铸件退火炉烟气余热的回收利用装置

提出了HTAC技术的新结构,即铸件退火炉烟气余热的回收利用装置,以期提高热效率、节约能源并减轻污染。     

退火温度对Ag/Cu层复合板分离强度的作用

对轧制复合的Ag Cu双金属薄板采用不同温度的退火处理 ,研究了结合面分离强度随退火温度变化的规律 ,讨论了影响分离强度的因素。结果表明 ,在 40 0℃以下随退火温度的升高 ,由于原子扩散及再结晶晶界的形成趋于充分而导致分离强度升高 ,40 0℃时分离强度达到最大值。当退火温度超过 40 0℃后 ,由于结合面的异类原子不等量对流而导致结合面形成空洞 ,从而使分离强度下降。 750℃退火时分离强度达到最低值。退火温度进一步上升到 80 0℃时可使结合面发生局部熔合 ,使分离强度又有小幅度回升     

新能源汽车电池负极材料的制备与性能研究

采用原位合成法制备了镍-氧化镍/多孔碳纳米片（Ni-NiO/PCNs）负极材料,对比分析了氯化钠模板、退火温度和退火时间对负极材料物相组成、显微形貌和电化学性能的影响。结果表明,Ni/PCNs、Ni-NiO/C和Ni-NiO/PCNs负极材料都主要含有镍和无定型C相,且后2种负极材料还含有氧化镍相;300 ℃/4 h为Ni-NiO/PCNs负极材料适宜的退火工艺,此时Ni-NiO/PCNs负极材料中Ni-NiO粒子分散性较好且保持着三维片层结构,平均尺寸约为27 nm,Ni-NiO实现了对无定型C的包裹;退火时间过长（6 h）会使得镍粒子过氧化且发生团聚,而温度过高（400 ℃）会使得粒子以团聚为主,三维片层状结构消失。电流密度为1 A/g、循环5 000圈后Ni-NiO/PCNs负极材料的放电比容量为235 mA·h/g,此时的放电比容量约为首圈放电比容量的83.93%;Ni-NiO/C和Ni/PCNs负极材料在充放电循环过程中以及循环5 000圈后的放电比容量和容量保持率都明显低于Ni-NiO/PCNs负极材料,Ni-NiO/PCNs负极材料具有更好的循环稳定性,这主要与其具有独特的多孔三维片层结构有关。     

Microstructure evolution of cold-sprayed coating during deposition and through post-spraying heat treatment

The microstructural features of cold-sprayed coatings were investigated using Cu, Ti and Zn feedstocks by optical microscopy, scanning electron microscopy and transmission electron microscopy to reveal the microstructure evolution mechanisms in cold spray. Four typical effects including tamping, refinement, impact-induced fusion and annealing were examined on microstrueture. It is found that the microstructure of cold spray coating is remarkably influenced by spray materials. Ti coatings consist of evident porous layer and Cu coatings present a limited porous layer only near the surface. It is clear that the successive tamping effect and dynamic refinement of grains significantly influence the microstructure evolution of cold-sprayed coating. The tamping effect leads to the densification of porous coating layer gradually and the refinement effect leads to the formation of fine microstructure. It is considered that the large difference in the formation of porous layer is attributed to the dynamic impact pressure and hardenability of materials. It is also found that the impact-induced fusion during deposition of Zn coating can also modify the interfacial microstructure between particles in cold spray coating. Moreover, the nanocrystalline phase can be formed at the interfaces among particles resulting from the localized melting of the interfaces and tamping effect. Furthermore, the annealing treatment can modify the microstructure and property of a cold-sprayed coating.     

铜元素和退火温度对TRIP冷轧钢板组织和力学性能的影响

将含铜和不含铜的两种TRIP钢板(0．2％C、1．5％Si、1．5％Mn)冷轧至1mm厚，然后分别在750℃、760℃、770℃、780℃下退火5min，最后在450℃等温3min，获得了不同含量和不同稳定性的残留奥氏体。金相和力学性能试验结果表明，铜元素能提高残留奥氏体量和钢板的力学性能；退火温度影响残留奥氏体量和力学性能，当退火温度选择在Ac1 10％时可获得最佳的力学性能。     

大型风电球墨铸铁件的生产实践

以轮毂为例,介绍对大型风力发电机球墨铸铁件生产工艺进行的试验研究。通过优化铸型工艺,采用适当的浇注系统和低温石墨化退火工艺,选择合理的化学成分,控制球化处理与孕育处理,可生产出各项性能指标合格的风电铸件。     

应力松驰与非晶态Fe_（79）B_（16）Si_5合金磁性优化

分析了退火过程中应力的松驰与作晶态合金磁性优化之间的联系淬态Ｆｅ_（７９）Ｂ_（１６）Ｓｉ_５非晶合金经退火后，饱和磁感应强度Ｂ、提高了７２％，最大磁导率μ_ｍ提高２２倍，矫顽力Ｈ_ｃ和功率损耗Ｐ（０．３Ｔ，１０ｋＨｚ）分别降低８６％和８３％。退火过程中条带内应力的松驰，有效地去除了应力感生磁各向异性，使非晶态合金的磁性得到显著优化。     

Effect of oxygen precipitates in solar grade silicon on minority carrier lifetime and efficiency of solar cells

The effect of oxygen precipitates on minority carrier lifetime and performance of solar cell was studied by means of Fourier Transform Infrared Spectroscopy (FTIR), quasi-steady state photoconductance (QSSPCD), optical microscope, spectrumresponse and solar cell efficiency test. The minority carrier lifetime and performance of solar cell reduced depend on oxygen precipitates. A few of oxygen precipitates have formed after single-step annealing; and they do not impact the efficiency dramatically. Pre-annealing at 650 ℃ for 4 h enhances the oxygen precipitation when it is subjected to middle temperature annealing. The solar cells performance decayed sharply. Especially annealing at 950 ℃ for 3 h, the V os and I sc of cells decrease 12% and 25% respectively. Few oxygen precipitates have formed in silicon after high temperature annealing at about 1050 ℃ whether pre-annealing is used or not, and the performance of cells is notbe affected.     

辊底式退火炉的炉体改造

分析了辊底式退火炉存在的问题，提出改进措施及改造后节能效果。     

Effect of annealing treatment on electrochemical property of LiNi0.5Mn1.5O4 spinel

LiNi0.5Mn1.5O4 was prepared under different cooling conditions. The electrochemical properties of LiNi0.5Mn1.5O4 prepared under different cooling conditions were investigated. The results show that LiNi0.5Mn1.5O4 synthesized with or without annealing treatment has similar X-ray diffraction patterns that can be indexed to cubic spinel structure. The mass loss occurring above 650℃ during the heating process can be mostly gained during the cooling process. LiNi0.5Mn1.5O4 synthesized with an annealing treatment exhibits almost one voltage plateau at around 4.7 V and higher capacity with a quick fading upon cycling, whereas LiNi0.5Mn1.5O4 synthesized without annealing treatment shows two voltage plateaus at around 4.1 and 4.7 V and superior capacity retention upon cycling both at rates of 1/7C and 1 C, though the capacity is not high.