A surface modification layer capable of tolerating substrate contamination on transparent electrodes of organic electronic devices

An organic molecule, hexaazatriphenylene hexacarbonitrile (HAT-CN), is found that it can be used not only as a hole-injecting material but also a surface modification material to clean contaminated substrate electrodes for the fabrication of organic electronic devices. As an example, HAT-CN can modify or “clean” indium-tin-oxide (ITO) anode surface in organic light-emitting diodes (OLEDs). Negative effect from ITO surface contamination on the electroluminescence performance of OLEDs can be dramatically reduced with this modification layer. As a result, the OLEDs with the same device architecture but with different ITO surface conditions, even with intentional contamination, can all exhibit substantially identical and superior electroluminescence performance. The surface modification function of this material is feasibly useful for the real fabrications of OLEDs as well as for advanced research on other organic electronic devices.     

Effects of annealing on Zr8Ni19X2 (X = Ni,Mg, Al,Sc, V,Mn, Co,Sn, La,and Hf): Hydrogen storage and electrochemical properties

The effects of 8-h annealing at 960 °C on the gaseous phase hydrogen storage and electrochemical properties of partial-Ni substituted Zr₈Ni₂₁ alloys were studied. The substituting elements included Mg, Al, Sc, V, Mn, Co, Sn, La, and Hf. Only the main phase of the annealed Sn-substitution remained Zr₈Ni₂₁-structured while those of other substitutions turned into Zr₇Ni₁₀ or Zr₂Ni₇. The observed trend in maximum gaseous phase hydrogen storage capacity followed the increasing order of B/A ratio of the main phase as orthogonal Zr₇Ni₁₀ > tetragonal Zr₇Ni₁₀ > Zr₈Ni₂₁ > Zr₂Ni₇. After annealing, due to the increase in abundance of the main phase, the maximum gaseous phase hydrogen storage capacities of alloys with higher capacities before annealing increased while others decreased. The full discharge capacity also improved in the same increasing order of B/A ratio in the main phase. Hf-substitution showed the highest electrochemical discharge capacity at 200 mAh g⁻¹. After annealing, all alloys with the same main phase as the as-cast alloys showed degradation in full electrochemical capacity due to the reduction in both number and abundance of the catalytic secondary phases. All supplements assisted in improving surface exchange current from the base binary Zr₈Ni₂₁ alloy. Except for La- and Hf-substitutions, annealing reduced the surface exchange current density. The bulk hydrogen diffusion coefficient decreased with most of the supplements except for V- and Sn-substitutions. All supplements, except for Sc, showed improvement in the bulk diffusion after annealing. Furthermore, the maximum gaseous phase hydrogen storage capacity showed a strong correlation to the full electrochemical discharge capacity. Among all alloys in this study, the as-cast Hf-substituted Zr₈Ni₂₁ alloy demonstrated the best overall gaseous hydrogen storage and electrochemical properties.     

Preparation of bismuth nanowire encased in quartz template for Hall measurements using focused ion beam processing

ABSTRACT: Forming electrodes on opposite sides of an individual bismuth nanowire was attempted to prepare for Hall measurements. Although a 1-mm-long bismuth nanowire which is completely covered with a quartz template has been successfully fabricated to prevent oxidation, it is very difficult to attach Hall electrodes on the opposite sides of the nanowire due to the quartz covering. One side of the cylindrical quartz template was removed by polishing without exposure of the nanowire to the atmosphere; the thickness between the polished template surface and the nanowire was estimated to be several micrometers. Focused ion beam processing was successfully employed to expose both surfaces of the nanowire under high vacuum by removing part of the quartz template. A carbon thin film was then deposited in situ on the wire surface to fabricate an electrical contact on the bismuth nanowire sample. Furthermore, the energy dispersive X-ray analysis was performed to the area processed by focused ion beam, and the bismuth component of the nanowire was successfully detected. It was confirmed that the focused ion beam processing was applicable to attach electrodes to bismuth nanowire for Hall measurement.     

