TiN附着膜的应力-应变关系

利用等离子体辅助化学气相沉积法(PACVD)在60Mn钢基片上沉积2．5μm厚的TiN膜．借助X射线应力分析技术和微拉伸设备，测量该附着膜纵向(加载方向)应力和横向应力及外载应变，进而求其等效应力-等效单轴应变关系，并由此算得它的条件屈服点σ0．1和σ0．2分别为4．2和4．4GPa，加工硬化指数为0．36．用纳米压痕仪测得其硬度为25GPa，弹性模量为420GPa．TiN膜在拉伸过程中发生了塑性变形．     

34CrNi3Mo钢高温变形行为与Zener－Hollomon因子的关系

通过热模拟压缩试验，研究了３４ＣｒＮｉ３Ｍｏ合金结构钢在温度８４０～１２００℃，变形速度０．１～８０Ｓ~（－１）变形条件下的热压缩行为。获得了３４ＣｒＮｉ３Ｍｏ钢的变形激活能及峰值流动应力（σ_ｐ）、发生动态再结晶的临界条件（包括临界因子Ｚ_ｃ和临界应变ε_ｃ）和再结晶晶粒大小（ｄ）与Ｚｅｎｅｒ－Ｈｏｌｌｏｍｏｎ因子Ｚ的关系，并给出了回归公式。     

三自由度平面全柔顺并联机构运动学分析

针对传统方法求解全柔顺并联机构Jacobian矩阵存在奇异性的缺陷,基于三自由度平面全柔顺并联机构的伪刚体模型,提出一种微位移法来求解机构的Jacobian矩阵。先建立机构的伪刚体模型,并采用传统方法和微位移法得到机构的输入输出Jacobian矩阵;通过HyperMesh软件仿真和实验测试分别得到机构动平台中心点位移的仿真值和实验值。最后,将两种方法得到的理论值分别与仿真值、实验值进行对比。对比结果表明:与传统法相比,微位移法的计算精度较高,误差较小,且验证了Jacobian矩阵的有效性,为全柔顺并联机构的运动特性分析提供了参考。     

Electrochemical properties of CeMg_(11)Ni+x% Ni composites (x=0,50, 100 and 200) prepared by ball-milling

1　INTRODUCTIONMagnesium and magnesium based alloys arepromising hydrogen storage materials because oftheir absorbability of hydrogen in large quantities,low specific gravity, rich mineral resources, lowmaterial cost and so on. Nevertheless, their hy drides are too stable to be used at room tempera ture[1]. It seems impossible for application of crys talline Mg based alloys in nickel hydrogen batter ies.It is well known that amorphous alloys havemany advanta…     

Microstructures and Properties of Laser-Glazed Plasma-Sprayed ZrO2-YO1.5/Ni-22Cr-10AI-1Y Thermal Barrier Coatings

Thermal barrier coatings (TBCs) consisting of two layers with various yttria contents (ZrO ₂- YO_1.5/Ni-22Cr-10Al- lY) were plasma sprayed, and parts of the various specimens were glazed by using a pulsed CO₂ laser. All the specimens were then subjected to furnace thermal cycling tests at 1100 °C; the effect of laser glazing on the durability and failure mechanism of the TBCs was then evaluated. From these results, two models were developed to show the failure mechanism of as- sprayed and laser- glazed TBCs: model A, which is thermal-stress dominant, and model V, which is oxidation-stress dominant. For top coats containing cubic phase, cubic and monoclinic phases, or tetragonal and a relatively larger amount of monoclinic phases, whose degradation is thermal- stress dominant, laser glazing improved the durability of TBCs by a factor of about two to six. Segmented cracks that occurred during glazing proved beneficial for accommodating thermal stress and raising the tolerance to oxidation, which resulted in a higher durability. Thermal barrier coatings with top coats containing tetragonal phase had the highest durability. Degradation of such TBCs resulted mainly from oxidation of the bond coats. For top coats with a greater amount of monoclinic phase, thermal mismatch stress occurred during cooling and detrimentally affected durability.     

