化学还原法制备纳米铜粉的研究

本文采用KBH4在液相中化学还原CuSO4,并加入KOH和络合剂EDTA ,制得了纳米级的纯净的铜粉 ,通过调整反应物的浓度 ,可以消除Cu2 O等杂质。制备的纳米铜粉还存在一定程度的团聚 ,需试验加入分散剂来改善。     

Aero-Acoustics of Modern Transonic Fans—— Fan Noise Reduction from Its Sources

The noise of aerodynamics nature from modern transonic fan is examined from its sources with the perspective of noise reduction through aero-acoustics design using advanced Computational Fluid Dynamics (CFD) tools. In particular the problems associated with the forward propagating noise in the front is addressed. It is identified that the shock wave spillage from the leading edge near the fan tip is the main source of the tone noise. Two different approaches have been studied to reduce the forward arc tone noise and two state-of-art transonic fans are designed using the strategies developed. The following rig tests show that while the fans exhibit other noise problems, the primary goals of noise reduction have been achieved through both fans and the novel noise reduction concept vindicated.     

一种复合型数值方法的改进与算法实现

文中对原有的复合方法进行了改进,提出了一种新的复合型数值方法,这种方法解决了原方法求解含源项的问题时存在数值震荡的缺点。为了验证算法的有效性,对计算流体力学中一阶浅水波问题的两个典型的算例进行了数值模拟,在解的光滑性、锐利性等几个方面做了分析,结果表明改进后的方法既消除了数值震荡现象,又能准确地逼近真解,求出锐利的间断,是一种行之有效的数值方法。     

薄板坯连铸生产SS400钢工艺技术研究

对唐钢薄板坯连铸机生产的SS400钢的生产工艺进行了分析,认为薄板坯连铸机生产的SS400钢,在采取了精炼站在线定氧,将钢水全氧控制在25×10~(-6)左右,同时连铸采取保护浇注和轻压下等技术后,能够确保薄板坯连铸SS400钢的顺利浇注,轧制的板带材表面质量良好,机械性能符合要求。     

Catalytic reduction of N2O with CH4 and C3H6 over Ag–Rh/Al2O3 bimetallic catalyst in the presence of oxygen

A study of nitrous oxide (N₂O) reduction with methane (CH₄) and propene (C₃H₆) in the presence of oxygen (5%) over Ag/Al₂O₃, Rh/Al₂O₃ and Ag–Rh/Al₂O₃ catalysts, with Ag and Rh loadings of 5 wt% and 0.05 wt% respectively, has been performed. From the results, it was observed that the Ag–Rh bimetallic catalyst was the most active for both nitrous oxide removal (more than 95%) and hydrocarbon oxidation. This high activity seems to be connected with a synergistic effect between Ag and Rh. The findings from X‐ray diffraction and X‐ray photoelectron spectroscopy studies showed also, that there were no strong interactions (eg alloying) between Ag and Rh. Copyright © 2005 Society of Chemical Industry     

Deactivation of V2O5-WO3-TiO2 SCR catalyst at a biomass-fired combined heat and power plant

The deactivation of a commercial type V₂O₅-WO₃-TiO₂ monolith catalyst under biomass combustion was studied at a full-scale grate-fired power plant burning straw/wood using a slip stream pilot scale reactor. The aerosols in the flue gas consisted of a mixture of potassium chloride and sulphate. Three catalyst elements were exposed at 350 °C, and one element was exposed at 250 °C for comparison. The catalyst activity was measured in the reactor at the exposure temperature by addition of NH₃ and extra NO. The activity, in terms of a first-order rate constant, dropped by 52% after about 1140 h indicating a very fast deactivation compared to coal firing. It was also found that the reactor temperature was not of importance for the deactivation rate. SEM-EDX analysis showed that particle deposition and pore blocking contributed to the deactivation by decreasing the diffusion rate of NO and NH₃ into the catalyst. However, potassium also penetrated into the catalyst wall and the resulting average K/V ratio in the catalyst structure was high enough (about 0.3–0.5) for a significant chemical deactivation. Chemisorption studies carried out in situ showed that the amount of chemisorbed NH₃ on the catalyst decreased as a function of exposure time, which reveals that Brøndsted acid sites had reacted with potassium compounds and thereby rendered inactive. When washed by 0.5 M H₂SO₄ the regenerated catalyst regains a higher activity than that of the fresh catalyst at temperatures higher than 300 °C, but even though reactivation is possible, the deactivation rate appears too high for practical use of the SCR process in straw combustion.     

裂隙岩体边坡稳定性的渗流与应力耦合分析

用裂隙岩体渗流与应力耦合分析的四自由度全耦合法对岩质边坡进行耦合分析,通过强度折减有限元法求解岩体边坡的稳定安全系数。四自由度全耦合法建立了同时以渗流水压和位移为未知量的耦合方程组,使得渗流场与应力场的求解能够一次性完成,与两场交叉迭代分析方法相比达到了彻底的完全耦合。通过强度折减,整个系统达到不稳定状态,有限元计算将不收敛,此时的折减系数就是安全系数。算例表明由此求得的边坡稳定安全系数和滑动面都与传统方法十分接近。     

消减空压机气流脉动方法的探讨

根据气流脉动的机理，提出了解决空压机常见的机组枷管过振动问题的一些具体措施。     

论BFe30—1—1冷凝管生产工艺及其改进的途径

论述了ＢＥｅ３０－１－１冷凝管生产工艺的优点及主要问题，对现行工艺提出了改进方案。     

直接还原在当代冶金变革中的发展

简述了当代的直接还原现状与方法，论述了直接还原是发展短流程的重要基础，直接还原也是熔融还原法的重要组成，同时分析了发展直接还原与熔融还原是当代世界冶金变革中的重要方向之一，也是中国面向２１世纪的重大任务。