Simple Synthesis of Hollow Tin Dioxide Microspheres and Their Application to Lithium‐Ion Battery Anodes

Hollow tin dioxide (SnO₂) microspheres were synthesized by the simple heat treatment of a mixture composed of tin(IV ) tetrachloride pentahydrate (SnCl₄·5H₂O) and resorcinol–formaldehyde gel (RF gel). Because hollow structures were formed during the heat treatment, the pre‐formation of template and the adsorption of target precursor on template are unnecessary in the current method, leading to simplified synthetic procedures and facilitating mass production. Field‐emission scanning electron microscopy (FE‐SEM) images showed 1.7–2.5 μm sized hollow spherical particles. Transmission electron microscopy (TEM) images showed that the produced spherical particles are composed of a hollow inner cavity and thin outer shell. When the hollow SnO₂ microspheres were used as a lithium‐battery anode, they exhibited extraordinarily high discharge capacities and coulombic efficiency. The reported synthetic procedure is straightforward and inexpensive, and consequently can be readily adopted to produce large quantities of hollow SnO₂ microspheres. This straightforward approach can be extended for the synthesis of other hollow microspheres including those obtained from ZrO₂ and ZrO₂/CeO₂ solid solutions.     

Evaluation of an Nd doping effect on characteristic properties of tin oxide

In the present work, transparent and conductive Nd doped SnO₂ thin films were deposited via spray pyrolysis. Crystallographic, morphological, optical and electrical characterizations of SnO₂ were researched as a function of Nd doping. The XRD analysis indicated the films had tetragonal cassiterite tin oxide structure and (211) preferential direction for NdTO-0, NdTO-1, NdTO-2 and NdTO-3 samples changed to (110) plane for NdTO-4 and NdTO-5 samples. The crystalline size and strain analysis were made by using a Williamson–Hall method. The SEM micrographs showed that all films had homogenously scattered pyramidal and small densely nanoparticles. The optical analysis indicated optical band gap value of undoped film increased with 1 at% Nd doping and then it decreased with more Nd content. The Hall measurements indicated that the highest electrical conductivity was obtained for 2 at% Nd doping content.     

Soldering of solution-processed organic vertical transistor and light-emitting diode on separate glass substrates by tin micro-balls

The vertical organic space-charge-limited transistor made of P3HT and small-molecule phosphorescent organic light-emitting diode (OLED) are made on two separate glass substrate by blade coating, then soldered vertically together by tin balls with 40 μm diameter. The soldering is done by hot wind of 150 °C for 5 min Contact resistance is only 10 Ω. The vertical transistor is annealed at 150 °C for 5 min before soldering to enhance the output current up to 25 mA/cm² and give high thermal stability. Both OLED and the annealed vertical transistor are not affected by the soldering process. The vertical transistor has 1/4 of the OLED area and turns on the bottom-emission white OLED up to 300 cd/m² and orange OLED up to 600 cd/m². The entire operation is within 8 V. OLED and transistor array can therefore be made on separate glass substrates then soldered together to form the display.     

新型MSIS结构气敏电容的研究

采用静电喷雾高温分解工艺制备ＳｎＯ２气敏膜，并与Ｓｉ３Ｎ４－ＳｉＯ２集成多层介质膜，用催化金属Ｐｔ作栅电极，制成新型的ＭＳＩＳ结构气敏电容。通过检测平带电压的变化，研究对Ｈ２和Ｏ２的气敏特性，分析其气敏机理并提出了检测的物理模型．     

Coating of multi-walled carbon nanotube with SnO2 films of controlled thickness and its application for Li-ion battery

Multi-walled carbon nanotubes (MWCNTs) coated with a smooth and uniform tin oxide (SnO₂) layers of different thickness were prepared by a novel thioglycolic acid assisted one-step wet chemical method. The coatings were characterized by powder X-ray diffraction (XRD) and transmission electron microscopy (TEM). The thickness of the SnO₂ coatings can be easily controlled by changing the synthesis conditions, such as pH value of the solution and hydrolysis time. The electrochemical properties of the SnO₂/MWCNTs composites as anode materials for lithium batteries were studied by galvanostatic method. The composites showed high charge capacities and good durability against decay. This could be ascribed to the good dispersion, thin layer and small particle size of SnO₂ on MWCNTs.     

Absorption Properties of Hybrid SnO<Subscript>2</Subscript> Nanocrystal-Carbon Nanotube Structures

Tin oxide (SnO₂) nanocrystals of a few nanometers are of great interest for electronic applications. Here we present a mini-arc plasma method to produce aerosol tin oxide nanocrystals at atmospheric pressure. The product SnO₂ nanocrystals are then assembled onto the external surface of carbon nanotubes (CNTs) to form hybrid SnO₂–CNT structures. The absorption properties of both the SnO₂ nanocrystals and the SnO₂–CNT hybrid structures have been characterized. Quantum size effects have been observed for as-produced SnO₂ nanocrystals. The intrinsic nanoparticle size selection during the assembly process results in a blue shift of the absorption spectrum for hybrid nanostructures.     

LGA器件焊点缺陷分析及解决

文章针对LGA器件回流焊后常见的空洞和锡珠等缺陷,对其产生的原因进行了分析.通过对LGA器件采用预上锡回流工艺和印制板钢网一字架桥开口的方式,提升回流焊过程中焊膏中挥发气体的逸出,并通过对比试验,找到合适的预上锡钢网尺寸,解决了生产中LGA器件焊接常见的空洞大等缺陷.     

锡铜包覆涤纶织物的结构与性能研究

在涤纶织物镀铜的基础上电镀锡制得了锡铜包覆涤纶织物,通过扫描电镜和电子能谱对其进行表征,研究了电压和时间对表面电阻的影响,并测试了结合牢度、抗氧化性和电磁屏蔽性能。结果表明,当电镀电压为1 V、时间6 min时,镀铜涤纶织物表面包覆了一层厚度约为3.0μm的锡,且锡铜包覆涤纶织物的表面电阻随电压的增加而减小,随时间的增加先减小后基本保持不变。金属锡铜镀层与涤纶织物之间的结合牢度良好,其摩擦牢度可达4～5级。该锡铜包覆涤纶织物对频率2 000～3 000 MHz电磁波的屏蔽可达99.999 99%,因此所制备的锡铜包覆涤纶织物不仅具有良好的电磁屏蔽性能,而且通过电镀锡实现镀铜层防氧化的目的,有效地增强了化学镀铜涤纶织物的实用性。     

色织物两种小断纬的起因及预防

一种小断纬是出现在织口到胸梁的布面上,另一种小断纬是出现在导布辊引出的布面上.这两种小断纬都是全幅纬向分散性的无规律的、像边撑疵一样的小断纬,而且经后整理后小断纬增多.经过分析,认为第一种小断纬是因单纱强力不同的漂白纱混批造成的,第二种小断纬则是刺毛铁皮刺高所引起.详细介绍了相应的预防措施.     

微波消解原子荧光光谱法测定炼乳中的锡

研究了微波消解一原子荧光光谱法测定炼乳中的痕量锡，在最佳仪器条件下，考察了不同酸介质、KBH4质量浓度、酸介质质量浓度对锡检测结果的影响，并对测定锡时共存离子的干扰和消除进行了探讨，建立了盐酸作为介质，铁氰化钾为还原剂，草酸作为掩蔽剂的检测方法。本方法的线性范围为1.12～200μg／L，相关系数r〉0.999，检出限为1．1214μg／L，相对标准偏差为1.11％～1.89％，回收率为93.2％～102．4％。