镁基储氢材料的研究进展

本文回顾和总结了近几十年来，特别是近十年来镁基储氢材料的发展情况，重点综述了机械合金化Mg-Ni2合金体系的研究情况及其近期的进展，从储氢材料成份及配比，制造工艺改进以及材料的组织结构对材料性能的影响等各方面进行一定的分析和归纳，对储氢材料研究中出现的问题以及今后的发展方向都作了探讨。     

Copper phthalocyanine as corrosion inhibitor for ASTM A606-4 steel in 16% hydrochloric acid

A study based on the corrosion inhibition properties of copper phthalocyanine is described. Coverage degrees of copper phthalocyanine (Cu-phcy) on ASTM-A606-4 steel, obtained by weight loss measurements, were fitted to Langmuir, Frumkin, Temkin and Flory–Huggins adsorption isotherms. A better fit to the Langmuir isotherm was obtained. The polarization curves showed that polarization of both the anodic and cathodic reactions were verified for concentrations higher than 10^–4 M, indicating a mixed type action. Only the anodic reactions were polarized for lower concentrations. At high frequencies the Nyquist diagrams showed one capacitive loop attributable to double layer charging and a small one at intermediary frequencies attributable to the faradaic process of hydrogen evolution. The formation of an adsorbed film was characterized by increasing charge transfer resistance values in the low frequency range for increasing inhibitor concentrations. According to the techniques used in this study, copper phthalocyanines showed a high corrosion inhibiting efficiency for all concentrations.     

孔径法测量铜带残余应力的试验研究

介绍了用于薄板残余应力测量的新方法——孔径法,该方法是通过测量冲孔直径的变化来间接求出各方向的残余应力;文中详细阐述了残余应力的标定方法;由于可针对不同材料建立了被测材料的平均应力(σ_l)与被测板材宽度(B)、厚度(H)以及冲孔后直径变化率(△D_i/D)之间的数学模型,因而使薄板残余应力测量变得简便而经济;此外还对该方法的分辨率与测量精度进行了实验、计算与分析。     

Gildes model studies of aqueous chemistry. III. Initial SO2-induced atmospheric corrosion of copper

The GILDES computer model, incorporating Stumm's concept of proton- and ligand-promoted dissolution, has been used to simulate the exposure of copper at room temperature to 210 ppb sulfur dioxide and 80% relative humidity. The agreement is good between the calculations and laboratory exposures performed under these exposure conditions. Surface reactions are relatively more important at lower relative humidities and the dominant corrosion products formed are solid state Cu₂SO₃, CuSO₃ and Cu₂U. Free-radical redox processes are important participants and control the relative distribution of Cu(I)- and Cu(H)-containing corrosion products.     

铝锂合金力学性能的各向异性

针对当前困扰铝锂合金实际应用的各向异性问题，概述关于铝锂合金中各向异性的表现规律，产生机理及对于降低各向异性所采用的方法等方面的研究现状和进展，对铝锂合金各向异性表现与微观组织结构的关系以及目前克服各向异性所采用方法的局限性进行分析。就此提出，若彻底解决这一问题则必须采用更先进的合金化方法及热加工工艺，研制新一代铝锂合金的观点和研究方向。     

铜蒸汽激光器双闸流管触发系统的研究

研制成用于钢蒸汽激光器的双间流管触发系统。用两个闸流管并联进行交替触发，总输入电功率达7．8kW。低功率运行时，激光器的效率为0．6％与单间流管激光器的效率一致。     

An investigation of pore cracking in titanium welds

Two welded Ti-6A1-4V pressure vessels leaked prematurely in service. The leaks were caused by cracks emanating from weld porosity. The cracks originated during fabrication, with subsequent growth in service leading to the formation of the leak paths. Pore cracking is thought to be caused by a mechanism that involves both sustained-load and cyclic contributions, with the former being the more prominent. It is shown that the tendency for cracking is influenced by pore position and that pore size is not a deciding factor in that regard. The factors that govern pore cracking are discussed, and the possible role of interstitial embrittlement is assessed.     

废电解液除杂制取硫酸铜和粗镍

介绍了废电解液除杂制取硫酸铜和粗镍的主要工艺条件及试验结果。在废电解液中加入CH80调节pH值到一定范围后,再加入CH64将电解液中Fe2+等杂质除去,铁的去除率可达到94%～98%。然后向滤液中加入CH80调节pH值沉淀铜。过滤后的滤饼用H2SO4溶解后再结晶,可得到CuSO4·5H2O晶体。滤液中加入Na2CO3沉淀镍,过滤后的滤饼即为粗镍(NiCO3)。铜和镍的回收率分别达96%和90%。该流程简单,投资少,效益高,环境保护好,在工业上有较广的应用前景。     

Mechanism for the Peritectic Reaction and Growth of Aligned Grains in YBa2Cu3O6+x

It is experimentally observed that the peritectic reaction, 211 + liquid → 123, can be driven essentially to completion in 1 h at an undercooling of only ∽30°C. The kinetic data, together with the observed microstructures, are inconsistent with the normal mechanism of the peritectic reaction. It is proposed that the mechanism of the reaction involves dissolution of 211 particles into the liquid and precipitation of solid 123. The aligned grain structure is explained through sympathetic nucleation of new 123 grains on existing grains.     

黄埔发电厂#6发电机转冷水系统改造

黄埔发电厂#6发电机转冷水铜离子含量超标，通过对缺陷原因进行分析，针对二级水封的特性对溢出的转冷水进行回收并利用化学凝结水处理去除溶出的铜离子，通过控制转冷水的pH值最终减缓铜管的腐蚀.