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91.
A number of copolymers were synthesised by condensing the 2,4-dinitrophenylhydrazone of resacetophenone with substituted benzoic acids/ phenols and formaldehyde in the presence of sodium hydroxide or hydrochloric acid. The decomposition temperature, solubility and viscosity of the polymers have been determined. The ion-exchange properties have been studied by using a batch equilibrium method. The distribution of a number of metal ions between an aqueous solution and the resin have been measured. A wide range of pH and variable ionic strengths have been investigated. 相似文献
92.
Although the gas metal arc welding (GMAW) process is widely used for joining metals, its planning is still a cumbersome task. The planning procedure involves many complex interrelationships among the process variables and depends heavily on empirical knowledge. Therefore, a solution method that allows a convenient way to represent the domain knowledge and evaluate the process variable relationships is needed. Further, the lack of a strong domain theory to quantify these interrelationships is a deficiency in the planning of the GMAW process. This paper presents a solution method that overcomes this deficiency and introduces a convenient knowledge representation scheme. The solution method considers the planning procedure to be a constraint satisfaction problem (CSP). The AC-4 algorithm is used to obtain arc consistency among nodes in the constraint network and the PC-4 algorithm is applied to obtain path consistency in the network. A modified version of the AC-4 algorithm is developed to reduce the search space and correspondingly reduce the computation time. An example is presented to demonstrate the capability of the method and its potential to reduce lead time. 相似文献
93.
Using the batch method, the retention of Ga(III) from HCl solutions by two gel‐type pyridine strong‐base anion exchangers containing 1‐methyl‐ or 1‐butyl‐4‐vinylpyridinium chloride structural units, called S1 and S2 resins, respectively, was studied. The influence of the HCl and Ga(III) concentrations as well as of the contact time between the resin and the liquid phase was investigated. The parameters, which characterize the retention process, were estimated using Langmuir and Freundlich isotherms. Both resins exhibited a higher affinity for gallium ions from a 6M HCl solution. According to Langmuir isotherms, maximum retention capacities of 44.44 and 60 mg Ga(III)/g dry resin for the S1 and S2 resins, respectively, were obtained. Freundlich isotherms provide additional proof for a higher affinity of the S2 resin for Ga(III) from HCl solutions. It is clear that the substituent length increase on N+ atoms led to an increasing affinity of the pyridine strong base anion exchangers toward Ga(III). © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3440–3444, 2002 相似文献
94.
介绍了鄂钢电炉厂70t consteel 电炉使用炉壁集束碳氧枪后对经济指标的改善,以及在生产实践中的冶金效果. 相似文献
95.
The interaction of alkali metal with surfaces has been of great interest to the community of catalysis since alkali metal can play an important role as a promoter. On alkali-doped MoS2, such a promotion effect of alkali metal has been exemplified in the direct synthesis of linear alcohols from CO and H2, where the alkali-doping switches the catalyst selectivity from methanation to alcohol synthesis. This paper reviews recent high-resolution X-ray photoelectron spectroscopy experiments that have provided direct
observation of electron transfer from alkali metals to a model single crystal MoS2 and the capture of the supra-valence electrons in the subsequent oxidation reactions. 相似文献
96.
David Nistr Karin Keis Sten-Eric Lindquist Anders Hagfeldt 《Solar Energy Materials & Solar Cells》2002,73(4)
In this paper a transport equation is derived which describes the behaviour of the nanostructured metal oxide films in a photoelectrochemical cell. It is shown that a detailed analysis of the charge compensation mechanism necessarily leads to a transport equation with characteristics similar to but logically distinct from the pure diffusion equation. The studied phenomenon was named ambipolar diffusion in the early 1950s. It takes into account the fact that the diffusion processes of ions and electrons occur at different speeds. A weak electric field therefore couples the processes together to preserve charge neutrality. The electric field in turn affects the transport resulting in a deviation from purely diffusive behaviour. However, this has not been widely recognised in the literature for nanostructured semiconductor films until very recently. In this paper a detailed analysis is presented. It is based on the assumption that the current density is solenoidal. It is shown that application of the ambipolar diffusion model to a photoelectrochemical cell based on a nanostructured metal oxide film leads to an additional term in the transport equation, rather than only a new diffusion coefficient as in earlier work. It is also shown that the boundary conditions interact closely with the equation to form a transport model. 相似文献
97.
98.
99.
固载于SBA-15分子筛中的同双核金属配合物催化剂 总被引:3,自引:1,他引:2
合成了3种同双核金属配合物[M2LCl3]Cl(L代表配体三亚乙基四胺,M代表Co,Cu,Cr),采用微波加热法合成了SBA-15分子筛,采用浸渍法将3种同双核金属配合物分别固载在表面官能化的SBA-15分子筛(SBA-15-NH2分子筛)中制得负载型催化剂。傅里叶变换红外光谱、X射线衍射、紫外可见光谱和热分析表征结果表明,同双核金属配合物被固载后,其结构仍保持完整。以环己烷氧化反应为探针反应,考察了[Co2LCl3]Cl/SBA-15-NH2,[Cu2LCl3]Cl/SBA-15-NH2,[Cr2LCl3]Cl/SBA-15-NH2催化剂的活性,环己烷转化率分别为11.0%,49.5%,57.9%;对于[Cr2LCl3]Cl/SBA-15-NH2催化剂,当分别以乙睛、丙酮和冰醋酸为溶剂时,环己烷转化率分别为57.9%,52.1%,34.2%,3次重复实验的环己烷转化率分别为57.9%,47.8%,46.5%,表明该催化剂具有较好的活性和重复使用性。 相似文献
100.
地下水污染修复的活性渗滤墙技术 总被引:15,自引:0,他引:15
活性渗滤墙是一种现场修复受污染地下水的新型技术,具有原理简单,施工方便,运行费用低廉等特点,活性渗滤墙垂直于地下水流动方向设置,当地下水流通过活性渗滤墙时,污染物与墙体材料发生化学反应,从而达到环境修复的目的。文中综述了活性渗滤墙技术的修复机理和实际应用,大量研究表明,应用金属铁作为活性渗滤墙材料,可以去除地下水中的重金属以及有机污染物,目前活性渗滤墙已经在世界各地应用,是一种非常有发展前景的环境污染修复技术。 相似文献