亚微米HMX/FPM2602超细混合炸药的制备工艺研究

采用"超声波、助剂-溶液-水悬浮-蒸馏-成型"和超临界流体反溶剂(SAS)包覆技术研究了亚微米奥克托今(HMX)/氟橡胶(FPM2602)混合炸药造型粉的制造工艺,并用组分分析、扫描电镜(SEM)和傅立叶变换红外光谱(FT-IR)等方法进行了表征,对两种制备工艺得到的混合炸药的起爆性能进行了测试.结果表明,超声波、助剂-溶液-水悬浮-蒸馏-成型由于自身的一些缺点不适合制备超细混合炸药;而SAS包覆技术适合制备超细混合炸药,是一种绿色环保技术.     

Experimental study of diffusivity of hexane in bitumen-saturated porous media under high temperature/pressure conditions

Solvent mass transfer plays a key role in a thermal gravity drainage process involving solvent. The diffusion coefficients of solvent in such a process are not well studied. This article presents the effective diffusion coefficients of solvent in bitumen-saturated sands under high temperature/pressure conditions measured using a CT scanning technique. Experimental results show that the effective diffusion coefficient of n-hexane in bitumen-saturated sands varied with the solvent concentration or with the viscosity of solvent–bitumen mixture (i.e., D_e ∝ c^0.4 or D_e ∝ μ_m^−0.46). The solvent concentration weighted diffusion coefficient of n-hexane in the bitumen under the condition 160–170°C/1,900 kPa had an order of magnitude of about 10⁻⁵ cm²/s for solvent volume concentration less than 0.2. The penetration distance of n-hexane in bitumen-saturated sands depended on the nonlinearity of diffusion and had a value of −2 cm after 1-day diffusion. The stronger the nonlinearity of diffusion, the shorter the penetration distance.     

Mixed convection in the heated semi-circular lid-driven cavity for nonNewtonian power-law fluids: Effect of presence and shape of the block

The present work delineates the hydrodynamics and thermal characteristics due to mixed convection in the liddriven semi-circular cavity affected by the presence of the adiabatic block at its geometric center for twodimensional, steady-state, laminar and for non-Newtonian power-law fluids. The semi-circular cavity has a diameter of D. The horizontal wall/lid is sliding with a uniform horizontal velocity(u = U) and is subjugated to the ambient thermal condition; while the curved surface is subjugated to a higher isothermal temperature.The convective characteristics inside the system is explored for the broad range of Richardson number(0.1 ≤Ri ≤ 10), Prandtl number(1 ≤ Pr ≤ 100) and non-Newtonian power-law index(0.5 ≤ n ≤ 1.5) at a constant Grashof number of 10~4. Apart from this, the effect of shape(cross-section) of the inserted block, i.e., circular, square and triangular on heat transfer characteristics has also been explored. It is observed that the shear thickening fluids display better cooling characteristics. Besides, the cavity with immersed triangular block shows better heat transfer results than the circular and square blocks. The deviations observed in the flow and heat transfer characteristics in the cavity by inserting an adiabatic block as compared with cavity without block have been ascertained by calculating normalized Nusselt number(Nu~N). The presence of the block was found to have a diminishing effect on the heat transfer due to convection in the cavity. In the end, the results of the study are summarized in the form of a predictive correlation exhibiting the functional dependence of average Nusselt number with Prandtl number, power-law index, and Richardson number.     

A simplified couette flow solution of non-newtonian power-law fluids in eccentric annuli

Flow of non-Newtonian fluids in both the concentric and eccentric annuli is of great importance in extruders for molten plastics and wellbore fluid circulation for the removal of drilling cuttings. The steady laminar couette flow of non-Newtonian power-law fluids in eccentric annulus is employed in this study to analyze the problems of surge or swab pressures encountered when running or pulling tubular goods (pipes) in a liquid filled borehole. This is similar to the annular space created by two long co-axial cylinders with the inner cylinder in motion at a steady velocity, and a stationary outer cylinder. The solutions of the equations of motion are presented in both dimensionless form and as a family of curves for different pipe/borehole eccentricity ratios and power-law fluid index values for a more general application. The expected error in surge computation for concentric annulus as a result of eccentricity is evaluated.     

