弹簧钢棒线材质量投诉的分析研究

为分析研究某特钢厂用户投诉的原因及存在的问题，统计了其两年间的弹簧钢棒线材用户质量投诉，从缺陷类型及生产过程控制进行了分析，重点对多起断裂原因不明的投诉进行了深入的失效研究。结果表明，弹簧钢生产厂在设备工艺、过程控制和管理中存在很多不足，加上用户的使用工艺、材料的内外质量和规格等综合因素导致了材料的断裂失效。     

Action of chelators on solid iron in phosphate-containing aqueous solutions

To study the effect of strong iron-ligands on steel corrosion, mild steel electrodes were immersed in solutions containing 20 mM phosphate buffer (pH=7.2) and between 0.01 mM and 1 M of either the iron(II)-chelators 2,2^′-bipyridine or FerroZine, or the iron(III)-chelators citrate or acetylacetonate. Resulting surface reactions were investigated by quantifying the electrochemical potential (E), the electrochemical polarization resistance (R_p), the corrosion current (I_corr) and the release of iron into solution. The surface was further analyzed by scanning electron microscopy (SEM/SEM-EDAX) and atomic force microscopy. Concentrations of 0.1 mM of any of the chelators led to slight, temporary changes in E, I_corr and R_p. Concentrations of 10 mM resulted in characteristic changes of E, which were the same for all chelators and in the precipitation of FePO₄ in the case of citrate and acetylacetonate, or vivianite [Fe₃(PO₄)₂ · 8H₂O] in the case of bipyridine and FerroZine. Concentrations of 1 mM of both iron(III)-chelators led to a temporary drop of E similar to that found with 0.1 mM chelator. With iron(II)-chelators, E dropped to about −500 mV before oscillating for several days. The amplitudes of the oscillations were up to 200 mV with periods of 30 and 20-25 min for bipyridine and FerroZine, respectively.     

Copper phthalocyanine as corrosion inhibitor for ASTM A606-4 steel in 16% hydrochloric acid

A study based on the corrosion inhibition properties of copper phthalocyanine is described. Coverage degrees of copper phthalocyanine (Cu-phcy) on ASTM-A606-4 steel, obtained by weight loss measurements, were fitted to Langmuir, Frumkin, Temkin and Flory–Huggins adsorption isotherms. A better fit to the Langmuir isotherm was obtained. The polarization curves showed that polarization of both the anodic and cathodic reactions were verified for concentrations higher than 10^–4 M, indicating a mixed type action. Only the anodic reactions were polarized for lower concentrations. At high frequencies the Nyquist diagrams showed one capacitive loop attributable to double layer charging and a small one at intermediary frequencies attributable to the faradaic process of hydrogen evolution. The formation of an adsorbed film was characterized by increasing charge transfer resistance values in the low frequency range for increasing inhibitor concentrations. According to the techniques used in this study, copper phthalocyanines showed a high corrosion inhibiting efficiency for all concentrations.     

微合金化高强度钢轧制采用的工艺技术

本文综述微合金化高强度钢轧制采用的工艺技术，其中包括热装热送、板坯加热、控轧控冷、快速冷却、采用的新设备等工艺技术。重点是生产低碳、高韧性、高强度、易焊接的造船用钢采用形变热处理技术，以提高产量和质量，节省昂贵的Ｎｉ、Ｃｒ、Ｍｏ等合金，降低生产成本。     

双相不锈钢焊接技术状况

双相不锈钢具有优异的综合性能，应用范围广，其焊接技术独具特点，受到特别关注。本文论述了双相不锈钢焊接的基本原则，焊丝、保护气体及焊接参数的选择等。     

45号钢二次枝晶臂间距与冷却速度的关系

本文利用可控平均冷却速度的单向凝固实验炉测定了４５号钢在不同平均冷却速度下的冷却曲线，由此得到其在凝固期间的平均冷却速度Ｒ，相应地测量了不同平均冷却速度下试样的二次枝晶臂间距Ｓ２，通过回归，得到了如下关系式：Ｓ２＝７２７Ｒ－０．４１，并将引式成功地应用于实际生产中。     

WTG420铁路罐车用钢的组织结构和力学性能分析

分析了ＷＴＧ４２０铁路罐车用钢的组织结构和力学性能。提出了冶炼与轧制的技术关键，其一，添加稀土元素改善钢中夹杂物；其二，采用控轧控冷使铁素体晶粒细化。     

Study on Factors Affecting the Structure of High SpeedSteel Ingot Produced by ESR

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MICROSTRUCTURE AND FATIGUE PROPERTIES OF A WELDED DUPLEX STAINLESS STEEL

Abstract— In response to the increasing structural applications in duplex steels for welded structures, fatigue behaviour of a SAF 2304 grade duplex stainless steel was investigated, considering both the base metal and GTAW welded joints. Fatigue curves and fatigue limits under rotary bending fatigue were obtained. The study focused attention on the microstructural features of fatigue crack propagation of the two series of experiments, thereby permitting an evaluation of the tortuous crack path of welded joints and the mechanisms related to threshold microstructural barriers.     

关于深冲薄钢板中的夹杂和成形性的商榷

对深冲薄钢板大生产的全工艺过程进行了跟踪，研究了ＷＹ０８ＡｌＡ薄钢板中Ａｌ＿２Ｏ＿３的形成，形态以及它们对冷轧成品的深冲性能和冲压小件的冲压成形废品率的影响。