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31.
Li-Na Zhu Lei Z. Zhang Wen-Zhen Wang Dai-Zheng Liao Peng Cheng Zong-Hui Jiang Shi-Ping Yan 《Inorganic chemistry communications》2002,5(12):434
A novel coordination polymer [Zn(BDC)(H2O)2]n 1 (where BDC = 1,4-benzenedicarboxylate), has been synthesized and characterized by X-ray diffraction. 1 crystallizes in the monoclinic space group C2/c, a=15.09(2) Å, b=5.058(7) Å, c=12.196(16) Å, β=103.62(2)°,
, Z=4. The most striking feature of 1 is that it consists of a high-dimensional network structure constructed from BDC-bridged 1-D chains via interchain hydrogen bonds. The coordination sphere of the zinc(II) ion is a distorted tetrahedron completed by four oxygen atoms from two water molecules and two BDC ligands. BDC adopts the bis-monodentated (syn–anti) coordination mode linking two adjacent zinc(II) ions. 1 shows strong blue photoluminescence as the result of the fluorescence from the intraligand emission excited state. 相似文献
32.
介绍一次性使用无菌注射器用橡胶塞的化学分析方法。在适宜的酸度条件下,用碘量法测定易氧化物;重金属含量通常是测其硫化物的含量来判定的,本方法是采用硫代乙酰胶试剂作沉淀剂;锌离子能与亚铁氰化钾溶液及应生成白色络合物沉淀,因此采用亚铁氰化钾比浊法测其锌含量;利用硫氰酸铵比色法测其铁含量。本方法操作具体,比色明显、定量明确,对试样的测定得到了满意的结果。 相似文献
33.
Jolanta ?wiatowska-Mrowiecka 《Electrochimica acta》2005,50(9):1829-1840
Anodic dissolution of poly- and single-crystals of zinc was performed in methanol solution of lithium perchlorate by means of cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The mechanism of anodic dissolution of zinc in organic solvents occurs in two oxidation steps. It is the first step that surface anodic product is created. Stability of the surface product is much better in anhydrous organic environments than in aqueous media; because the product is stable, a barrier layer composed of is formed at low anodic overvoltage. The formation of the layer is much stronger on the low index than on the high-index plane (0 0 0 1), where the adsorption of anodic product is more difficult. 相似文献
34.
Following our previous papers on mechanism of cyclic esters' polymerization coinitiated by tin(II) octoate [tin(II) bis-(2-ethylhexanoate), (Sn(Oct)2)] in the presence of either the low molar mass coinitiator (an alcohol, hydroxy acid, or H2O) or a macromolecule fitted with a hydroxy end group (ROH), the present work deals with ?-caprolactone (CL) and l,l-lactide (LA) polymerizations coinitiated with zinc octoate (Zn(Oct)2) or aluminum acetylacetonate (Al(Acac)3). A series of kinetic measurements revealed that similarly as in the Sn(Oct)2 coinitiated process, these polymerizations proceed by simple monomer insertion into the …Mt-OR bond, reversibly formed in the reaction -Mt-L + ROH ? …-Mt-OR + LH (where Mt = Sn, Zn or Al; L = Oct or Acac), taking place throughout the whole polymerization process. MtLn itself does not play an active role in the polymerization. Applicability of the commercially available Zn(Oct)2 or Al(Acac)3 for the aliphatic polyester (103 ≤ Mn ≤ 4 × 105) synthesis is also discussed. 相似文献
35.
《Journal of the European Ceramic Society》2021,41(15):7807-7815
The present work aimed to reduce the microstructure heterogeneity inherent to flash sintering by using alumina blankets as a thermal insulator around ZnO cylindrical samples during the sintering process, under different electric field conditions. Thermal insulation significantly reduced the flash onset temperature and the grain size heterogeneity. For higher electric fields, a temperature reduction as high as 480 °C was observed, which also led to lower densification. These findings were discussed in terms of changes in the heat loss dynamics coupled with the adsorbed water retention, both promoted by the applied thermal insulation. A model to estimate the temperature at stage III of flash sintering was proposed. The final temperature reached with thermal insulation did not differ significantly from the ones without it. Thus, thermal insulation could represent an alternative route to flash sinter materials with lower furnace temperatures with energy savings up to 78 % and a more homogeneous microstructure. 相似文献
36.
烧结型钕铁硼电镀锌工艺研究 总被引:3,自引:3,他引:3
研究了不同前处理工艺对烧结型钕铁硼电镀锌层性能的影响,通过对镀层孔隙率、结合力、耐蚀性等性能的测试,确定了封孔、除油、除锈、活化、浸锌、电镀锌工艺,得到了光亮、孔隙率低、结合力和耐蚀性强的镀层。 相似文献
37.
Effect of Fe-Zn alloy layer on the corrosion resistance of galvanized steel in chloride containing environments 总被引:2,自引:0,他引:2
In this study, the effect of Fe-Zn alloy layer that is formed during galvanizing process on the corrosion behavior of galvanized steel has been investigated. The galvanostatic dissolution of galvanized steel was carried out in 0.5 M NaCl solution to obtain the Fe-Zn alloy layer on the base steel. The alloy layer was characterized to be composed of FeZn13, FeZn7 and Fe3Zn10 intermetallic phases, which constitute the zeta, delta1 and gamma layers of galvanized steel, respectively. It was observed that the alloy layer has similar cathodic polarization behavior but different anodic polarization behavior compared to galvanized steel. The anodic current plateau of alloy layer was up to 100 times lower than that of galvanized coating. Corrosion test performed in wet-dry cyclic condition has shown that the alloy layer has lower corrosion rate as compared to galvanized steel. From the results of corrosion test of alloy layer and base steel, it was concluded that Zn2+ has positive effect on the protectiveness of the zinc corrosion products. The measurement of surface potential over the alloy/steel galvanic couple has confirmed the galvanic ability of alloy layer to protect both the alloy layer itself and the base iron during initial stage of atmospheric corrosion. 相似文献
38.
硅锰稀土元素对铸态锌基合金组织性能的影响 总被引:3,自引:0,他引:3
采用正交组合回归设计实验方法,研究硅、锰元素对持态锌基合金力学性能的影响规律。结果表明,硅、锰元素对锌合金的室温硬度、100℃硬度、抗压强度和冲击韧性都有显著影响。适当控制硅、锰含量、并加入稀土元素进行变质处理,可得到具有较高强韧性的耐磨锌合金。 相似文献
39.
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