WF40防腐蚀涂料在原料水罐上的应用

中国石化股份有限公司洛阳分公司炼油厂污水汽提装置的原料水罐(V303)由于接触的污水中含有H2S,NH3,CO2,CN-,酚等多种腐蚀介质因此经常发生腐蚀泄漏事故。经涂刷WF40玻璃鳞片防腐蚀涂料后,已平稳运行两年。2002年检修检查,涂层完好,仍在继续使用。WF40涂料为环氧型玻璃鳞片涂料,其热膨胀系数与钢质基体接近,因此具有耐热冲击性强等优点。待涂罐体经喷砂除锈到Sa2.5级后,涂底漆2道,中间涂层2道、面漆2道,使干膜厚度达到350μm,可有效防止腐蚀性介质的渗透。     

复合多功能通风管道的性能及在空调系统中的应用

详细介绍了复合多功能通风管道的各种性能,并与薄钢板通风管道作了比较,指出了其在空调系系统中的推广应用具有广阔的发展前景。     

Microstructural investigation of long-term degradation mechanisms in GFRP dowel bars for jointed concrete pavement

Steel dowel bar is used to transfer loads in concrete pavement slab. However, once the steel dowel bar corrodes, it may cause faults, such as joint freezing in concrete pavement, level differences resulting from spalling or decreased efficiency of load transfer, etc., which are the same problems experienced by typical reinforcing steel. This study evaluated the applicability of glass fiber-reinforced polymer (GFRP) dowel bar as a substitute for steel dowel bar. A microstructural analysis was conducted to examine the decrease in durability of GFRP dowel bar exposed to deterioration environments. To analyze the deterioration mechanism of GFRP dowel bar, scanning electron microscopy was employed and the porosity was measured by the gas absorption method. It was concluded that the longer the GFRP dowel bar was exposed to deterioration environments, the more the interlaminar shear stress decreased. This result was validated by the microstructural analysis. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Water absorption properties of phosphate glass fiber‐reinforced poly‐ϵ‐caprolactone composites for craniofacial bone repair

The moisture uptake of polymers and composites has increasing significance where these materials are specified for invasive, long‐term medical applications. Here we analyze mass gain and the ensuing degradation mechanisms in phosphate glass fiber reinforced poly‐?‐caprolactone laminates. Specimens were manufactured using in situ polymerization of ?‐caprolactone around a bed of phosphate glass fibers. The latter were sized with 3‐aminopropyltriethoxysilane to control the rate of modulus degradation. Fiber content was the main variable in the study, and it was found that the moisture diffusion coefficient increased significantly with increasing fiber volume fraction. Diffusion, plasticization, and leaching of constituents appear to be the dominant aspects of the process over these short‐term tests. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Functional copolymer of geraniol and acrylonitrile: Synthesis and characterization

The radical copolymerization of acyclic terpene namely geraniol [GER] with acrylonitrile [AN] in DMF at (70 ± 0.1)°C for 1 h, using benzoylperoxide (BPO) as an initiator has been carried out under inert atmosphere of nitrogen. The kinetic expression for reaction is R_p ∝ [BPO]^0.5 [AN]^1.0 [GER]^1.0. The IR spectrum of the copolymer shows bands at 3432 and at 2244 cm^?1 due to ? OH group of GER and ? CN group of AN, respectively. The ¹³C‐NMR spectrum shows peaks at 73–75 δ ppm and 116–120 δ ppm due to ? OH group of GER and ? CN group of AN, respectively. The thermogravimetric analysis and differential scanning calorimetry study shows that copolymer is thermally stable up to 407°C and has glass transition temperatures (T_g) 56°C. The reactivity ratios r₁ (AN) and r₂ (GER) have been calculated as 0.05 and 0.005, respectively. The Alfrey‐Price Q‐e parameter for GER has been calculated as 0.094 and ?2.0, respectively. The molecular weights of the copolymers have been evaluated by gel‐permeation chromatography. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Bruchanalyse an Hohlgläsern

Failure analysis of hollow glasses The failure analysis is very important to clarify damages of hollow glasses. Damages of glass bottle through over pressure are very often linked with damages to persons. This is the reason why the causal research is from particular importance. Different surface characteristics of glass fragments as well as the fracture pattern give hints to the direction of the crack, the stress just before breakage and the reason of stress. A reconstruction of the bottle is a further helpful instrument for cause studies. The difference of the various characteristics of the surface will be explained. Further on there will be discussed different reasons and mechanism of fracture.     

