以“新发展理念”引领地勘行业持续健康发展

"十二五"以来,地勘行业在服务和支撑经济社会发展中的地位与作用越发凸显。"十三五"时期是全面建成小康社会的决胜时期,地勘行业面临一系列的机遇与挑战。本文在总结"十二五"地勘行业发展成效的基础上,深入分析全面建成小康社会决胜阶段地勘行业面临的新形势、新要求,提出以创新发展激发地勘行业发展新动力、形成地勘行业发展协调新格局、探索地勘行业绿色发展新模式、开拓地勘行业开放发展新空间、最终共享地勘行业发展新成果的建议。     

13X沸石用于硬水软化的研究

利用由河北赤城县金矿尾矿合成的 13X沸石 ,进行了吸附硬水中Ca2 + 、Mg2 + 的实验研究。实验结果表明 ,13X沸石具有较好的硬水软化性能 ,当溶液为中性或弱酸性时 ,Ca2 + 、Mg2 + 的初始浓度分别为 392 4mg·L-1和 10 6 9mg·L-1,按沸石用量 1 0 0 g进行吸附 ,Ca2 + 、Mg2 + 的吸附率可达 98%和 94 %。     

Ti02／13X分子筛的合成、表征及催化脂肪氧化的研究

以钾长石与碳酸钠焙烧的热料为原料,经水热法合成13X型分子筛。进一步经溶胶一凝胶化过程和13X分子筛上负载TiO2以制稀TiO2／13X,并利用XRD、FTIR、SEM和EDS等对儿结构与性能进行表征。将13X和TiO2／13X用于催化脂肪氧化,测定氧化脂肪的过氧化值、p-茴香胺值和酸值,并以总钒化值和p-1茴香胺值作为反戍转化牢和选择性的评价参数,考察了催化剂的催化性能。结果表明,Ti／13X催化脂肪氧化的转化率和选择性者都远高于13X。此外,还研究了催化反应条件如温度、时间、空气流量等对催化反应的影响。     

超级13Cr不锈钢腐蚀性能的研究现状与进展

针对超级13Cr不锈钢管材料在各种环境下所面临的腐蚀问题,介绍了其CO2腐蚀机理及其影响因素,分析了腐蚀产物膜成分破坏机理,简要说明了超级13Cr不锈钢几种常见的腐蚀类型,并提出了今后超级13Cr不锈钢及其腐蚀行为研究的重要方面,为今后油套管材料提供参考。     

CuCI负载型吸附剂吸附CO的研究

利用Cu＋能与C0结合形成羰基络合物,将Cu＋盐负载到分子筛表面,经过热处理能达到自发单层分散状态,有效提高了C0的吸附量。利用直接混合法将CuCl负载于13X分子筛表面上制备高效的CO专用吸附剂。实验结果表明,将样品置于管式炉内,流动N2氛围保护下,在350℃焙烧4h后,CuCl／13X质量比0．4：1．0吸附剂表现出较好的吸附性能,C0吸附量可迭45mL／g,对工业分离混合气体有重要的意义。XRD也显示,不同质量比的CuCl／13X样品,在N2氛围中350℃焙烧4h后,CuCl晶相峰从有变无,说明CuCl均匀分散于栽体表面,提供了更多的与C0络合的铜离子活性中心,进而提高了吸附剂对C0的吸附量。     

珠江口盆地陆丰13东洼新生代构造演化与油气成藏特征

陆丰13东洼是珠江口盆地油气勘探的重点区域。结合区域构造背景,在精细解释高品质三维地震资料的基础上,对陆丰13东洼的洼陷结构和构造特征进行综合分析,并运用平衡剖面技术对洼陷的构造演化进行了恢复与研究,探讨了构造演化对圈闭形成与成藏的影响。研究结果表明：(1)陆丰13东洼新生代构造演化可划分为早—中始新世断陷、晚始新世断坳转换、渐新世—第四纪区域热沉降坳陷等3个阶段,其中断陷阶段具有完整的断陷旋回,根据断陷活动的强弱可进一步划分为断陷初始期、断陷高峰期、断陷萎缩期,断陷初始期和断陷萎缩期储层较为发育,断陷高峰期烃源岩较为发育。(2)在多期次构造活动的影响下,陆丰13东洼新生代形成了多种类型的圈闭,包括披覆背斜圈闭、断背斜圈闭、断块圈闭、断鼻圈闭、构造-地层圈闭（削截、超覆）、构造-岩性圈闭。众多的圈闭类型表明研究区油气勘探潜力巨大,特别是断陷阶段与断坳转换阶段沉积的文昌组和恩平组均发育大量各类型圈闭,且邻近优质烃源岩,成藏条件优越,是陆丰13东洼油气勘探的重点层系;平面上,南部缓坡带发育圈闭类型及数量最多,其次是中央隆起带与低凸起,均是研究区油气勘探的重要区带。     

