Photoresponsive peptide and polypeptide systems: part II. Photochromism of poly(l-ornithine) containing various azo-contents in side chains

Poly(L-ornithine)s having various azo-contents in the side chains were synthesized by the water-soluble carbodiimide procedure. The photochemical properties of the polypeptides poly[N^δ-p-(phenylazo)benzoyl-L-ornithine] (PPABLO) containing 3–77 mol% azobenzene were investigated by absorption and circular dichroism spectroscopy in hexafluoro-2-propanol (HFIP) or water, and in HFIP-water or methanol-water solvent mixtures. The photochromism of the dichroic bands of the PPABLOs containing 20–77 mol% azobenzene in the visible and ultraviolet wavelength regions was found to be mostly reversible as a function of irradiation time at different wavelengths due to the photostationary state (above 80% trans-cis photoisomerization) of the azo aromatic moieties. The PPABLO containing 3.2 mol% azobenzene in water exhibited conformational changes from random coil to helix by the addition of methanol or sodium dodecyl sulphate (SDS). The photo-induced conformational change was observed in HFIP-water-SDS solvent mixtures, while no conformational change was seen in water and HFIP-water solvent mixtures.     

电子直线加速器中计入纵向与横向耦合效应的束流包络线方程组

一、引言从束流动力学的观点出发,对于粒子束在直线加速器中的运动,有两种主要的分析方法,也即粒子轨迹跟踪法及考察束流包络运动的方法。前者是通过解单粒子运动方程,跟踪大量的单粒子运动轨迹而后进行分析;后者则是通过解束流的包络线方程,根据束流包络的变化来进     

稀土混合物水溶液中囊泡的形成

依据柠檬酸的螯合作用和乙二醇的空间位阻效应，获得了稀土混合物囊泡。并利用ＩＣＰ、ＴＥＭ、ＦＳ等仪器对囊泡的性能进行了研究，最后对囊泡的形成机理进行了讨论。     

五强溪水电站缆索起重机的安装与使用

五强溪水电站主体工程混凝土浇筑垂直运输在大坝两岸分高、低层布置４台平移式２０ｔ缆索起重机。其中２台高缆从德国引进，属世界上首次采用全遥控的缆机，同时也是国内塔架最高的缆机；２台低缆属我国目前自行设计制造安装的规格最大、速度最高的缆机。     

Fundamental solutions for half plane with an oblique edge crack

An elastic half plane with an oblique edge crack is considered in this paper. A pair of concentrated forces or point dislocations is assumed to act at an arbitrary point in the half plane. The half plane with an edge crack is first mapped into a unit circle by a rational mapping function so that the following analysis can be carried out on the mapped plane analytically. Then the complex stress functions are derived by separating the whole problem into two parts; one is the principal part corresponding to the infinite plane acted on by concentrated forces or dislocations, the other is the holomorphic part, which can be determined by making use of the property of regularity of complex stress functions. The stress intensity factors of the crack can be calculated with different inclined angles of the crack, and the displacement and stress components at an arbitrary position in the half plane can be expressed explicitly.     

红外热成象技术在股骨头坏死疾病针刺疗法中的应用

红外热成象技术可以有效地用于股骨头坏死疾病的诊断和针刺治疗效果的评价，效果优于其它常规方法。     

基本粒子简介

介绍了基本粒子的结构和模型，指出了人类对微观世界的认识是无穷无尽的，近代天文观测已证实了宇宙往大、往小都是不可穷尽的。     

上市公司资金使用效果实证分析

对1999年在上海证券交易所上市的和当年配股的共108家公司的经营效果进行了跟踪分析。以净资产收益率为指标，对这些公司进行了比较分析，并提出了相应建议。     

振动采油工艺在稠油区的实验研究与应用

在天然地震的影响下,油井产量发生波动,使人们受到启示,从而引进了振动采油工艺技术。本文对振动增产的机理进行了探讨,指出振动增油机理在于加快地层中流体的流速;改变储集层内油、气、水的重新分布;改变岩石表面润湿性,有利于清除油层堵塞,提高渗透率。通过分析两个试验区的振动采油效果,总结出在不同扰动力、不同激振频率、不同振动周期下的增产效果和规律,对振动采油的实施具有一定的指导意义。     

Cohesive stresses and size effect in quasi-brittle materials

A novel approach to the derivation of Bažant’s size effect law is presented. Contrarily to the original Lagrangian derivation which hinged on energetic consideration, a Newtonian approach based on local stress intensity factors is presented. Through this approach, it is shown that Bažant’s size effect law is the first (and dominant) term in a series expansion for the nominal stress. Furthermore, analytical expressions forB are derived for selected specimen geometries.