321不锈钢点蚀电位影响因素的研究

通过正交设计和对比实验研究了温度、pH值以及Cl-和SO2-4含量对321不锈钢点蚀电位的影响.正交设计表明,温度和Cl-(Cl-≥0.014mol/L)含量对点蚀电位Eb的影响显著,但pH值(6～9)则没有影响.对比实验表明,当Cl-≤0.014 mol/L时,Cl-对Eb没有影响,当Cl-＞0.014 mol/L,则Eb随Cl-浓度对数升高而线性下降.点蚀电位随温度升高而下降.如不含Cl-,则SO2-4对Eb没有影响,当Cl-=0.028 mol/L时,Eb随SO2-4浓度升高而升高,并趋于稳定值.     

SIMA法制备LC4半固态合金的流变行为研究

半固态坯的流动性能是获得优质、复杂制件的基础和关键。通过对两种状态合金在相同载荷作用下进行半固态压缩试验,结果表明:挤压态合金的流动性最差,挤压后冷变形态合金Ⅱ(压缩方向垂直于冷变形方向)的流动性最好。这主要有两方面的原因:一是晶粒形状上的差异;二是与半固态坯料的制备历史及其后续加工有关。     

Surface destructive mechanism on high-temperature ablation, supersonic-erosion, dreg-adherence and corrosion

The exhaust and flame from a supersonic airborne missile high-energy smoke-born engine (SAMHSE) may lead to high-temperature ablation, supersonic-erosion, dreg-adherence (HTASED) and corrosion on the launcher slide track, causing serious problems to the operation and decreasing the lifetime of the launcher. Therefore, it is imperative to study the destructive mechanism so as to guarantee the smooth operation and increase the lifetime of military equipments. Accordingly, HTASED and corrosion were systematically observed and analyzed with the emphasis placed on the mechanism investigations making use of a series evaluation tests, typical missile engine simulation tests, national military standard methods, scanning electron microscopy and electrochemical corrosion tests. It is found that the thermal impact of high-temperature flame and supersonic erosion of corrosive melting particle jet of the SAMHSE lead to surface defects of micro-cracks, denudation and corrosive residue. Some defects reach to metal base becoming to "corrosive channels". Repetitive HTASED may cause ablation-adhesion fatigue stress, which enhances the surface corrosion and destruction. HTASED and corrosion are related to the type of a SAMHSE fuel and experience of the launcher. Surface destruction is related to synergistic effects of the HTASED. The ablated and failed Al or steel surface is liable to electrochemical corrosion characterized by pitting in humid and salt-spray environment.     

嵌入式电子节温器综合检测系统设计北大核心

设计一款基于嵌入式系统的汽车电子节温器综合检测系统,采用空气作为泄漏测试介质,效率和安全性相比使用PLC和水介质的传统检测系统高。系统由上位机与下位机组成:下位机使用STM32F405RGT6处理器;上位机基于LabVIEW软件开发。系统能够完成包括汽车电子节温器内泄漏测试、外泄漏测试和流量测试,能够实时采集电机工作电压、电流、温度,完成电机位置与角度传感器标定,并生成数据报表和曲线,最终可以判定电子节温器样件合格与否。     

钴酸锂的再生及其电化学性能

采用提取的含少量Co3O4的LiCoO2为原料,在不同温度下合成正极材料LiCoO2,烧结时间为12 h,并采用XRD和SEM技术研究合成的LiCoO2的晶相结构与微观形貌。结果发现:烧结温度对LiCoO2的晶体结构影响较大,烧结温度越高,LiCoO2的层状结构发育越完整。循环伏安曲线很好地反映了再生LiCoO2的脱/嵌锂行为。将LiCoO2样品做成电池进行电化学检测,结果发现,烧结温度为850℃的样品首次放电容量为151mA.h/g,30次循环之后,放电容量仍有141mA.h/g,表现出良好的电化学性能。