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991.
Sodium sulfate: Deposition and dissolution of silica 总被引:1,自引:0,他引:1
Nathan S. Jacobson 《Oxidation of Metals》1989,31(1-2):91-103
The hot-corrosion process for SiO2-protected materials involves deposition of Na2SO4 and dissolution of the protective SiO2
scale. Dew points for Na
2SO4 deposition are calculated as a function of pressure, sodium content, and sulfur content. Expected dissolution regimes for SiO2 are calculated as a function of Na2SO4 basicity, hence
generated by fuels with 0.5% and 0.05% S. Controlled-condition burner-rig tests on quartz verify some of these predicted dissolution regimes. However, the basicity of Na2SO4 is not always a simple function of
(Na2O) show that carbon creates basic conditions in Na2SO4, which explains the extensive corrosion of SiO2-protected materials containing carbon, such as SiC. 相似文献
992.
993.
Dilute copper-aluminium alloys were oxidized in air from 700 to 1000 °C. Two distinctive behaviours were observed: alloys with at least 3 wt% aluminium showed excellent oxidation resistance in the whole temperature range. Alloys with 2 wt% or less aluminium exhibited good oxidation resistance up to 800 °C; but as the temperature was further increased, the oxidation rate of these alloys increased and became comparable to that of pure copper. A kinetic model was developed to explain the oxidation behaviour and indirectly determine the amount of dissolved oxygen in the alloys tested. It was found that the oxygen dissolved in alloys with up to 2 wt% Al exceeded its solubility limit in copper, whereas the dissolved oxygen in alloys with higher aluminium contents was below the solubility limit. This difference may account for the significantly different oxidation resistance. 相似文献
994.
995.
Key experiments were carried out on the three Al–R–Mg (R=Gd,Dy,Ho) systems and the results obtained used for the thermodynamic optimisation reported in a separate paper in this issue [Caccasmani G, De Negri S, Saccone A, Ferro R. Intermetallics this issue.]. The samples were characterized by differential thermal analysis (DTA), X-ray powder diffraction (XRD), light optical microscopy (LOM), scanning electron microscopy (SEM) and quantitative electron probe microanalysis (EPMA). The isothermal sections at 400 °C are all characterized by extended homogeneity regions at a constant rare earth content. The extension of the (Mg,Al)R solid solution, cP2-CsCl type, varies with the R atomic number. Ternary compounds (τ) of Al2(R,Mg) stoichiometry (hexagonal Laves phases with MgNi2-type structure) have been found to exist at 400 °C in all the systems. Their temperatures of formation were detected by DTA measurements. 相似文献
996.
Compared with grinding, hard turning is competitive in many cases, with substantial benefits. However, hard turning applications are not preferred, due to the existence of the process-induced white layer on the component surface, which is often assumed to be detrimental to component life. Nevertheless, white layer properties have not been well understood or clearly defined, especially the properties of the white layer induced in hard turning as against grinding. A clear understanding of white layer properties will provide a solid physics basis for product performance analysis and useful data for process selection. In this study, benchmark hard turning and cylindrical grinding experiments were conducted to generate thick white layers for reliable measurement. It was found that the properties of white and dark layers by hard turning and grinding are fundamentally different in four aspects: surface structure characteristics, microhardness, microstructures, and chemical composition. A white layer is not untempered martensite in terms of retained austenite. Additionally, a thick white layer can be produced in grinding under certain conditions. 相似文献
997.
Surface modification of spherical LiNi1/3Co 1/3 Mn1/3O2 with Al2O3 using heterogeneous nucleation process 总被引:1,自引:0,他引:1
To improve the cycle stability at high voltage and high charge/discharge rate, spherical LiNi1/3Co1/3Mn1/3O2 was coated with Al2O3 by using heterogeneous nucleation process, and the physical and electrochemical properties were studied. The SEM images show that there is a uniform coating on the modified spherical LiNi1/3Co1/3Mn1/3O2. The electrochemical tests indicate that the properties of LiNi1/3Co1/3Mn1/3O2 coated with 0.5% aluminum oxide are the best. The initial capacities are 150 and 173 mA.h/g at the rate of I C in the voltage range of 2.7-4.3 V and 2.7-4.6 V, respectively, and the discharge capacities maintain about 99% and 85% after 30 cycles, respectively. While those of the bare LiNi1/3Co1/3Mn1/3O2 are only 90% and 75%, respectively. The CV tests of LiNi1/3Co1/3Mn1/3O2 show that Al203-coating can restrain the oxide-reduction peak currents fading during the charge/discharge course. 相似文献
998.
调制波长对Cu/Ni金属多层膜力学性能的影响 总被引:2,自引:0,他引:2
用电沉积法在低碳钢基体上制备了具有不同调制波长(一个调制波长等于单层Cu膜与单层Ni膜厚度之和)的Cu/Ni金属多层膜,研究了多层膜硬度与其中单层膜厚度之间的关系。结果表明,当膜厚在亚微米范围内时,Cu/Ni多层膜的屈服强度(为硬度值的1/3)与单层膜厚之间符合基于位错塞积模型的Hall-Pctch(H-P)关系式;而当单层膜厚小于100nm时,屈服强度与膜厚的关系偏离了H-P线性关系。基于程开甲等人位错稳定性理论首次对金属多层膜变形行为偏离Hall-Petch关系的现象作了定量解释。 相似文献
999.
The extended X-ray absorption fine structure (EXAFS) method and transmission electron microscopy (TEM) have been used for characterizing the local structure and morphology of ferric oxyhydroxides, α-FeOOH and γ-FeOOH, with and without chromium. These ferric oxyhydroxide powders were prepared from aqueous solutions containing iron and chromium ions. Radial structural functions for iron obtained by Fe K edge EXAFS spectra showed that the linkage of structural units formed by FeO6 octahedra in γ-FeOOH is distorted by chromium addition, while such distortion in α-FeOOH is not clearly detected. On the other hand, Cr K edge EXAFS spectra showed that the local structure around chromium does not necessarily correspond to the local structure around of iron, which is observed by Fe K edge EXAFS spectra. This suggests that the structural units containing iron and chromium are heterogeneously distributed in these ferric oxyhydroxides. The local structural information was discussed coupled with morphological features of these ferric oxyhydroxides observed by TEM. 相似文献
1000.
Attila Diószegi 《中国铸造》2007,4(3):210-214
The thermal conductivity or diffusivity of pearlitic grey irons with various carbon contents is investigated by the laser flash method. The materials are cast in controlled thermal environments and produced in three dissimilar cooling rates. The cooling rate together with the carbon content largely influence the thermal conductivity of grey iron. Linear relationships exist between the thermal conductivity and the carbon content, the carbon equivalent and the fraction of former primary solidified austenite transformed into pearlite. The work shows that optimal thermal transport properties are obtained at medium cooling rates. Equations describing the thermal conductivity of pearlite,solidified as pre-eutectic austenite, and the eutectic of grey iron are derived. The thermal conductivity of pearlitic grey iron is modeled at both room temperature and elevated temperature with good accuracy. 相似文献