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61.
Zhiqiang Wu Qiang Guo Yang Liu Huihui Zhou Hua Zheng Xingfeng Lei Lei Gong Yanhui Chen Zhenguo Liu Qiuyu Zhang 《大分子材料与工程》2021,306(11):2100456
In order to meet the requirements of polymer dielectric materials for high thermal stability and excellent dielectric properties in the application of high-temperature film capacitors, a series of polyimide (PI) films are fabricated by introducing a self-synthesized aniline trimer (ACAT) with a conjugated structure in this work. Since the conjugated ACAT in the main chains of PI improves the electron polarization and carrier mobility of the PI molecular chains, the dielectric constant of the ACAT-PI films is greatly enhanced (4.4–7.4). Meanwhile, the dissipation factor does not increase apparently (0.002–0.013). The dielectric properties are stable even when the temperature is up to 200 °C, the thermal degradation temperature is as high as 450 °C, and the mechanical properties are also excellent (70–105 MPa). Among all the films, the PI film with 5 mol% ACAT exhibits the maximal energy density of 3.6 J cm−3 under the field of 426 kV mm−1, the high tensile strength (90 MPa) and the excellent thermal stability (Td5 = 515 °C). The work paves the way to prepare high-temperature polymer dielectric film materials with high energy storage density. 相似文献
62.
Effects of CeO2 doping on the structure and properties of PSN-PZN-PMS-PZT piezoelectric ceramics 总被引:1,自引:0,他引:1
SUN Qingchi LU Cuimin ZHOU Hua 《稀有金属(英文版)》2005,24(3):235-239
Quinary system piezoelectric ceramics PSN-PZN-PMS-PZT were prepared by using a two-step method. The effects of CeO2 doping on piezoelectric and dielectric properties of the system were investigated at morphotropic phase boundary (MPB). The results reveal that the relative dielectric constant ε33^T|ε0, the Curie temperature To, the piezoelectric constant d33, the mechanical quality factor Qm, and the electromechanical coupling coefficient Kp are changed with the increase of CeO2 content. On the other hand, the effects of CeO2 doping on the dielectric properties of PSN-PZN-PMS-PZT piezoelectric ceramics at high electric field are consistent with the change at weak electric field. The values of dielectric constant and dielectric loss are enhanced with the increasing of electric field. 相似文献
63.
The polymer-ceramic composites of epoxy resin (EP) and barium titanate (BT) were prepared.BT powders of different BT particle sizes from 100 nm to 1 μm were used in the preparation.The dielectric properties, such as dielectric constant, dielectric loss and electrical breakdown strength, of the EP/BT composites were studied.The morphology of the composites was characterized by the means of scanning electron microscopy (SEM).The results show that the dielectric constant of the composites is much higher than the epoxy matrix at frequency range from 1 kHz to 10 MHz, and it is also obviously dependent on the size of BT particles.The electrical breakdown strength of the composites decreases with the increase of the BT content.The dependence of electrical breakdown strength on BT particle sizes was also discussed. 相似文献
64.
混粉电火花镜面加工技术及应用 总被引:2,自引:0,他引:2
利用自行研制的混粉电火花镜面加工装置,对混粉电火花镜面加工影响因素,加工表面性能等进行了深入研究,找出了粉末特性,工件材料,粉末浓度及放电参数等对混粉电火花镜面加工的影响规律,给出了合理的混粉电火花镜面加工工艺条件,以文中确定的加工工艺条件对铸造和压铸模具进行混粉电火花镜面加工,结果表明,该技术能提高模具制造质量,降低工人劳动强度,缩短模具制造周期。 相似文献
65.
PBSZT系大功率压电陶瓷极化工艺的研究 总被引:1,自引:0,他引:1
为探索大功率低损耗压电陶瓷材料的最佳制备工艺,对改性锆钛酸铅压电陶瓷Pb0.9Ba0.05Sr0.05(Sn1/3Nb2/3)0.06(Zn1/3Nb2/3)0.06Ti0.44Zr0.44O3 0.5wt%MnO2 0.5wt%Sb2O3的极化工艺进行研究。结果表明,该体系的最佳极化电场为4Kv/mm,极化温度120℃左右,此时得到的陶瓷性能较佳。 相似文献
66.
67.
