Interfacial energy for solutions of nanoparticles,surfactants, and electrolytes

The addition of surfactants to modify the surface property of nanoparticles (NPs) from hydrophilic to hydrophobic also enhances their interfacial properties. Several approaches were previously proposed to calculate the surface tension/interfacial tension (IFT) for different systems in the presence of NPs, surfactants, and electrolytes. However, most of these approaches are indirect and require several measured parameters. Therefore, a mathematical model is developed here to calculate the surface tension/IFT for these systems. The developed model takes into account the cohesive energy due to the interaction of the surfactant CH₂ groups, the electric double layer effect due to the interaction among the ions of NPs, surfactants, and electrolytes, and the dipole–dipole interaction of NPs and electrolytes. The developed model is compared and validated with the laboratory experimental data in literature. The results reveal further understanding of the mechanisms involved in stabilization of oil/water emulsion in the presence of NPs, surfactants, and electrolytes.     

基于VOF模型的层叠器流动过程分析及流道结构优化

基于FLUENT软件的流体体积(VOF)模型研究了不同壁面滑移程度以及不同流道结构参数下4层等厚熔体通过层叠器倍增为8层熔体时,流道中熔体的分层情况变化。结果表明,壁面滑移程度的降低会促使熔体在上下壁面聚集,进而导致上下壁面处熔体层厚增加;汇流段与出口段间圆角半径、汇流段扩压角和平衡段长度这3个结构参数则只会影响熔体在左右壁面的聚集,进而影响各层熔体的尺寸精度,且其中扩压角的影响程度最大,平衡段长度次之,圆角半径的影响较小。     

A 1D High Performance Thin Layer Chromatography Method Validated to Quantify Phospholipids Including Cardiolipin and Monolysocardiolipin from Biological Samples

The aim of this study is to identify high performance thin layer chromatography (HPTLC) conditions allowing the separation and quantification of mammalian cellular phospholipids (PLs) (sphingomyelin, phosphatidylcholine, phosphatidylserine, phosphatidylinositol, phosphatidylethanolamine, and especially phosphatidic acid, cardiolipin, and monolysocardiolipin, these latter two being specifically located in mitochondria membranes). In order to make this method faster and easier, a 1D HPTLC method is chosen, testing several eluents as well as several staining methods. A pre‐conditioning of HPTLC plates with boric acid and a copper staining reagent followed by carbonization are selected for the quality of PL separation and homogeneity of staining. The selected conditions are discussed and the method validation is performed according to the International Conference on Harmonization guidelines. Linearity is effective between 1 and 8 µg and limit of quantification is between 0.5 and 2.3 µg depending on PL classes. Precision measurements show coefficients of variation <6%, and when amounts are close to the detection limit, <12%. Lipid extracts of tumor cell lines or isolated mitochondria are used to assess PL profiles. This shows that the HPTLC method can be used routinely to follow level variations of PLs. Practical Applications: The changes in PL composition play a crucial role in tumor processes and regulate cellular functions modulating cellular signaling or mitochondrial metabolism. The simple and cost‐effective 1D HPTLC method that is developed is applied to lipid extracts of whole tumor cells or hepatocyte‐isolated mitochondria. It is sensitive as well as precise to detect variations of phosphatidic acid or cardiolipin levels linked to physio‐pathological conditions. It can also be used to investigate the composition changes of other membrane PLs. Moreover, with a simultaneous analysis of 14 samples/standards on the same plate (six plates per day), this method is adapted for large series of samples.     

Ni对铁基合金粉块氩弧堆焊层组织和性能的影响

通过氩弧焊在基体材料Q235钢板上熔敷铁合金混合粉末压块,研究了压块成分及堆焊工艺对堆焊层组织及性能的影响。结果表明:在固定压块粉末总质量为16 g、镍铁含量为0.64 g、堆焊电流为180 A时,堆焊层的硬度最大,达到HRC48.9;耐磨性最高,相对磨损量为0.013 4 g/(cm^2·min)。     

高瓦斯矿井回采工作面瓦斯综合抽采技术实践

为了解决高瓦斯矿井工作面瓦斯涌出量大、瓦斯浓度高,制约工作面安全生产的问题,以亨元煤业为背景,结合矿井开采及瓦斯地质条件,确定了本煤层顺层钻孔抽采、穿层钻孔抽采邻近层和覆岩裂隙带瓦斯、以及对上隅角布置抽采管路进行抽采的综合治理方法。试验表明,工作面开采期间瓦斯涌出正常,上隅角瓦斯浓度保持在0.56%以下,实现了工作面安全高效开采。     

