Electrochemical behavior of YAG laser-welded NiTi shape memory alloy

Electrochemical behaviors of laser-welded Ti-50.6%Ni（mole fraction） shape memory alloy and the base metal in 0.9% NaCl solution were investigated by electrochemical techniques as corrosion potential measurement, linear and potentiodynamic polarization. The results indicate that the laser-welded NiTi alloy is less susceptible to pitting and crevice corrosion than the base metal, which is demonstrated by the increase in polarization resistance（Rp） and pitting potential（φpit） and decrease in corrosion current density（Jcorr） and mean difference between φpit and φprot values. It is confirmed by scanning electron microscope micrographs that pits could be observed on the surface of base metal but not on the surface of laser-welded alloy after potentiodynamic tests. An improvement of corrosion resistance of laser-welded NiTi alloy could be attributed to almost complete dissolution of inclusions upon laser welding.     

Electrodeposition of dixanthogen（TETD） on pyrite surface

The electrochemical reaction of xanthate on the surface of pyrite was studied using cyclic voltammogrametry, chronopotentiometry and rotating-disc electrode measurements.Experimental results demonstrate that the first step in the reaction is electrochemical adsorption of xanthate ion,and then the adsorbed ion associates with a xanthate ion from the solution and forms a dixanthogen on the pyrite electrode surface.The diffusion coefficient of butyl xanthate on pyrite electrode surface can be determined to be about 1.09×10- 6cm2/s.Using the galvanostatic technique,the kinetic parameters of oxidation of the butyl xanthate ion on the pyrite surface are calculated as Ja=200μA/cm2 ,β=0.203 and J0=27.1μA/cm2.     

热处理对La0．7Mg0．3Ni2．8Co0．5贮氢合金电化学性能的影响

La0．7Mg0．3Ni2．8Co0．5贮氢电极合金经过适当热处理后(1123K)，最大放电容量、循环稳定性、高倍率放电性能(HRD)、交换电流密度(I0)以及极限电流密度(IL)都有明显改善，铸态合金电极的最大放电容量为392mAh／g，放电电流密度，Id=2000mA／g时，HRD2000=74．0％，I0=266．7mA／g，IL=3425．5mA／g；经1123K保温8h退火的合金电极的最大放电容量提高到414mAh／g，HRD2000=76．2％，I0=407．9mA／g，IL=3753．6mA／g。X射线衍射(XRD)分析表明，衍射峰宽度随着退火温度的升高而变窄，其原因是合金经退火处理相结构的变化和成分的均匀化。     

炼铁原、燃料检、实验系统的建立与应用

介绍了济钢炼铁原、燃料检、实验系统的构成，主要性能特点，使用过程中的经验教训。此系统使用后年节省检、实验费用95．64万元。     

On the electrochemical nature of hot-corrosion attack in Ni-Cr alloys

Hot-corrosion attack on gas-turbine components has been a problem of practical importance for over two decades. The nature and the extent of corrosion are influenced by the type of contaminants, the alloy constituents, and temperature. The hot-corrosion process is quite complex. There is controversy regarding the role of alloying elements, and whether the process is chemical or electrochemical in nature. In this investigation, an attempt has been made to investigate the role of Al and Ti in influencing the hot-corrosion attack of Ni-20 wt. % Cr alloys in molten Na₂SO₄-NaCl mixtures. It was found that Ni-Cr-Al alloys undergo a localized, heavy-blister attack under certain experimental conditions which is electrochemical in nature. An electrochemical model has been proposed which can satisfatorily explain the nature and kinetics of the localized blister corrosion.     

民机疲劳试验载荷谱简化研究与验证北大核心

在常规试验技术下,民用飞机全机疲劳试验周期过长,不仅费用高,更影响到适航取证和服役使用,开展载荷谱简化研究可有效加速疲劳试验。结合细节疲劳额定值(DFR)法和线性损伤累积理论,建立以损伤比门限值为折算依据的载荷谱等损伤折算方法。选用螺接和铆接的两种试验件进行试验验证,将原谱分别折算简化为五级谱和三级谱,折算后循环次数减少了约98%,且疲劳寿命结果符合工程要求,证明了该载荷谱折算方法的正确性和有效性。     

Effects of pH value of reaction solution on structure and electrochemical performance of calcium-containing active material of secondary zinc electrodes

The calcium-containing active material of secondary alkaline zinc electrodes was prepared by a chemical coprecipitation method and characterized by scanning electron microscopy(SEM) and X-ray diffractometry(XRD).Their electrochemical performance was tested by the Galvanstatic charge-discharge method. The experimental results show that the sample synthesized at pH: 11. 15 has a typical calcium zincate crystal. The zinc electrode using this sample as active material shows higher discharge capacity, more negative discharge plateau potential and longer cycle lifetime.     

薄壁铸造铸态贮氢合金的电化学性能及微观分析

讨论了壁厚(1～10mm)对无钕低铈低钴LPC(NiCoMnAlCuFeSi)5和商用成分Mm(NiCoMnAl)5铸态贮氢合金电化学性能的影响。研究发现：10mm厚的两种合金活化性能均优于1～6mm厚度合金；在0.2C充放电制度下，两种合金的放电容量对铸锭厚度均不敏感，LPC(NiCoMnAlCuFeSi)。合金的最大容量约为285mAh／g，Mm(NiCoMnAl)5合金的放电容量约为300mAh／g；在1C充放电制度下，LPC(NiCoMnAlCuFeSi)5合金的最大容量约为250mAh／g，对壁厚不敏感，Mm(NiCoMnAl)5合金的放电容量为250～280mAh／g，对壁厚敏感，并且前者显示出更好的循环稳定性。造成LPC(NiCoMnAlCuFeSi)。合金电化学性能对冷却速度不敏感的主要原因是元素Cu、Fe和Si的作用；晶胞参数和内应力等因素的交互作用也对该合金的性能有一定的影响。     

湿型球磨机槽型衬板工业性试验

通过改变衬板的结构形状来改善衬板的磨损状态，经工业性试验，不仅达到延长衬板使用寿命的目的，而且使磨机处理矿粒的综合性能指标得到有效改善。     

Q-52-51型摩托车车轮轮毂开裂原因分析

检测和分析了Q-52-51型摩托车车轮轮毂从材料成分，力学性能和金相组织。结果表明，轮毂在径向冲击检测时开裂的主要原因是镁含量偏高，以及热处理加热温度高造成组织过热所致。