纳米晶体硅量子点薄膜的制备及表征

利用激光烧蚀沉积法在n-Si（100）衬底上制备非晶硅（α-Si）薄膜，再经过高温退火技术处理使α-Si晶化成纳米硅晶体（nc—Si）量子点．利用拉曼（naman）L谱仪、X射线衍射仪（XRD）、透射电子显微镜（TEM）以及原子力显微镜（AFM）等测试仪器对nc-Si薄膜进行表征，发现制备的nc-Si量子点排列紧密、尺寸均匀，具有很好的单晶结构，制备的nc-Si薄膜晶化比例很高，并且优先选择在[111]方向晶化．     

Effect of lattice-mismatch strain on the structural and dielectric properties of (Pb,Sr)TiO3 thin films grown by pulsed laser deposition

Pb_0.35Sr_0.65TiO₃ (PST) thin films have been fabricated on LaAlO₃ (LAO) and MgO substrates using the pulsed laser deposition technique. The microstructure characteristics of the films were examined by means of X-ray diffraction, atomic force microscopy, scanning electron microscopy and Raman spectroscopy, and the results indicate that the films are epitaxially grown and show good crystallinity. The dielectric constant dependence on DC bias voltage and temperature were measured in a planar capacitor configuration for these films. Compared to the PST thin film grown on LAO, the film grown on MgO showed a higher temperature of the capacitance maximum and a higher dielectric constant at zero bias. We explain the results by taking into account the lattice-mismatch strain between the substrate and the film. In contrast to the in-plane compressive strain induced by the LAO substrate, the in-plane tensile strain induced by the MgO substrate enlarges the unit cell of PST and enhances the magnitude of dipole moments, which increases the dielectric constant. These results indicate that a reasonable in-plane tensile strain could improve the dielectric properties of PST thin films.     

光电印制电路板的发展评述（3）——聚合物光波导层的成型工艺（1）

文章简述了光电印制电路板中聚合物光波导层的制作应该遵循的原则,介绍了光波导层的主要成型工艺,包括反应离子蚀刻、平版影印、激光烧蚀和加热模压等方法。     

ZnO nanostructured film deposition using the separated pulsed laser deposition (SPLD) assisted by electric and magnetic drift motion

We have developed the separated pulsed laser deposition (SPLD) technique to prepare high quality ZnO based films exhibiting uniform and droplet-free properties. This SPLD consists of an ablation chamber and a deposition chamber which can be independently evacuated under different ambient gases.The gas species and the pressures in both chambers can be arbitrarily chosen for the specific deposition such as nanostructured films and nanoparticles. The ablation chamber is a stainless steel globe and the deposition chamber is a quartz tube connected to a metallic conic wall with an orifice. We used a KrF excimer laser with λ = 248 nm and 25 ns pulse duration. The different gas conditions in two chambers allow us to realize optimal control of the plasma plume, the gas phase reaction and the film growth by applying the bias voltage between the conic wall and the substrate under the magnetic field. We can expect that at appropriate pressures the electric and magnetic field motion (E × B azimuthal drift velocity) gives significant influences on film growth.We have deposited ZnO thin films at various pressures of ablation chamber (Pab) and deposition chamber (Pd). The deposition conditions used here were laser fluence of 3 J/cm², laser shot number of 30,000, Pab of 0.67-2.67 Pa (O₂ or Ar), Pd of 0.399-2.67 Pa (O₂), and substrate temperature of 400 °C. Particle-free and uniform ZnO films were obtained at Pab of 0.67 Pa (Ar) and Pd of 1.33 Pa (O₂). The ZnO film showed high preferential orientation of (002) plane, optical band gap of 2.7 eV, grain size of 42 nm and surface roughness of 1.2 nm.     

飞秒激光对Mg/PTFE药剂烧蚀加工过程安全性分析

文章简要介绍了飞秒激光发展过程及其特点,讨论了利用飞秒激光的超快速时间和超高峰值的特性烧蚀加工烟火药剂Mg/PTFE的可行性与安全性.建立了飞秒激光与Mg/PTFE作用过程中的传热模型,根据模型计算了药剂内部的温度分布以及烧蚀反应放出的热量对周围药剂的影响;在本研究的计算条件下,确定了在切割过程中,受激光作用表面的温度可达3000℃以上,单个激光脉冲的作用深度小于5.0×10-7m,药剂反应放出的热量对周边基本上没有影响,因而飞秒激光能够用于Mg/PTFE药剂的加工.     