煤层软硬分层吸附瓦斯性能差异性及其对瓦斯赋存的影响

为研究煤层软、硬分层吸附瓦斯性能差异性及其对瓦斯赋存的影响,分析了煤层内软分层的形成机理及结构特征,采集了我国多个煤与瓦斯突出矿井的煤样作为试验对象,应用高压容量法开展了软、硬分层煤样吸附瓦斯性能参数的对比试验,探讨了软煤、硬煤吸附性能的差异性。在此基础上,对煤层软、硬分层吸附瓦斯性能差异性与瓦斯赋存特征之间的关联进行了研究,结果表明:试验煤样软分层的极限吸附量均大于硬分层;随着瓦斯压力的增加,试验煤样软、硬分层瓦斯含量的差值逐渐增大,其曲线的变化特征与Langmuir方程类似,并且软、硬分层瓦斯含量数值的差异主要由吸附量差值构成;煤层软、硬分层吸附瓦斯性能的差异不仅对煤层原始瓦斯赋存特征有着显著的影响,同时还将影响煤巷掘进、瓦斯抽采过程中煤体内瓦斯流场的分布规律,需要根据煤层软、硬分层的组合特点,制订切实有效的瓦斯抽采技术方案。     

利用表面硬度值间接获取镐形截齿钎焊层力学性能的方法研究

利用维氏硬度实验和数值模拟相结合的方法,间接得出了截齿表面各区域材料所对应的屈服强度值,建立了一种由实验硬度值HV获取截齿焊接接头等不易测量区域力学性能参数的方法。     

高边坡开挖卸荷过程强度折减法分析

针对露天矿开采过程中边坡变形破坏严重影响露天矿安全生产的问题,采用数值模拟的方法,应用MidasGTS NX软件建立重钢太和露天铁矿黄家山高边坡三维模型,进行开挖卸荷过程中的应力应变、位移及安全系数变化的数值模拟分析。结果表明：边坡岩体开挖卸荷过程中,随着采场的延深,边坡角的增大,塑性应力带的逐渐向边坡岩体内部扩大,风化破碎层及上部冰碛土层之间产生塑性应变贯通区,破坏面形成。开挖完成后整体边坡坡脚处发生剪切破坏,坡顶后缘形成张拉破坏区,边坡上部冰碛土层形成 “坐落—滑移”式滑动。边坡安全系数随向下开挖过程逐级降低,最终达到1.15稍显偏低。后期开采过程中,需对边坡中上部风化破碎岩层及冰碛土进行加固措施。     

基于温度冲击的冷冻靶氘氘冰层结晶生长行为研究

惯性约束聚变冷冻靶中氘氘（D₂）冰层的质量对聚变实验的成功与否起重要作用。目前文献报道的制备冷冻靶D₂冰层的方法并不具备好的可操作性,且技术、工艺不定型,制约了高质量冰层的形成。因此,本文采用将温度梯度、降温速率和温度冲击相结合的技术实现燃料冰层在靶丸内的均化。通过温度控制以及施加温度冲击可控地形成残留冰,并在残留冰的控制技术基础上,实现了高质量冰层的可控结晶生长。同时,研究了温度控制对靶丸内D₂冰层品质的影响和D₂冰层结晶生长的过程,并应用晶体生长动力学理论分析了D₂冰层结晶生长行为。从背光阴影图像中的D₂冰层亮环可知,D₂冰层均匀度为85.2%、厚度为40.35 μm、内表面粗糙度为2.15 μm。本方法拓宽了超低温下D₂冰籽晶控制、晶体生长技术,为DT冷冻靶中冰层均化打下了坚实基础,并形成了一定的技术储备。     

青藏高原铁路多年冻土路堤的碎石层高度

分析表明路堤尺寸、形状和边界形式对碎石路堤自然对流效应的发生有显著影响,需要根据具体工程要求来确定路堤的压力边界条件。对4种压力边界情况的碎石路堤自然对流进行了数值计算,显示透气边界的碎石路堤自然对流降温效应为最强。最后,通过引入自然对流指数,提出了实际冻土路堤碎石层填筑高度的确定方法,具体给出了粒径为2cm~4cm、4cm~6cm、6cm~8cm和8cm~10cm的碎石层填筑高度,并对粒径为6cm~8cm的碎石层填筑高度进行了实验验证,结果表明,通过自然对流指数所确定的碎石层高度对实际冻土路堤工程的设计具有参考价值。