栅控电子枪理论新探

本文主要是利用电子光学静电透镜原理，研究栅网对栅控电子枪的影响，以及如何消除这种影响。结果表明，理论分析的结果与实验相符，对实际栅控电子枪的设计具有一定的指导意义。     

PbO－Bi_2O_3－B_2O_3－SiO_2系重金属氧化物玻璃的结构与光学性

通过密度、可见光光谱、红外吸收光谱、Ｃｏ－６０辐照损伤试验及荧光光谱的测试，研究了ＰｂＯ－Ｂｉ２Ｏ３－Ｂ２Ｏ３－ＳｉＯ２玻璃系的光学性能与结构．密度最高可达８．４６４ｇ／ｃｍ３其紫外吸收达截止波长随Ｐｂ２＋及Ｂｉ３＋含量升高而红移．玻璃熔化温度低达８５０℃．在ＰｂＯ－Ｂｉ２Ｏ３－Ｂ２Ｏ３系玻璃中加人ＳｉＯ２可使玻璃结构更致密．室温下该系统玻璃在３６０ｎｍ有一个宽的激发峰，能产生４１８ｕｍ及４３８ｕｍ两个弱的发射峰．该系统玻璃的结构是由［ＳｉＯ４］４－、［ＢＯ３］３－、［ＢＯ４］５－、［ＰｂＯ４］６－及［ＢｉＯ６］９－构成．其中部分Ｐｂ２＋及Ｂｉ３＋以网络外体进入玻璃．     

自聚焦透镜用于端泵浦DPL的耦合光学系统

本文用自聚焦透镜耦合ＬＤ输出，解决了需要短焦距、大数值孔径透镜的设计和制方面的困难。提出了计算自聚焦透镜耦合效率的简化模型。用自聚焦透镜和一对正交柱面透镜设计了一个耦合系统，并用该耦合系统端泵浦Ｎｄ：ＹＡＧ棒做了实验。     

Adhesion Mechanisms of Polyurethanes to Glass Surfaces. III. Investigation of Possible Physico-Chemical Interactions at the Interphase

Surface free energies of polyurethanes made from toluene diisocyanate and 1, 4 butanediol-based hard segments and caprolactone polyol-based soft segments were calculated using additive functions. Good agreement was found between the calculated values based on additive functions and the calculated values based on contact angle measurements. The phase-separated polyurethanes were found to have a higher polar surface free energy component (γ^P). This was linked to the preferential segregation of butanediol/butanediol-derived moieties to the polyurethane surfaces due to phase separation. The adhesion values of these polyurethanes to soda-lime glass were correlated with their respective γ^P values and a linear relationship was found. It was also shown that the adhesion values of the low γ^P polyurethanes improved substantially when the glass surfaces were coated with a thin layer of butanediol prior to the bonding. The modulus of the interphase region rich in butanediol was evaluated. Although a modulus increase was found at the interface, this increase was found to play a secondary role in the adhesion. The chemical interactions at the polyurethane/glass interphase were investigated by pre-treating the glass surfaces with methyl-trimethoxysilane and trimethylchlorosilane prior to adhesion testing. The adhesion data showed no significant difference between the uncoated and the silane-treated glass substrates. Based on this experimental evidence, the possibility of any covalent or ionic bonding at the polyurethane/glass interphase was assumed negligible. It was determined that the mechanism of adhesion between the polyurethanes and the glass surface could be through the formation of an interphase region in which hydrogen bonding between the butanediol-rich interphase region and the hydroxylated glass surface plays a key role.