Thickening and Rheological Properties of Crystalline Polyester Used in Low Pressure Sheet Molding Compounds

Low pressure sheet molding compound (LPMC,1.0-3.0 MPa,95-103 ℃) is a new kind of thermosetting material with crystalline polyester as a physical thickenner.LPMC is different from conventional SMC using an earth oxide thickening agent (e.g.MgO) as chemical thickenner,it relies on the physical thickening of crystalline polyester.Crystalline polyester resin is the key material to mold LPMC parts.Currently there was no report about the thickening mechanism of crystalline polyester in LPMC.In this article,crystalline polyester resins,whose melting points were between 45 ℃ and 89 ℃,were synthesized by a two-step esterification.The melt points of crystalline polyesters are controlled by regulating the mol ratio of the two glycols and the two acids.And by means of varying the content of crystalline polyester resin,the thickening effect on resin paste is investigated.In addition,the thickening mechanism of crystalline polyester in LPMC was investigated by FTIR and DSC analysis.The effects of the diameters and viscosity of crystalline polyester on the rheological property and fiber distribution of LPMC sheets were studied,too.Results show that the thickening effect is excellent when the weight content of crystalline polyester resin is 3%.And there exists three kinds of functions acting in the process of thickening:swelling,hydrogen bonds and induction crystallization.During the preparing process of resin paste in LPMC,the temperature of resin paste must be kept at 90 ℃.In addition,crystalline polyester make LPMC have a perfect fluid property.When the viscosity of LPMC sheet is beyond 1 kPa s,the fiber orientation is not obvious.But when the viscosity of LPMC sheet is about 500 Pa s,the fiber shows a certain degree of orientation.Moreover the study of physical and chemical thickening mechanism of crystalline polyester and the rheological discipline of LPMC sheets in the hot mould will provide the researchers and enterprises with theory guidance.     

A Composite Formation Route to Well‐Crystalline Manganese Oxide Nanocrystals: High Catalytic Activity of Manganate–Alumina Nanocomposites

Manganese oxide nanocrystals are combined with aluminum oxide nanocrystals to improve their crystallinity via calcination without a significant increase of crystal size. A nanocomposite, consisting of two metal oxides, can be synthesized by the reaction between permanganate anions and aluminum oxyhydroxide keggin cations. The as‐prepared manganese oxide–aluminum oxide nanocomposite is X‐ray amorphous whereas heat‐treatment gives rise to the crystallization of an α‐MnO₂ phase at 600 °C and Mn₃O₄/Mn₂O₃ and γ‐Al₂O₃ phases at 800 °C. Electron microscopy and N₂ adsorption‐desorption‐isotherm analysis clearly demonstrate that the as‐prepared nanocomposite is composed of a porous assembly of monodisperse primary particles with a size of ～20 nm and a surface area of >410 m² g^?1. Of particular interest is that the small particle size of the as‐prepared nanocomposite is well‐maintained up to 600 °C, a result of the prevention of the growth of manganate grains through nanoscale mixing with alumina grains. The calcined nanocomposite shows very‐high catalytic activity for the oxidation of cyclohexene with an extremely high conversion efficiency of >95% within 15 min. The present results show that the improvement of the crystallinity without significant crystal growth is very crucial for optimizing the catalytic activity of manganese oxide nanocrystals.     

Metal Forming of Vibration‐Damping Composite Sheets

Composite materials with vibrations damping qualities can be made of two steel sheets enclosing a viscoelastic plasticcorelayer. These sandwich sheets often need to be formed. Material parameters are determined to describe the forming process. Based on these parameters, pilot studies are carried out in order to develop recommendations for forming this class of material.     

以蔗糖为模板剂合成介孔氧化铝

以蔗糖为模板剂,异丙醇铝为铝源,水相体系下,考察了体系pH和模板剂用量对介孔氧化铝合成的影响。并采用X射线衍射、透射电镜(TEM)、氮吸脱附以及固体核磁等手段对合成样品进行表征。结果表明,合成的介孔氧化铝为γ-Al2O3,具有较高的比表面积以及较集中的孔径分布。体系的pH和模板剂用量对介孔氧化铝产物的性能有一定影响,并对蔗糖的模板作用机理进行了讨论。     

液相法合成氢化铝钠的研究

以NaH和AlCl3为主要原料,通过改变实验条件,探索研究液相法合成NaAlH4的合成条件。实验表明,在不加入任何催化剂的情况下无法实现NaAlH4的合成,在以NaAlH4、三乙基铝等物质为催化剂的条件下,虽有少量的产物生成,但是反应不明显,且产物中存在大量的非晶态物质。即便在高温高压下反应亦难以进行,大量的化合物均以非晶态形式存在。     

3-丙酰氨基-N,N-二丙酸甲酯基苯胺的合成研究

用无水三氯化铝作催化剂在较低温度下将3-氨基丙酰苯胺和丙烯酸甲酯转化为3-丙酰氨基-N,N-二丙酸甲酯基苯胺,其产品收率达到89%,纯度高于92%。     

门式刚架轻型房屋钢结构的荷载取值和结构计算应引起重视的问题

本文对门式刚架轻型房屋钢结构的荷载取值、结构设计和计算、优化设计中应引起重视的问题做一定的分析、探讨,供设计同行参考。     

聚碳酸酯板屋面幕墙——记深圳大运会主体育场屋面幕墙工程的深化设计

聚碳酸酯板是一种新型建筑材料,由于其显著的优点,在大型屋面幕墙上广泛应用,但它也有明显的不足,热胀冷缩变形大,这对屋面幕墙的密封防水影响很大,如何对PC板节点优化设计是本文的重点。     

基于数据关联技术的调度停电申请票管理系统的开发与应用

调度停电申请票管理系统基于调度运行管理平台,在继承传统模式的调度停电申请票管理基础上,提出了停电申请票之间以及停电申请票与调度操作票之间＂技术关联＂的概念,从而有效降低了设备重复停电的次数,防止调度误操作事故的发生,充分满足了电网管理的需求,提高了电网调度机构的管理水平。     

铝衰减膜表面氧化对软X光透过率的影响与修正

对用不同方法制备的软Ｘ光激光实验用的Ａｌ衰减膜样品,用Ａｕｇｅｒ电子能谱（ＡＥＳ）结合氩离子束刻蚀进行了组分的表面和深度分布分析,结果表明表面氧化层主要由Ａｌ２Ｏ３组成,氧化达到饱和时的氧化层厚度≈７．５ｎｍ。由于在软Ｘ光波段内,氧的吸收系数比铝大一个多数量级,这一氧化层对软Ｘ光透过率的影响甚大。将ＡＥＳ测试结果作为参数,使用公式Ｉ＝Ｉ０·ｅｘｐ［－μ（Ｅ）·（ρｄ）］对Ｘ光透过强度进行修正。同步辐射软Ｘ光对样品透过率的直接测量表明,对于透过率大于２０％的Ａｌ膜,直接测量结果与按修正公式计算的结果在最大偏差１１％范围内符合。