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Novel polypyrrole (PPy)/polydimethylsiloxane (PDMS) composite membrane was prepared by interfacial polymerization to make a very effective gas separation membrane. We found that Polymerized PPy films as thin as ~200 nm could be chemically synthesized as freestanding membranes by using the interfacial polymerization technique. Additionally, we show that difference morphology of PPys films was obtained by controlling polymerization rate and more dense films were formed at low polymerization rate. Wide X-ray diffraction study showed the d spacing value of the PPy film decreased from 4.89 å to 3.67 å by the rate of polymerization decreases. According to d spacing value decrease, selectivity of a PPy composite membrane was increased dramatically and permeability was reduced gradually. This high selectivity was derived from d spacing closed to the kinetic diameter of nitrogen. These results indicated that the permeability is controlled by the diffusion coefficient, reflecting the packed structure of the PPy film. The highest selectivity value of composite membrane that was prepared by interfacial polymerization was O2/N2=17.2 and permeability for O2 was 40.2 barrer. 相似文献
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为了研究分流叶片对离心泵内部固液两相流的影响,建立固液两相流模型,对无分流叶片离心泵和3种带分流叶片的离心泵进行全流道非定常数值模拟。重点分析了添加分流叶片对离心泵外特性、叶片表面压力脉动、叶片表面颗粒体积分数分布、叶片表面颗粒滑移速度的影响。分析结果表明:添加分流叶片以后,离心泵的扬程和效率均有显著的提高,叶片表面的颗粒分布更加均匀,叶片表面颗粒的滑移速度有不同程度的下降,使颗粒对叶片表面的磨损程度得以降低;当分流叶片的进口直径为0.65D2时,叶片出水边处的压力脉动幅值最小,减小了离心泵在运行过程中的振动和噪声。 相似文献
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简要介绍了石家庄炼油厂GHH公司生产的烟气膨胀机叶片国产化情况、使用中出现的问题以及改进方法,肯定了进口机组叶片国产化的工作思路。 相似文献
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Tests and numerical simulations of super-critical adjust stage blade were carried out and the effect of bowed blade on flow characteristics and the secondary flow were analyzed. The simulation and test results show that the adjust stage blade with aft-loading and big front-edge radius has good flow characteristics by meridian shrink. The numerical studies were carried out with software of NUMECA in order to investigate the aerodynamic characteristics of adjust stage blades,which include prototype blade(tested blade) ,positive curved blade (15°) and negative curved blade(-15°) . The simulation results show that the positive curved blade forms a negative static pressure gradient in the lower region of the cascade along the blade height and a positive static pressure gradient in the upper region. This leads to the reduction of the streamwise vortices intensity and the aerodynamic load on both sides of the blade and the endwall. Therefore,the crosswise secondary flow losses of endwall can be decreased considerably. 相似文献
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For a certain type of transonic axial fan, the flow field of a fan rotor with splitter blade was computed by numerical simulation, and the shape of the rotor was modified. The effects of different circumferential distributions concerning the splitter cascades upon the aerodynamic performance were investigated. The studies show that the optimum splitter cascade is not very close to the suction side of main blade. The load between the main blade and the splitter blade can be soundly distributed in terms of the adjustment of circumferential position of the splitter blade. The best aerodynamic performance can be successfully obtained according to the optimum shape of the expanding fluid channel reasonably formed by the splitter blade and the main blade. 相似文献
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To improve the performance of the Turbofan engine,several measures should be considered during design process.Such measures,relating to aerodynamic characteristic design,include the maximum enthalpy per stage,the shortest axial length,the minimum blade rows and the highest efficient in design and off design condition.To satisfy theses design characters,the meridian geometry of the engine will he excurvature at a high degree transition part between HP and LP turbines.The study is to investigate the effect of blade bowing on flow loss at blade tip and root of the type of turbine.Such turbine,tending towards separation,with severe secondary flow at the tip and strong radial flow at exit,was simulated by the 3D N-S solver Numerea,and there were several different stacking line bowing schemes in all.The results show that tip negative bowing and root positive bowing is able to weaken radial flow,consequently reduce the flow loss at the tip and root. 相似文献
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基于流固耦合的叶片动力特性分析 总被引:2,自引:0,他引:2
在考虑耦合流场与旋转预应力条件下,建立了对应的叶片流固耦合系统的动力特性方程.采用ANSYS与FLUENT对整体叶片的耦合模态进行了计算,并利用实验获得气流压力脉动数据,对叶片振动进行了瞬态分析.结果表明:在旋转预应力与耦合流场压力作用下,叶片模态频率约有9Hz的上升,模态振型的最大位移位置点转移,振动方向改变,前三阶相对振幅分别从29.128,19.400,44.566下降到28.945,19.285,44.562;叶片最大变形和加速度位于前缘的上端,最大应力点集中在叶片根部一侧. 相似文献