Strengthening boron carbide through lithium dopant

The high strength of boron carbide (B₄C) is essential in its engineering applications such as wear-resistance and body armors. Here, by employing density functional theory simulations, we demonstrated that the strength of B₄C can be enhanced by doping lithium to boron-rich boron carbide (B₁₃C₂) to form r-LiB₁₃C₂. The bonding analysis on r-LiB₁₃C₂ indicates that the electron counting rule (or Wade's rule) is satisfied in r-LiB₁₃C₂ whose formula can be written as r-Li⁺(B₁₂)^2-(CB⁺C). The shear deformation on r-LiB₁₃C₂ indicates that its ideal shear strength is larger than that of B₄C because of the existing of Li dopant. The failure process of r-LiB₁₃C₂ under ideal shear deformation initiates from breaking the icosahedral-icosahedral B-B bonds. Then these B atoms react with the middle B in the C-B-C chain, resulting in the disintegration of icosahedral clusters and brittle failure. More interesting, the nanotwinned r-LiB₁₃C₂ is even stronger than r-LiB₁₃C₂ because of the directional nature of covalent bonding at the twin boundaries. This suggests that the nanotwinned r-LiB₁₃C₂ has a significant enhanced strength compared to B₄C. Our simulation results illustrate the deformation mechanism of Li-doped boron carbide and its nanotwinned microstructure. We proposed to improve the strength of boron carbide by doping Li into B₁₃C₂ and increasing its twin densities.     

Quantification of Mixtures of C2 and C3 Hydroxy Acids and Products of Glycerol Oxidation by High-Performance Liquid Chromatography and Quantitative 13C NMR

The aim of this study was to develop an improved general method for detecting and quantifying mixtures of hydroxy acids and other products of glycerol oxidation in aqueous media, to prevent the confusions that can occur due to similarities and interactions between these compounds depending on media conditions. Standard potential products of glycerol oxidation—glycerol, glyceraldehyde, dihydroxyacetone, glyceric acid, lactic acid, glycolic acid, glyoxylic acid, oxalic acid, tartronic acid, and mesoxalic acid—were analyzed by high-performance liquid chromatography (HPLC) and quantitative ¹³C nuclear magnetic resonance (NMR), in mixtures of known composition. The results obtained were concordant with the known compositions tested. HPLC was more accurate than quantitative ¹³C NMR for simple mixtures, but ¹³C NMR was required for complex mixtures containing dihydroxyacetone and glycerol, oxalic acid and mesoxalic acid, or glyoxylic acid and tartronic acid, pairs of compounds not well separated or detected by HPLC. As proof-of-concept, an unknown mixture generated by glycerol oxidation was analyzed by HPLC and quantitative ¹³C NMR. The results obtained were concordant and allowed accurate determination of the composition of the sample, which contained mesoxalic acid as the major product, with oxalic acid, tartronic acid, and glyceric acid as by-products.     

基于iSCSI网络存储协议的映射SCSI磁盘启动方法

文章基于iSCSI网络存储协议研究开发了一种新的远程启动技术。首先扩展DHCP选项以便从应答包中获得iSCSI登录参数,针对扩展ROM运行特点,设计了一种简洁、高效、且对存储资源要求很少的iSCSI启动器,该策略基于数据收发共同维护同一个4KB的缓冲区,且严格按序执行命令发送和接收相应命令的响应,保证了原子性操作,不会出现发送缓冲和接收缓冲数据被覆盖现象。设计了磁盘访问重定向服务和引导连接向量,按上述方法开发设计了iSCSIBIOS并应用于无本地存储设备的刀片服务器上,真正做到网络启动和网络存储,便于安全管理和升级维护。     

AC-13级配钢渣沥青混合料粘弹塑本构模型研究

为了研究钢渣沥青混合料非线性粘弹塑性变形特性,提出Schapery模型与改进Swchartz模型组合的积分型粘弹塑本构模型。采用钢渣替换AC-13级配中粒径2.36 mm以上的石灰石粗骨料,制作得到钢渣沥青混合料试件。设计并开展一系列的单轴压缩蠕变实验,通过应力递增蠕变回复实验,获得不同应力条件下材料的弹性、粘弹性应变和粘塑性应变,进而拟合确定本构模型参数。利用0.4 MPa、1.0 MPa下的蠕变回复实验验证模型有效性。结果表明,模型不仅能准确刻画钢渣沥青混合料蠕变过程中的弹性、粘弹性与粘塑性变形,还可用于预测不同应力水平下钢渣沥青混合料蠕变变形规律。