清洁镀铬用紫色硫酸铬

紫色硫酸铬是一种新型清洁镀铬（Cr^3 镀铬）的原料，在镀铬中显示了优良的性能，特别是镀液无需预电解处理亦能得到满意镀层这一实验结论，使清洁镀铬工艺实现工业生产又向前迈进了一步，介绍了它的制法，技术要求，物相分析及使用效果。     

碱式硫酸铬中微量Cr(6价)的测定

采用磷酸三丁酯萃取分离碱式硫酸铬中CrO2-4与Cr3+,CrO2-4被有机溶剂萃取后直接显色,通过分光光度法进行定量分析。方法加标回收率为97 6%～99 1%,变异系数1 9%。     

改性凹凸棒土净化含铬废水的研究

将凹凸棒土进行改性处理，用于对含铬废水中铬离子的吸附。本文研究了改性方式、凹凸棒土用量、吸附时间、pH值对含铬废水中铬离子净化率的影响。     

制革工业污泥中Cr~(3+)的回收试验

对制革工业污泥中Cr回收与再利用进行了试验。试验表明:Cr的总回收率的高低主要决定于Cr3+的氧化是否彻底,在n(H2O2):n(Cr3+)为7.5,pH=10,温度为60℃以及反应时间为30min的条件下,污泥中Cr3+氧化率接近90%,总回收率可以达到80%以上。     

中国铬盐生产现状与发展建议

较全面地回顾了中国铬盐生产历史和现状，系统总结了铬盐行业发展过程中的经验教训，提出了中国铬盐生产发展的建议，即中国铬盐工业在大型化的同时，应推广采用新工艺、新技术；应开发新品种，进行深加工；应密切注意最新技术动向，并及时跟进。     

An economic and sensitive method for extracting chromium speciation in airborne inhalable dust,using a green sample treatment coupled with electrothermal atomic absorption

ABSTRACT

A new approach of cloud point extraction CPE procedure is optimized for hexavalent chromium determination in airborne dusts. Triton X-114 is used as a surfactant and 1-(2-pyridylazo)-2-naphthol as a specific complexing agent for the trivalent chromium’s removal from the aqueous phase to isolate hexavalent chromium compounds. The parameters influencing the extraction protocol (pH, surfactant concentration, and temperature are optimized. The obtained detection and quantification limits are 0.1 and 0.4 μg/L, respectively. The linearity is verified, with a regression coefficient close to 0.999 and the extraction recovery exceeds 99%. The method was successfully applied to analyze airborne samples collected from workplaces.     

微生物处理含铬(Ⅵ)废水的研究进展

文章综述了国内外微生物法处理含铬(Ⅵ)废水的研究进展，介绍了以非生物活性的微生物体为铬(Ⅵ)的吸附剂的失活微生物体吸附法及应用活体微生物的活体微生物法，活体微生物法在吸附剂的制备及处理效果等方面都具有更好的实际应用价值。文章同时指出了该法目前存在的一些问题，认为培养和应用高效工程菌是将来的发展方向。     

大块液膜技术处理含六价铬废水

以磷酸三丁酯(TBP)为载体,煤油为稀释剂,NaOH为反萃剂,采用大块液膜技术处理含95~100mg/LCr(VI)的模拟废水。考察了液膜相用量、载体体积分数及反萃剂浓度对大块液膜过程中Cr(VI)传质过程的影响。结果表明,大块液膜技术对废水中Cr(VI)的去除效果较好。Cr(VI)迁移速率随TBP体积分数的提高而加快。当反萃剂NaOH浓度大于0.5mol/L时,反萃剂浓度对Cr(VI)传质过程的影响较小。处理后废水中Cr(VI)含量降至0.5mg/L以下,达到国家排放标准。     

Activity–Composition Relations of Chromium Oxide in Silicate Melts at 1500°C under Strongly Reducing Conditions

The solubility and activity–composition relations of chromium oxide in melts of the systems CaO–CrO _x –SiO₂ and CaO–Al₂O₃–CrO _x –SiO₂ have been determined at 1500°C by equilibrating melts with Pt–Cr alloys at known oxygen pressures. It is shown that the increase in the concentration of divalent chromium ions, as the oxygen pressure and the basicity of melt decrease, results in a dramatic increase in the solubility of chromium oxide in the liquid phase. An increase in the Al₂O₃ content of the melt leads to a decrease in the solubility of chromium oxide over the whole composition range studied. The activity coefficient of CrO has been found to increase with increasing melt basicity and decreasing oxygen pressure whereas the activity coefficient of CrO_1.5 decreases sharply with increasing melt basicity for siliceous melts but levels off at a basicity ratio (wt% CaO/wt% SiO₂) of about 0.7. An increase in the Al₂O₃ content of the melts results in an increase in the activity coefficient of CrO.     

蒙脱土有机改性及对铬的吸附性能研究

对蒙脱土进行了有机改性.表征结果表明:有机基团已经进入到蒙脱石的结构之中(IR);改性后有机蒙脱土层间距为2.156 nm(XRD);晶层结构被解离,较疏松,层间被改性剂插层(TEM).以制备的有机蒙脱土对废水中的铬进行了吸附研究.结果表明,对铬吸附的最优化条件是:吸附时间为40 min,pH值为5,固液比为18 g/L,温度为40℃;此时,吸附率可达79%.