海河大桥横隔梁有限元分析

以海河大桥为工程实例,探讨了横隔梁的结构安全性,运用ANSYS建立了实体单元进行模拟,得出了横隔梁的应力分布规律,以了解其力学行为,为横隔梁的配筋提供依据。     

A Study of Mutual Coupling between Vertical Grounding Electrodes

This paper investigates the mutual grounding impedance between vertical grounding electrodes based on field measurements and FDTD simulations. In the case of vertical electrodes, the mutual impedance between the electrodes is almost completely independent of the electrode length, and thus the induced voltage is nearly constant as the electrode length becomes longer. This characteristic is different from that of an overhead conductor, where the electromagnetic‐induced voltage is proportional to the conductor length. The greater the separation distance between the electrodes, the smaller the induced voltage, as in the case of an overhead conductor. The propagation speed increases as the separation increases. It is found that the speed is not necessarily proportional to the inverse of the relative permittivity of the earth.     

Oxygen influenced intergranular crack propagation: analysing microstructure and chemistry in the crack tip region

Abstract

Ni-base superalloys have for decades been studied with regard to environmentally influenced intergranular crack propagation. For high temperature fatigue frequencies <0.1 Hz, it has been shown that an oxygen-rich environment promotes time-dependent crack growth while at >0.1 Hz and/or in inert environments (e.g. vacuum) crack growth is cycle dependent. Oxygen interaction at, or ahead of, the crack tip has been pointed out as the reason for the degraded mechanical properties. While many aspects of this type of crack growth have been previously investigated there is still no consensus about the detailed mechanisms, mainly due to the lack of in-detail investigations of the crack-tip region.

Here, crack tip regions in the Ni-base superalloy Alloy 718 were studied. Specimens were subjected to 90 s hold-times at 550°C and 650°C. Crack growth was arrested before final fracture, allowing cross-sectional analyses of the crack-tip region using scanning electron microscopy (SEM). Detailed studies of the crack-tip region were performed using transmission electron microscopy (TEM) and atom probe tomography (APT). For both APT and TEM samples, site-specific focussed ion beam (FIB) sample preparation was performed in a combined FIB-SEM system. The methodology of accessing and analysing the crack tip region is shown. Initial results on oxidation, oxygen penetration and plastic deformation are shown and discussed.     

Momentum in nonlinear optics

Abstract

Although it is well known that light carries momentum and exerts a pressure on objects, a conservation of momentum principle is apparently rarely used in optics. In nonlinear optics light waves interact and may exchange both energy and momentum. We demonstrate that a conservation of momentum principle holds in these cases and in fact its use is widespread but generally unrecognized in the standard mathematical methods. In both the cases of linear basis waves interacting nonlinearly, e.g. coupled-wave theory and frequency mixing, and fully nonlinear waves, we demonstrate that a governing Hamiltonian is related to momentum. Action principles are used to discuss the generality of these results.     

Development of a Compact and User-friendly Ion Irradiation System Controlled Remotely through the Internet

A compact and user-friendly ion irradiation system controlled remotely through the Internet was developed for the execution of collaboration experiments together with researchers at remote sites. Several hardware instruments and software programs were constructed and provided for the remote control of the system and for its connection to the Internet. Surface modification and analysis experiments with this system were remotely performed through the Internet. It was confirmed from the experiments that the present ion irradiation system was precisely controlled through the Internet and could be easily and safely used for the surface modification and analysis, that the normal communication speed of around 10Mbps for the Internet was fast enough for the execution of such typical remote-controlled experiments, and also that an access to the system by a mobile phone was convenient and useful enough to check the condition of the system and experimental data.     

Effects of water chemistry and potential distribution on electrochemical corrosion potential measurements in 553 K pure water

The effects of water chemistry distribution on the potential of a reference electrode and of the potential distribution on the measured potential should be known qualitatively to obtain accurate electrochemical corrosion potential (ECP) data in BWRs. First, the effects of oxygen on a platinum reference electrode were studied in 553 K pure water containing dissolved hydrogen (DH) concentration of 26–105 μg kg^?1 (ppb). The platinum electrode worked in the same way as the theoretical hydrogen electrode under the condition that the molar ratio of DH to dissolved oxygen (DO) was more than 10 and that DO was less than 100 ppb. Second, the effects of potential distribution on the measured potential were studied by using the ECP measurement part without platinum deposition on the surfaces connected to another ECP measurement part with platinum deposition on the surfaces in 553 K pure water containing 100–130 ppb of DH or 100–130 ppb of DH plus 400 ppb of hydrogen peroxide. Measured potentials for each ECP measurement part were in good agreement with literature data for each surface condition. The lead wire connecting point did not affect the measured potential. Potential should be measured at the nearest point from the reference electrode in which case it will be not affected by either the potential distribution or the connection point of the lead wire in pure water.