Ti16Si2Sn3 amorphous material was deposited by a vacuum plasma spraying technique onto steel and copper substrates in order to investigate their behaviour in a corrosive environment. For comparison, the same alloy was prepared as amorphous ribbons by melt spinning. The amorphous nature of the coatings and ribbons was characterized by XRD, DSC and TEM, while XPS and AES analyses were performed to understand the origin of passivation and mode of corrosion. The corrosion behaviour of the coating was studied in H2SO4 and HCl solutions open to air at room temperature. Potentiodynamic polarisation and galvanic coupling tests were carried out on the substrate and the coating. It was found that the formation of Zr-, Ti- and Si-rich passive oxide layers provide a high corrosion resistance in H2SO4 solution while the breakdown of the passive layer by chloride ion adsorption was responsible for pitting corrosion of the Ni59Zr20Ti16Si2Sn3 amorphous ribbons in HCl solution. Galvanic corrosion was the dominant corrosion mechanism for the coating/copper hybrid structure, in contrast to the Ni59Zr20Ti16Si2Sn3 amorphous coating, which efficiently protected the steel substrate in the corrosive environment. 相似文献
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83.
利用“球化效应”激光扫描制备球形Ti粉的研究 总被引:1,自引:0,他引:1
利用“球化效应”,在SLS设备上探索将异形Ti粉转化为高性能球形粉末的可行途径。通过系统地改变激光功率、扫描速度,以及选取合适的激光扫描间距,探明了形成“球化效应”的工艺条件,并在激光功率为600W,扫描速度为30mm/s时,获得了较为理想的球形Ti粉。通过对球化过程进行理论分析,得出了选取激光扫描制备球形Ti粉工艺参数的准则。 相似文献
84.
F. Zucchi A. Frignani V. Grassi G. Trabanelli C. Monticelli 《Corrosion Science》2007,49(12):4542-4552
The formation of stannate and permanganate–phosphate conversion coatings on AZ31 magnesium alloy was investigated in situ by EIS measurements and their protective performances were studied by different electrochemical techniques in diluted (0.05 M) sodium sulphate solution.The influence that short or long treatment times exert on the performances of such conversion coatings is discussed. While permanganate–phosphate baths always built layers characterized by penetrating cracks, long stannate baths produced layers without interconnected porosity, but were defective. This accounted for the initial greater protectiveness achieved with the stannate treatment; nevertheless, the easy penetration of the electrolytic solution through such a layer quickly decreased its corrosion resistance. 相似文献
85.
1 INTRODUCTIONTheorthorhombicalloysareofgreattech nolog icalinterestinhightemperatureapplicationssincetheyhaveagoodbalanceamongst 相似文献
86.
87.
燃烧合成三元碳化合物Ti2AlC1-x 总被引:1,自引:0,他引:1
采用Ti,Al和C元素粉末为反应物原料,通过燃烧合成法首次成功地制备出了单相三元碳化合物Ti2AlC1-x。实验结果表明:若以“理想”晶体结构化学式Ti2AlC化学计量比为起始反应原料配比,燃烧产物主晶相为Ti2AlC2;以缺碳的非化学计量比(Ti2AlC1-x)为反应原料配比,即Ti:Al:C=3:1.5:1=2:1:0.7(摩尔比),得到单相的燃烧产物Ti2AlC1-x。从热力学原理的角度探讨了不同原料摩尔配比对燃烧产物相组成的影响机理。 相似文献
88.
为研究包覆方式对片状发射药燃烧性能的影响,建立了不同包覆方式下多层片状发射药的物理模型,并推导了形状函数和燃气生成猛度表达式,利用Matlab软件对不同的宽厚比、长厚比及多层结构的片状发射药进行了数值计算;制备了不同长厚比的片状变燃速发射药,并进行了密闭爆发器实验。结果表明,四面包覆和全包覆可以很好地消除临界宽厚比对片状发射药燃烧性能的影响;与两面包覆的片状发射药相比,四面包覆和全包覆的片状发射药能够延缓内层药减面燃烧的时间,其燃气生成猛度的阶跃程度分别提高了1.17%和1.23%,呈现出良好的燃烧渐增性。 相似文献
89.
90.
Shilin Liu Jing Lin Qiyuan Chen Zili Liu Lishuang Gui Liwei Chen Shilin Huang Xuelin Tian 《大分子材料与工程》2021,306(10):2100242
Crude oil spill accidents pose a worldwide environmental threat. Oleophilic and hydrophobic absorbents that can selectively absorb oil from water have shown promising application potential in oil spill remediation. Simultaneous optimization of the absorption and desorption speed of absorbents towards oil is highly desirable for their recyclable usage, but remains a great challenge, because these two properties are generally conflicting. Here, a facile and ingenious strategy is proposed to tackle the above challenge via surface modification of porous sponges with highly flexible linear polydimethylsiloxane (LPDMS) brushes. The LPDMS brushes feature liquid-like properties at room temperature owing to its extremely low glass transition temperature, and act as a covalently-grafted lubrication layer throughout the 3D network channels of the sponge, which can minimize contact angle hysteresis and reduce friction between oil and sponge channel. Compared to the prevalent cross-linked polydimethylsiloxane (CPDMS) modification strategy, sponges modified with LPDMS brushes not only shows significantly enhanced absorption speed, but also exhibits superior desorption dynamics towards viscous crude oils. The design strategy of slippery sponges with liquid-like molecules may open a new avenue for developing advanced absorbents with simultaneously enhanced absorption and desorption performances for liquid separation and purification applications. 相似文献