金属玻璃飞秒激光烧蚀特性

采用飞秒激光对Zr基金属玻璃在空气中进行了表面烧蚀、微打孔与微细切割等过程的研究.通过扫描电镜(SEM)、能量弥散X射线(EDX)能谱分析与透射电镜(TEM)及电子衍射等方法,分析了飞秒激光烧蚀金属玻璃的表面形貌与加工区域发生的相关效应.实验与分析表明加工区域周围无熔融和液滴溅射现象,热影响区极小,并且无晶化现象发生,但飞秒激光微细加工金属玻璃时存在极薄的表面氧化现象.研究结果表明,在适当选择参数的条件下,飞秒激光烧蚀是一种极有前途的金属玻璃无晶化微细加工方法.     

脉冲激光修锐青铜金刚石砂轮烧蚀机制研究

青铜金刚石砂轮具有优良的磨削性能，在初次使用和磨损后必须对其修锐。由于青铜结合剂和金刚石磨粒之间存在热物理、光学性质的差异，可通过选择合适的脉冲激光功率密度去除结合剂，凸出磨粒，实现选择性去除。针对声光调Q YAG脉冲激光修锐青铜金刚石砂轮，建立了适合激光烧蚀青铜结合剂的实际过程的传热与气化动力学模型，运用数值计算模拟出各种激光功率密度下的熔层温度、熔层厚度和烧蚀速率，进而获得激光功率密度与激光烧蚀凹坑深度的关系，并与实验结果进行比较。通过验证表明所建立的模型可以正确描述实际物理过程。     

Subtractive methods to form pyrite and sulfide nanostructures of Fe,Co, Ni,Cu and Zn

The low Z metals Fe, Co, Ni, Cu and Zn are Earth abundant, i.e. inexpensive, and their sulfides are of low toxicity. This makes them appealing candidates for materials applications requiring semiconductors or, in the case of CoS₂, a metal since they can potentially be produced in large quantities and low cost. Though of great potential little work has explored how subtractive methods can be used to form nanostructured and/or porous structures in, e.g. FeS₂, CoS₂, NiS, Cu₂S and ZnS.     

Multilayers of Ge nanocrystals embedded in Al2O3 matrix: Structural and electrical studies

In this paper, Ge/Al₂O₃ multilayer systems were grown by pulsed laser ablation. The grown samples were annealed at 900 °C to promote the formation of Ge nanocrystals. Rutherford backscattering spectroscopy and transmission electron microscopy confirmed the presence of a multilayer system. Grazing incidence small angles X-ray scattering technique demonstrates the formation of Ge nanoclusters formed between alumina layers. Room temperature I-V measurements showed weak carrier trapping in the system. This was explained by the leakage caused by Ge diffusion through the multilayer.     

Evaluation of pressure-sensitive tape adhesion and backing directionality by excimer laser methods

The effects of 248 nm KrF excimer laser irradiation on a pressure-sensitive adhesive tape bonded to a glass substrate were investigated as a possible method to evaluate the quality of adhesion, as well as the directionality induced during manufacture. The model pressure-sensitive tape consisted of biaxially-oriented polypropylene (PP) tape coated with a hot-melt rubber resin. Analysis of the front-shot experiments, which were performed by irradiation through the PP backing, allowed correlation between the excimer laser irradiation-induced detachment and the peel adhesion strength. For this purpose, peel tests were performed before and after laser shots. The directionality induced during manufacture resulted in a more ablated area in the strength direction than in the transverse direction when the bonded tapes were irradiated with an elliptically-shaped laser beam above the ablation threshold. A correlation was found between the detachment bubbles created by irradiation below the ablation threshold and their respective peel adhesion values, which allows us to evaluate the quality of adhesion for pressure-sensitive tapes. Thus, a method to evaluate the quality of adhesion using an excimer laser is proposed based on the findings of this work.