如何正确选择合适的耐蚀材料

文章较全面的介绍了如何根据设备、装置、构件所处的工作环境及使用条件进行防腐蚀设计,及其防腐蚀设计的内容和注意事项,选择合适的防腐蚀材料,确保产品的使用寿命     

Biodegradation and corrosion behavior of manganese oxidizer Bacillus cereus ACE4 in diesel transporting pipeline

The degradation problem of petroleum products arises since hydrocarbon acts as an excellent food source for a wide variety of microorganisms. Microbial activity leads to unacceptable level of turbidity, corrosion of pipeline and souring of stored product. The present study emphasizes the role of Bacillus cereus ACE4 on degradation of diesel and its influence on corrosion of API 5LX steel. A demonstrating bacterial strain ACE4 was isolated from corrosion products and 16S rRNA gene sequence analysis showed that it has more than 99% similarity with B. cereus. The biodegradation and corrosion studies revealed that B. cereus degraded the aliphatic protons and aromatic protons in diesel and is capable of oxidizing ferrous/manganese into oxides. This is the first report that discloses the involvement of manganese oxidizer B. cereus ACE4 on biodegradation of diesel and its influence on corrosion in a tropical country pipeline.     

Validity of dynamic electrochemical impedance spectra of some amine corrosion inhibitors in petroleum/water corrosive mixtures by Kramers-Kronig transformation

In our previous works, the corrosion inhibition properties of propylamine (PA), iso-propylamine (i-PA), butylamine (BA), tert-butylamine (t-BA), hexylamine (HA), ethylenediamine (EDA), diethanolamine (DEA), 3-amino-1-propanol (3-AP), 2-dimethylethanolamine (2-DEA), cyclohexylamine (CHA), N-methylcyclohexylamine (N-MCA) and dicyclohexylamine (DCHA) have been investigated by means of electrochemical impedance spectroscopy (EIS) with a carbon steel rotating disc electrode in some petroleum/water corrosive mixtures containing acetic acid and NaCl at 25 °C. In this work, the Kramers-Kronig transformations (KKTs) were applied to evaluate the validity of the impedance data of these amine compounds in hydrodynamic condition. The results obtained showed that experimental impedance data did not satisfy in K-K relations completely viz. indicated some errors. These errors were related to stray capacitances, external transmission line effects, pits formation and change in interface during data acquisition at high and low frequencies regions. In addition, the selection of a suitable equivalent circuit strongly emphasized to better interpret of EIS data which in turn cause better resulted KKTs spectra. With considering obtained transformations, more effective inhibitor was selected with regard to its charge transfer resistance, the corrosion capacitance and well satisfying in K-K relations.     

Corrosion Behavior of a Sputtered K38G Nanocrystalline Coating with a Solid NaCl Deposit in Wet Oxygen at 600 to 700°C

A nanocrystalline coating of K38G alloy was obtained by means of magnetron sputtering. The corrosion behavior of cast K38G alloy and its sputtered nanocrystalline coating with a solid NaCl deposit in dry air or wet oxygen at 600 and 700°C have been studied and compared. The results indicated that the mass gain of the coating is higher than that of the cast alloy at 600 and 700°C. Therefore, nanocrystallization reduced the corrosion resistance at these temperatures. Furthermore, the mass gains of the coating and the cast alloy with a NaCl deposit in wet oxygen were less than that with a NaCl deposit in dry air. The relevant corrosion mechanisms are discussed.     

蒸馏与减粘热联合装置的设备腐蚀及防护

介绍了锦西石化分公司南蒸馏与减粘热联合装置炼制辽河高酸值原油及带炼高硫进口油在 2 0 0～40 0℃范围内对设备、管线和阀门的腐蚀特点、腐蚀机理以及针对高温环烷酸腐蚀所采取的防护措施。通过试验和理论分析 ,提出了应用新材料和新工艺解决减粘后高温渣油系统的腐蚀及低温露点腐蚀的建议     

杜84断块超稠油开发中后期稳产对策研究

对杜84断块超稠油生产中后期暴露的主要矛盾，即随着轮次升高，周期吞吐效果变差，井下技术状况日益变差。油层动用不均，汽窜加剧等问题进行了分析。并提出了相应的稳产对策-实施多井整体吞吐，大修复产，调剖等措施。现场应用证明，这些措施基本能够确保杜84断块超稠油中后期的稳产。     

高压锅炉补给水系统管道的腐蚀

讨论了锅炉补给水管道的腐蚀情况 ,指出溶解氧和二氧化碳是产生腐蚀的主要原因 ,其腐蚀速率为0 .4 2mm/a。确保真空除气系统正常运行和二级除盐水箱的密封效果是控制腐蚀的主要手段。在此情况下 ,该管线尚可运行 7年     

凝析气藏物质平衡方程的改进与应用

为了提高凝析气藏油气采收率，通常采用目前最有效的循环注气保持地层压力的开采方式。在此开采方式下，直接采用气藏物质平衡方程进行地质储量计算将出现很大偏差。针对这种情况，将气藏物质平衡方程进行了改进，得到凝析气藏在注气开发方式下的物质平衡方程。     

罐装食品用电镀锡板的耐蚀性及其试验方法

综述了影响罐装食品用电镀锡板耐蚀性能的因素及其试验方法。