Formation of WC/Ni hard alloy coating by laser cladding of W/C/Ni pure element powder blend

WC/Ni coating was formed by laser cladding of a W/C/Ni powder blend. The formed WC crystals have rectangular or quadrangle cross-section shapes with size of 2–30 μm. Step, twist and cross growth morphologies of WC formation were observed. The coating contains WC, CW_3, WNi, FeW₃C, Fe₆W₆C, W₃O, W, C, and (Fe,Ni) phases.     

钢表面化学气相沉积TiC晶体的择优取向

本文用化学气相沉积(CVD)法,以TiCl_4-CH_4-H_2为原料气体,在不锈钢表面获得了致密的TiC膜.研究了TiC的成膜速度、表面形貌和晶体择优取向与沉积条什的关系.结果表明,沉积温度T_(dep),碳钛比CH_4/TiCl_4强烈地影响了TiC的成膜速度、表面形貌和晶体择优取向.CH_4/TiCl_4低时,TiC晶体的择优取向为(220):而CH_4/TiCl_4高时,TiC晶体的择优取向为(200).TiC晶体的择优取向主要取决于气氛中活性碳的平衡浓度。     

钼对渗碳过程中碳化物形态的影响

通过萃取复型观察和对衍射花样的标定，研究了深层渗碳过程中析出碳化物的形态和分布。实验结果表明：渗碳过程中析出的形态较好的碳化物，象点状、球状和椭球状碳化物均为钼的碳化物；而形态较差的针状、网状则为（Cr、Fe）7C3和（Fe，M）3C。并对其形成机理进行了初步探讨。     

基于阈值分割的松材线虫病树计数与定位

松材病虫病是最紧迫的威胁之一,最近对中国针叶林造成了严重破坏,为了阻止松材病虫病的快速传播,必须在早期准确检测和计数受感染的树木。提出了一种基于密度图的方法,用于从高分辨率航拍图像中估计具有松材病虫病的树木数量,方法引入了阈值分割、形态处理和超像素技术,以最大限度地减少由于建筑物和岩石等相似背景物体引起的误差。实验表明,所提出的方法优于密度学习 算法,平均绝对误差、均方根误差和绝对误差方差分别从21.3、22.2和127.2减少到8.0、11.7和59.6,计数准确率从54.7%提高到81.3%。     

N,N−二甲基−二硫代甲酰胺丙磺酸钠对THPED体系化学镀铜的影响

研究了N,N?二甲基?二硫代甲酰胺丙磺酸钠(DPS)作为添加剂对以四羟丙基乙二胺(THPED)为单一配位剂的化学镀铜体系的沉积速率、镀层形貌和晶体结构的影响。结果发现,当DPS的质量浓度从0 mg/L增大到1.0 mg/L时,沉积速率从2.91μm/h提高到6.73μm/h,所得镀层结晶均匀、细致。线性扫描伏安测量结果表明,DPS是通过促进甲醛的阳极氧化来加速化学镀过程。本体系的Cu镀层主要呈面心立方多晶取向,DPS的添加会令晶面取向从(220)转变为(111)。     

不同晶型纳米二氧化锰制备及对亚甲基蓝吸附性能

以高锰酸钾（KMnO₄）为氧化剂、硫酸亚铁铵[（NH₄）₂Fe（SO₄）₂]为还原剂,用水热氧化还原反应制备了层状δ-二氧化锰和隧道型α-二氧化锰纳米材料。用X射线衍射（XRD）、扫描电镜（SEM）和氮气吸-脱附技术对产物的晶型、形貌及孔结构进行了表征。实验结果表明,δ-二氧化锰呈花状微球形貌,具有介孔结构（平均孔径为3.4 nm）,BET比表面积为219 m²/g;α-二氧化锰呈纳米线束形貌,具有部分介孔结构（平均孔径为35.7 nm和154.6 nm）,BET比表面积为26 m²/g。研究了不同晶型纳米二氧化锰对亚甲基蓝的吸附性能。实验结果表明,在相同条件下α-二氧化锰的吸附性能优于δ-二氧化锰,且在碱性环境下吸附效果较好。当反应时间达到120 min时,α-二氧化锰和δ-二氧化锰对亚甲基蓝的去除率分别为84.4%和82.9%。     

Structure and electronic properties of SiC thin-films deposited by RF magnetron sputtering

SiC thin-films were prepared by RF-magnetron sputtering technique(RMS) with the target of single crystalline SiC and then annealed. The surface morphology of thin-films was characterized by AFM. The result shows that the surface of the thin-films is smooth and compact; XRD analysis reveals that the thin-films are amorphous. The thickness, square-resistance and curves of resistance—temperature were measured. The results show that the curves of lnR versus 1/kT both before and after annealing satisfy the expression of lnR∝△W/kT, where ?W is electron excitation energy in the range of 0.014 2-0.018 5 eV, and it has a trend of increasing when the temperature is increased. After synthetical analysis we get the conclusion that the electronic mechanism of the thin-films is short distance transition between the localized states in the temperature range of 25-250 ℃. The resistivity is in the range of 2.4×10-3-4.4×10-3 Ω·cm and it has the same trend as electron excitation energy when annealing temperature is increased, which further confirms the electronic mechanism of thin-films and the trend of electron excitation energy versus annealing temperature.     

化学镀Ni-P镀层的组织形貌与耐蚀性

通过观察化学镀Ni－P镀层沉积过程形貌及形貌变化特征，研究了用不同镇液化学镀所获得的不同含磷量镀层的形貌变化，并指明在含磷量为（4．0～7．0）％范围内，镀层成胞状和菜花状的腐蚀破坏常常首先沿胞壁进行，且大胞中心易出现腐蚀裂纹和沟槽。若胞的大小均匀，凸凹不明显，胞表面光滑，含磷量均匀，则耐蚀性好。     

Tensile behavior change depending on the varying tungsten content of W–Ni–Fe alloys

Tungsten heavy alloys (WHAs) are metal–metal composites consisting of nearly pure spherical tungsten particles embedded in a Ni–Fe–W or Ni–Co–W or Ni–Cu–W ductile matrix. In this dual phase alloy, there are several complicated relations between the ductile matrix and hard tungsten particles. The aim of this research was to examine the effect of varying tungsten content on the microstructure and mechanical properties of tungsten heavy alloys. The microstructural parameters (grain size, connectivity, contiguity and solid volume fraction) were measured and were found to have a significant effect on the mechanical properties of tungsten-based heavy alloys. The result shows that the binding strength between the W and the matrix phase has a major influence on the ductility of tungsten-based alloys. The larger this binding force is, the better the ductility is.     

超声参振对Al-Fe合金凝固过程的影响

在Al-Fe合金的凝固过程中引入不同功率的超声振动,利用受控凝固和受控振动相结合的实验装置和方法,研究了超声参振对Al-Fe合金熔体温度场以及组织形态和抗拉强度的影响.实验表明:熔体的温度场随振动功率的增加和振动时间的延长而升高,并趋于一个平衡的温度场;超声参振可以显著细化先共晶FeAl3相,Al-Fe合金生长的组织形态的差异主要取决于凝固速度;超声参振凝固的Al-Fe合金的热稳定性好,有良好的应用前景.