Hung C. Ling Man F. Yan Warren W. Rhodes 《Journal of the American Ceramic Society》1991,74(2):287-289
The aging behavior of a series of lead perovskite dielectrics with the compositions x Pb(Fe2/3 W1/3 )O3 ·(1 – x )Pb(Fe1/2 -Nb1/2 )O3 , where 0 ≤ x ≤ 1, and the effect of dopants were studied. Below the Curie temperature ( T c ), the capacitance and the dissipation factor (tan δ) decrease approximately linearly with logarithmic time. The aging rate depends on the temperature difference, Δ T , between the aging temperature and T c , and on the dopant concentration, but is independent of the measurement frequency between 1 and 1000 kHz. The maximum aging rate is about 3% per decade of time for capacitance and 5% per decade for tan δ at 1 mol% dopant concentration, and increases to 6.3% for capacitance and 8.5% for tan δ at 0.7 mol% dopant concentration. These results are consistent with an aging mechanism caused by changing ferroelectric domain structure with time, as proposed for BaTiO3 . 相似文献
68.
Xingsen Gao Junmin Xue John Wang Ting Yu Ze Xiang Shen 《Journal of the American Ceramic Society》2003,86(5):791-794
0.6Pb(Ni1/2 W1/2 )O3 ·0.4PbTiO3 (0.6PNW·0.4PT) of complex perovskite structure is successfully synthesized by mechanical activation of mixed oxide composition, followed by sintering at 950°C. It exhibits a considerably stable temperature dependence of dielectric constant over the wide temperature range of −120° to 20°C, although there occurs a dielectric peak at around 74°C. Raman spectroscopic studies show the coexistence of tetragonal and pseudocubic perovskite phases on sintering at 950°C, which are attributed to the inhomogeneous distribution of PbTiO3 arising from mechanical activation. The dielectric behavior can be fine tuned by thermal annealing at 750°C, leading to phase redistribution in PNW-PT. 相似文献
69.
The effect of miscible low molecular weight additives on the mobility of the carbonate group in bisphenol-A polycarbonate (BPAPC) has been studied using n.m.r. and dielectric relaxation experiments in the solid state. Proton-enhanced dipolar-decoupled carbon-13 n.m.r. spectra of BPAPC, isotopically enriched at the carbonate position, are obtained without magic-angle sample spinning. The resolved chemical shift anisotropy allows study of nuclear spin relaxation for the carbonate groups in the polymer that have different orientations relative to the static magnetic field in the laboratory frame. The spin-lattice relaxation time in the rotating frame (T1?) is measured at a motional-probe frequency of 50 kHz for the undiluted polymer and for BPAPC-diluent blends containing either dibutylphthalate or dinitrobiphenyl. The T1? exhibits some dependence on orientation in all systems studied. In the blend containing dibutylphthalate (DBP), T1? is decreased by a factor of two for all orientations of the carbonate group. This implies that DBP substantially increases the spectral density of 50 kHz motions in the carbonate region of the polymer at ambient temperature. In contrast, dinitrobiphenyl does not significantly alter the Fourier component of thermal fluctuations at 50 kHz. Dielectric relaxation measurements at 10 kHz reveal that the primary (Tg) and secondary (β) motional processes in BPAPC are affected by low molecular weight additives. An intermediate relaxation process appears in the temperature interval between the glass transition temperature (Tg) and the sub-Tg β-relaxation (Tβ) in the polymer-diluent blends. The n.m.r. spin-lattice relaxation rate in the rotating frame, T?11?, correlates well with the relative magnitude of the dielectric dissipation factor (tan δε) between Tg and Tβ. 相似文献
70.
锰掺杂对PNW-PMS-PZT压电陶瓷结构和性能的影响 总被引:1,自引:1,他引:1
采用传统陶瓷工艺制备了Pb(Ni1/2W1/2)O3-Pb(Mn1/3Sb2/3)O3-Pb(Ti,Zr)O3-xMnO2压电陶瓷,分析了经1150℃烧结2h制备的陶瓷样品的相结构组成。实验结果表明:所有陶瓷样品均为钙钛矿相,未发现其它晶相。随着锰掺杂量的增加,陶瓷晶粒逐渐长大。研究了不同剂量的锰掺杂对压电陶瓷介电和压电性能的影响。结果表明:随着锰掺杂量的增加,材料逐渐变“硬”,当MnO2掺杂量少于0.2%(按质量计,下同)时,相对介电常数εr、压电常数d33和机械品质因数Qm逐渐增加,介电损耗tanδ减小;当MnO2掺杂量多于0.2%时,εr、d33和Qm逐渐降低,tanδ增加。随着锰掺杂量的增加,机电耦合系数kp和Curie温度θc逐渐减小。MnO2掺杂量为0.2%的压电陶瓷适合制作大功率压电陶瓷变压器。其压电性能为:εr=2138,tanδ=0.0058,kp=0.613,Qm=1275,d33=380pC/N和θc=205℃。 相似文献