新型SiMnCr系高强度粗钢筋材料的研制

针对高强度钢筋的性能要求和钢筋生产的工艺特点 ,设计了一种新型的低碳SiMnCr系高强度钢。测定了该钢种的CCT曲线及其力学性能。在锻造或轧态下 ,可获得以低碳马氏体为主含少量贝氏体、残留奥氏体的复相组织 ,经低温回火 ,可获得高的强度 (σb>12 30MPa)和良好的塑性 (δ5≥ 8% )。     

修正步冷温度曲线试验研究

按修正步冷温度曲线对经步冷脆化的 2 .2 5Cr 1Mo和在加氢反应器内运行 5a的 2 2 5Cr 1Mo试块进行了修正步冷试验 ,评定了材料的回火脆性。结果表明 ,按修正步冷曲线进行修正步冷试验能使已经脆化的材料进一步脆化 ,为加氢反应器材料损伤的研究提供了一条途径。     

改进渣浆泵过流件铸造工艺及硬度的措施

介绍了渣浆泵过流件材质的化学成分及其正交试验的优选过程，以及重新制定的铸造工艺。     

Ti-23Al-14Nb-3V合金氩弧焊接头的显微组织及其力学性能

研究了预热对Ｔｉ－２３Ａｌ－１４Ｎｂ－３Ｖ合金焊接性，特别是对消除氩弧焊冷裂纹的作用以及对接头显微组织和力学性能的影响。结果表明，焊前预热可有效降低该合金的冷裂倾向。经预热处理后，焊缝区的结晶层状线消失，热影响区的硬度峰得到缓和，整个焊缝的显微硬度分布趋于均匀，但焊缝区的枝晶发生粗化，热影响区有所扩大。焊件接头的拉伸试验表明，预热可使焊缝区的接头强度系数增加，但无论预热与否，接头强度均低于母材强度，且不显示宏观塑性。     

High energy Urbach characteristic observed for gallium nitride amorphous surface oxide

We have observed an “above band-gap” Urbach like characteristic for gallium nitride films (at the high energy side of the band-edge). A combination of X-ray diffraction, secondary ion mass spectroscopy and optical transmission measurements were taken for gallium nitride samples of different thickness. From this data we demonstrate that the high energy Urbach like characteristic is related to the presence of an amorphous surface oxide. It is shown to dominate the absorption spectra of thin gallium nitride samples, for which the influence of surface oxidation is strongest.     

固载于SBA-15分子筛中的同双核金属配合物催化剂

合成了3种同双核金属配合物[M2LCl3]Cl(L代表配体三亚乙基四胺,M代表Co,Cu,Cr),采用微波加热法合成了SBA-15分子筛,采用浸渍法将3种同双核金属配合物分别固载在表面官能化的SBA-15分子筛(SBA-15-NH2分子筛)中制得负载型催化剂。傅里叶变换红外光谱、X射线衍射、紫外可见光谱和热分析表征结果表明,同双核金属配合物被固载后,其结构仍保持完整。以环己烷氧化反应为探针反应,考察了[Co2LCl3]Cl/SBA-15-NH2,[Cu2LCl3]Cl/SBA-15-NH2,[Cr2LCl3]Cl/SBA-15-NH2催化剂的活性,环己烷转化率分别为11.0%,49.5%,57.9%;对于[Cr2LCl3]Cl/SBA-15-NH2催化剂,当分别以乙睛、丙酮和冰醋酸为溶剂时,环己烷转化率分别为57.9%,52.1%,34.2%,3次重复实验的环己烷转化率分别为57.9%,47.8%,46.5%,表明该催化剂具有较好的活性和重复使用性。     

Cr12MoV钢冷挤压成形模强化工艺的研究

针对Crl2MoV钢冷挤压成形模热处理存在的质量问题，对加热温度和方式进行了大量的试验研究，在此基础上，提出了改进的快速加热工艺。结果表明，经该工艺处理后，模具使用寿命得到显提高。     

调质状态下40Cr钢的焊接

在合理制定焊接工艺的基础上，采用R307珠光体耐热钢焊条成功地进行40Cr钢在调质状态下的焊接，解决了通常采用25—13型奥氏体焊条焊接出现的焊缝强度低、焊接接头性能差的问题。     

Simulation of the Forming Behaviour of a Boron Modified P91 Ferritic Steel

The forming behaviour at high temperature of a modified 9%Cr‐1%Mo (P91) ferritic steel containing B and Ti for elevated temperature service was investigated. The microstructure of the as‐received material is mainly martensite at room temperature, but special etching revealed prior austenite grains of about 25 μm in size. Torsion tests were conducted at temperatures in the range 850 to 1250 °C to simulate the hot rolling process under comparable conditions of temperature, strain rate and strain. The deformation data obtained from these tests were correlated with the Garofalo equation with a stress exponent of 4.6 and an activation energy of 315 kJ/mol. This equation was used to predict the formability behaviour for the rolling process and also to determine the maximum forming efficiency and stability of the steel. A temperature of 1200 °C is recommended to conduct the forming process.