泡沫夹克管的防水与保温

针对辽河油田应用泡沫夹克管道的情况，从泡沫夹克管的制作和敷设施工直到设计等环节，结合泡沫夹克管防腐保温的机理，并从理论与实践相结合角度出发，提出导致泡沫夹克管腐蚀损坏的最主要原因是管道保温层漏水，进而提出了在设计和施工过程中提高泡沫夹克管质量的措施。     

On the corrosion fatigue crack initiation model and expression of metallic notched elements

In the present study, attempts are made to extend the application of the mechanical model for the fatigue crack initiation (FCI) and the FCI life formula of metallic notched elements in laboratory air to those in the corrosive environment. The test results and analysis of the corrosion FCI (CFCI) life of aluminum alloys and Ti---6A1---4V show that the expression of the CFCI life obtained by modifying the FCI life formula in laboratory air can give a good fit to the test results of the CFCI life. The salt water (3.5% NaCl) environment has no effects on the CFCI resistant coefficient compared with the FCI resistant coefficient in laboratory air. However, 3.5% NaCl environment greatly decreases the CFCI threshold of aluminum alloy, but has little effect on the CFCI threshold of Ti---6A1---4V. The loading frequency ranging from 1 Hz to 10 Hz has no appreciable effect on the CFCI life, and thus, the CFCI threshold of aluminum alloys investigated. Hence, the expression for the CFCI life of metallic notched elements proposed in this study is a better one, which reveals a correlation between the CFCI life and the governing parameters, such as, the geometry of the notched elements, the nominal stress range, the stress ratio, the tensile properties and the CFCI threshold. However, this new expression of the CFCI life needs to be verified by more test results.     

核电材料在模拟反应堆环境中应力腐蚀破裂测试技术与性能评价

简要介绍了采用慢应变速率试验，Ｕ型弯曲和Ｃ形环试验等技术，分别对８００合金，３０４和３１６及３１６Ｔｉ不锈钢Ａ５３３Ｂ压力容器用多在模拟核反应堆环境中的应力腐蚀破裂敏感性性进行的试验研究的一些主要结果；并结合电化学测试和表面膜俄歇电子能谱分析结果进行了讨论。     

Processing of Yttria-Alumina Coated Silicon Nitride Slips by Slip Casting

Si₃N₄powders coated with 6 wt% Y₂O₃and 4 wt% Al₂O₃were prepared by coprecipitation. The resulting powders were dispersed in water at different pH values and with addition of various amounts of ammonium polyacrylate (NH₄PA) to produce 32 vol% slips. The influence of the amount of NH₄PA solution added and pH on the rheological properties of 32 vol% coated Si₃N₄slips were studied. In addition, the sintered density of cast samples was determined and related to the degree of slip dispersion. The adsorption of the NH₄PA on the coated particle surface was rather high and the surface became saturated near 0.86 mg/m²at pH 9.2. High NH₄PA concentrations (1.7–3 wt%) were necessary to obtain well dispersed 32 vol% coated Si₃N₄slips at pH 9.2. The best stabilization was obtained with the addition of 2.3 wt% NH₄PA; in this condition, the viscosity reached a minimum value of 35 mPa.s at 100 s^–1. The slip viscosity increased with increasing pH from 9.2 to 10.2. Slips with low viscosities gave a more dense packing of cast samples and consequently higher sintered density values.     

湿硫化氢环境下的球罐腐蚀状况分析

在湿硫化氢环境下 ,尤其储存介质中的硫化氢含量超标时 ,很容易对储存容器壳体 (含焊缝和母材 )造成硫化氢应力腐蚀或氢鼓包。作者较仔细分析了 1 0 0 0m3 丙烯球罐产生硫化氢应力腐蚀开裂和40 0m3 LPG球罐产生氢鼓包的原因。提出了此类设备在设计选材、设备制造、施工安装和使用维护等环节应注意的问题。     

减粘裂化分馏塔顶系统的腐蚀及防护

辽河石化分公司减粘裂化装置改炼辽河超稠油的减压渣油后 ,分馏塔顶系统由HCl -H2 S -HCN -有机酸 -H2 O引起的电化学腐蚀严重 ,其中油水分离器局部腐蚀速率达 3.1mm/a ,12AlMoV管束的空冷器运行不足两个月即发生泄漏。塔顶系统采用BZH - 1中和缓蚀剂、无机氨BZH - 913油溶性缓蚀剂综合注剂方案 ,使腐蚀得到控制     

Incoloy 800H合金的应用和性能分析

通过对耐热耐蚀合金Incoloy 80 0H的性能分析 ,指出它与普通奥氏体不锈钢相比具有较优的抗氧化性能、耐蚀性和高温蠕变强度。针对催化裂化装置同轴式沉降再生器内部所用Incoloy 80 0H焊件易出现裂纹的问题进行分析 ,认为在施焊过程中由于合金凝固时有低熔点金属或化合物的液态膜残留在晶界区 ,该合金具有高的焊接热裂纹敏感性 ,若焊材选择不当 ,焊丝填充不充分、缺少保护气等将导致晶间裂纹产生。提出了该合金采用TIG焊接防止热裂纹产生的措施。     

加氢裂化热高分油管线弯头开裂分析

对国产加氢裂化热高分油管线的弯头开裂原因进行了分析 ,对预防连多硫酸腐蚀提出了相应的防范措施 :选用碳含量 <0 .0 3 %并含有稳定化元素Ti、Nb的奥氏体不锈钢或双相钢 ;控制焊缝硬度不大于HB2 0 0并焊后热处理 ;12CrMo和 15CrMo耐应力腐蚀性能好 ;设备停运后马上进行清洗并用碱液中和     

复相材料的循环变形行为

对三种组织状态的F-M复相钢进行了对称和非对称循环加载条件下的形变研究.结果表明,双相钢的循环变形行为,不仅与组织中位错组态的演变过程有关,同时也受循环载荷大小、类型以及加载方式所影响.分析表明,双相钢的循环硬化、软化行为主要受控于两个基本过程,即循环变形时位错组态演变的物理过程和相间分载应力的转嫁、相间残余应力变化的力学过程.