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31.
对导热油加热炉炉壁温度升高的原因进行了分析,介绍了新型复合内衬的特点,并对其技术特点、施工工艺及应用效果进行了简单阐述。 相似文献
32.
两栖装甲装备新型防腐材料的研究 总被引:1,自引:0,他引:1
沿海地区特殊海洋环境造成装甲装备的严重腐蚀,为了研制一种新型的耐蚀有机涂层,该文作者研究了有机硅改性环氧树脂的化学反应,并对改性树脂的性能进行了测试分析.结果表明,改性树脂克服了环氧树脂的耐温性差、亲水性强以及盐水渗透率高的性能缺陷,为进一步制备该地区装甲装备防腐涂料奠定基础. 相似文献
33.
H. H. Rehan 《Materialwissenschaft und Werkstofftechnik》2003,34(2):232-237
Water extracts from leaves of date palm, phoenix dactylifera, henna, Lawsonia inermis, and corn, Zea mays, were tested as corrosion inhibitors for steel, aluminum, copper and brass in acid chloride and sodium hydroxide solutions using weight loss, solution analysis and potential measurements. The inhibition action was found to critically depend on metal type and solution composition. Only, date palm and henna extracts were found highly effective in reducing corrosion rate of steel in acid chloride solutions and aluminum in sodium hydroxide solutions. The inhibition efficiency increased with increasing the concentration of the extract. The inhibition was interpreted in terms of chemisorption of some active ingredients in the leaves according to Temkin isotherm. 相似文献
34.
35.
The catalytic activity of fresh Pd and Pt catalysts supported on γ-alumina in the complete oxidation of CH4 traces under lean-burn conditions was studied in the presence or the absence of water or H2S. Steam-aged catalysts were also studied in order to simulate long-term ageing in real lean-burn natural gas fuelled vehicles (NGVs) exhaust conditions. Without water or H2S added to the feed, Pd catalysts exhibit a superior catalytic activity in methane oxidation compared to Pt ones, whatever the catalysts were fresh or aged. The addition of 10 vol.% water vapour to the feed strongly affects the activity of the fresh Pd catalyst, thus being only slightly more efficient than the fresh Pt one. H2S has a strong poisoning effect on the catalytic activity of Pd catalysts, while Pt catalysts are more resistant. The fresh H2S-poisoned Pd/Al2O3 catalyst was studied by TPD in O2/He. Poisoning species decompose above 873 K as SO2 and O2 in relative concentrations consistent with the decomposition of surface sulphate species. However, a treatment in O2/He at temperatures as high as 923 K does not allow the complete regeneration of the catalytic activity of H2S-poisoned Pd/Al2O3. A mechanism involving the poisoning of PdO by sulphate species is proposed. Different diffusion processes by which these sulphate species can migrate back and forth between PdO and the support, depending on the experimental conditions, are suggested. 相似文献
36.
37.
Copper phthalocyanine as corrosion inhibitor for ASTM A606-4 steel in 16% hydrochloric acid 总被引:2,自引:0,他引:2
A study based on the corrosion inhibition properties of copper phthalocyanine is described. Coverage degrees of copper phthalocyanine (Cu-phcy) on ASTM-A606-4 steel, obtained by weight loss measurements, were fitted to Langmuir, Frumkin, Temkin and Flory–Huggins adsorption isotherms. A better fit to the Langmuir isotherm was obtained. The polarization curves showed that polarization of both the anodic and cathodic reactions were verified for concentrations higher than 10–4 M, indicating a mixed type action. Only the anodic reactions were polarized for lower concentrations. At high frequencies the Nyquist diagrams showed one capacitive loop attributable to double layer charging and a small one at intermediary frequencies attributable to the faradaic process of hydrogen evolution. The formation of an adsorbed film was characterized by increasing charge transfer resistance values in the low frequency range for increasing inhibitor concentrations. According to the techniques used in this study, copper phthalocyanines showed a high corrosion inhibiting efficiency for all concentrations. 相似文献
38.
一种新型声波降粘防蜡装置 总被引:1,自引:1,他引:0
新型声波降粘防措装置由上、下接头、振动簧片和收缩喷嘴构成。装置安装在抽油泵泵简之下,尾管之上,在压差作用下井下流体以较大速度从装置的喷嘴射出,冲击振动簧片,产生机械振动声波,油水混合液在声波中产生相应的声波力学效应和分散乳化作用等,使混合液在油管内的粘度降低,蜡晶不易聚集长大,从而达到降粘防蜡延长油井热洗周期的目的。室内试验及现场近20口井的应用情况表明,这种装置具有结构简单、成本低廉、应用方便等特点,具有明显的降粘防蜡效果。 相似文献
39.
The GILDES computer model, incorporating Stumm's concept of proton- and ligand-promoted dissolution, has been used to simulate the exposure of copper at room temperature to 210 ppb sulfur dioxide and 80% relative humidity. The agreement is good between the calculations and laboratory exposures performed under these exposure conditions. Surface reactions are relatively more important at lower relative humidities and the dominant corrosion products formed are solid state Cu2SO3, CuSO3 and Cu2U. Free-radical redox processes are important participants and control the relative distribution of Cu(I)- and Cu(H)-containing corrosion products. 相似文献
40.
Rates of coke formation during steam pyrolysis of naphtha have been investigated in a jet-stirred reactor both for sodium silicate coated and uncoated Inconel 600 surfaces in the temperature range of 1078–1108 K. Coke formation rates were significantly reduced on sodium silicate coated plates due to the passivation of the metal surface. However, the coking rates gradually increased with successive decokings of the coated surface. 相似文献