壳核型聚苯胺/钛酸钡复合电流变材料的制备及表征

采用溶液聚合的方法,在经过硅烷偶联剂表面修饰的钛酸钡微粉表面原位聚合聚苯胺,得到聚苯胺/钛酸钡壳核结构(BaTiO3/PAn)的有机-无机复合粒子.借助SEM、XRD、FT-IR、DSC-TG等分析手段研究了复合粒子的形貌、结构及热性能.利用改装后的旋转粘度计分别对钛酸钡和聚苯胺/钛酸钡复合颗粒的电流变性能进行研究.结果表明利用硅烷偶联剂成功地在钛酸钡粒子表面接枝合成聚苯胺,聚苯胺/钛酸钡复合颗粒电流变液的电流变性能明显比纯钛酸钡的电流变性能有所提高.     

叶片式MRF减振器的工作原理及磁路设计

介绍了一种基于传统叶片式液压减振器设计的叶片式MRF减振器的工作原理和磁路设计,利用Ansoft工程电磁场有限元分析软件对两种不同结构的叶片式MRF减振器的磁路进行了有限元分析.通过深入分析该型减振器的磁场分布,为其在车辆悬挂系统半主动控制中的应用奠定了基础.     

磁流变双筒式液压减振器设计及磁路仿真研究

介绍了某装甲车辆用被动式双筒式液压减振器的基本结构,基于这种结构提出了两种磁流变双筒式液压减振器的结构设计方案.为了确定最优的设计方案,利用Ansofi工程电磁场有限元分析软件对两种不同结构的MRF双筒式液压减振器的磁路进行了有限元分析.使用车载电源,在相同的工作电流下仿真得到两种结构该型MRF双筒式液压减振器的磁感应强度矢量和磁场强度分布,为其在车辆悬挂系统半主动控制中的应用奠定了基础.     

湖南瑶岗仙两类钨矿成矿流体对比研究

湖南瑶岗仙钨矿田由夕卡岩型白钨矿矿床和石英脉型黑钨矿矿床组成,分别位于瑶岗仙花岗岩体的东南侧和北西侧。文章从成矿流体的演化特点、流体成分以及流体来源方面,探讨了两类钨矿化的区别,并讨论成矿地质条件及流体成分对矿化的控制。研究认为,脉型黑钨矿形成于封闭系统,成矿流体呈临界状态,为一种介于岩浆与热液之间的过渡性流体,该流体的形成与岩浆的熔离及分异作用有关,成矿流体主要为来自岩浆的中高温、中低盐度,富含CO₂、CH₄以及H₂S的卤水。而白钨矿化形成于开放环境,流体演化过程中混合作用明显,其来源早期以岩浆水为主,后期有大量天水的加入。除了围岩性质不同,两类钨矿化对应的流体性质也是形成不同类型钨矿化的另一重要因素。     

Nonhomogeneous flow of micellar solutions: A kinetic—network theory approach

The rheological behavior of micellar solutions is analyzed under nonhomogeneous velocity and stress flow conditions. The framework is based on the extended irreversible thermodynamics and the transient network formulation coupled to the underlying kinetics embodying two relevant processes: formation of wormlike chains from a free micellar solution through a thermally activated process and their flow induced degradation. The second kinetic process consists in the formation of entanglements from the free wormlike chains and their flow‐induced breakage. These processes are modeled in a coupled kinetic scheme constituted by a set of reversible kinetic equations describing the evolution in average of the three microstates (free short rod‐like micelles, free wormlike chains, and entangled wormlike chains) that reflect the complexity of macromolecular interactions. The predictions of the shear stress and first normal stress difference as a function of shear‐rate under banded flow are in good agreement with experimental data. © 2018 American Institute of Chemical Engineers AIChE J, 64: 2277–2292, 2018     

黏弹性复杂流动的微观-宏观确定性模拟

Deterministic simulation approach was applied to simulating viscoelastic complex flows,in which,the SIMPLE algorithm based on collocated grid was used to solve the conservation equations on the macroscopic level and the spectral method was used to solve the Fokker-Planck equation on the mesoscopic level.Here,the transient 4∶1 planar contraction flow for dilute polymer solution was computed by using the coupled technique and the calculated polymeric stress distributions at steady state were identical with the results of continuum approach as well as the corresponding references.Therefore,the presented results indicated that the SIMPLE algorithm based on collocated grid coupled with the spectral method can be used to simulate viscoelastic complex flows effectively.Moreover,the influence of Deborah number and viscosity ratio on polymeric stress was also investigated.