Preparation and optical properties of Nb-NbN multilayer films as solar selective absorptive coatings

Based on the cermet double layer structure, Nb-NbN multi-layer films for solar selective coatings were deposited by direct current reactive magnetron sputtering. The Nb/Nb-NbN/Al2O3 trilayered structure was deposited on a stainless steel (SS) substrate by using a single niobium target. The expected components were adjusted by changing the gas flowing ratios of Ar: N2. The Al2O3 antireflective layer on the top of the film was produced by r. f. magnetron sputtering using Al2O3 ceramic target. A solar absorptivity of 0.94 and a normal emissivity of 0.16 at room temperature have been achieved for the coating. Thermal vacuum aging to the samples was carried out at 350 and 500 ℃ for 1 h. The results show a good thermal stability. Microstructure and its dependence on temperature of the Nb, NbN and Nb-NbN single layers were investigated, respectively.     

The influence of TiAlN and enamel coatings on the corrosion behavior of Ti6Al4V alloy in the presence of solid NaCl deposit and water vapor at 450 °C

The corrosion behavior of Ti6Al4V alloy with solid NaCl deposit and water vapor at 450 °C has been investigated. Serious corrosion occurred. In order to improve the corrosion resistance, TiAlN and enamel coatings were prepared, and their effectiveness and corrosion resistance were evaluated. The results indicated that both coatings were effective in protecting the alloy against corrosion induced by NaCl deposit and water vapor at 450 °C. The protection mechanisms of these two coatings were also studied.     

TiO2涂层耐蚀性能研究

用溶胶－凝胶法在碳钢表面制备TiO2涂层。用正交设计法对水解反应温度、涂覆次数、热处理温度和时间等4因素进行了优化，并考察了上述4 因素对涂层在10％H2SO4介质中的耐蚀性能的影响。     

热沉影响钛合金薄板焊接残余应力的试验分析

采用切条应力释放法测量了钛合金TC4薄板常规钨极氩弧焊(GTAW)和动态控制低应力无变形GTAW对接试件中的纵向残余应力和纵向残余塑性应变的分布。测量结果表明,钛合金常规GTAW缝中残余拉应力峰值小于其母材屈服强度,焊缝附近存在残余压缩塑性应变;动态控制低应力无变形GTAW焊技术中热沉的冷却作用使得热源与热沉之间的高温金属承受强烈的拉伸作用,产生拉伸塑性变形,部分抵消了焊接过程中已产生的缩短的塑性变形,使得试件中纵向残余塑性应变减小,焊接残余拉应力峰值降低,残余压应力水平降低。切条应力释放法是一种简便有效的薄板焊后残余应力测量方法,能够满足工程应用的精度要求。     

钢结构制造中焊接变形的控制方法

着重介绍了桥梁、建筑、船舶、压力容器等钢结构制造中经常遇到的一个比较棘手的问题--焊接变形的控制方法和解决方案.     

SiC（Cu）／Fe复合材料制备工艺研究

采用非均相沉淀法制得Cu包裹SiC复合粉体，利用粉末冶金和常压烧结制备SiC（Cu）／Fe复合材料。利用Zeta电位仪、XRD，EDS以及SEM等手段对包裹粉体和烧结样品进行了分析。结果表明，采用非均相沉淀法可以得到Cu／SiC复合粉体。包裹后的粉体与原始SiC粉体的表面电位不同，达到了对SiC颗粒表面改性的目的。Cu作为过渡层改善了SiC／Fe的界面相容性，在1050℃烧结的样品只有微量的FeSi或Fe2Si生成，界面反应得到有效控制，获得化学结合的界面，温度过低不能烧结致密，温度过高出现大量缺陷。     

炭/炭复合材料声电沉积钙磷生物活性涂层的生长机理

通过声电沉积在炭/炭复合材料表面制备钙磷生物活性涂层,采用SEM（带EDAX）,XDR,FTIR研究电沉积时间对钙磷生物活性涂层的形貌、结构和组成的影响.实验结果表明：沉积初始先在炭/炭表面形成无定形层,片状磷酸氢钙（DCPD）在其表面生长,随着电沉积时间的延长,逐渐向针状的羟基磷灰石Ca10（PO4）6（OH）2（HA）转变,涂层厚度和n（Ca）/n（P）不断增加,涂层的结晶度和电解液的pH值下降.涂层为缺钙磷灰石.同时探讨了在炭/炭复合材料表面钙磷生物活性涂层的生长机理.     

冷喷涂钛涂层与1Cr13不锈钢的电偶腐蚀行为

以氮气为载气,在压力为2.0MPa,载气温度为500℃的状态下,用冷喷涂的方法在1Cr13不锈钢基体上制备了钛金属涂层。经SEM观察,发现涂层的厚度较大,没有直接贯穿到基体的孔隙存在,距离基体越近的区域,涂层的孔隙率越小,XRD分析表明,涂层基本无氧化物相生成;从热力学和动力学两方面研究冷喷涂钛涂层与1Cr13不锈钢的电偶腐蚀行为,发现两者的电偶腐蚀倾向较小。     

金属材料屈服强度的应变率效应和热激活理论

对４种金属材料进行了应变率为１０＾－４－１０＾３ｓ＾－１的拉伸试验，结果表明，屈服中度随应变率的升高分两阶段线性升高，提出了位错线热振动对加载频率的响应的热激活作用机理，依据该机理计算所得Ⅰ，Ⅱ区临界应变εｃ与实测值相符，并在此基础上将应变率对掘强度影响的机制图重新划分为：Ｉ区，富热激活区；Ⅱ区，贫热激活区。     

Accelerated electrospark deposition and the wear behavior of coatings

Electrospark deposition (ESD) is a coating process that is featured by low heat input to the substrate. Low coating efficiency and other limitations influence its wider application. The present paper introduces newly designed ESD equipment, by which a higher coating rate can be reached. The relationship among coating thickness, surface roughness, and process parameters such as pulse energy, pulse frequency, and deposition time are presented. Electrospark deposition coating by the new equipment on AISI 1045 steel (with WC-8% Co as electrode) increases the wear resistance by 5 to 8 times. The micromechanism is investigated by scanning electron microscopy observation.