Platinum particle size effect on the oxidative dehydrogenation of aqueous ethanol

The effect of the platinum particle size was investigated for the catalytic oxidative dehydrogenation of aqueous ethanol to ethanal at a temperature of 303 K, an ethanol concentration of 260 mol m^–3, a partial oxygen pressure 60 kPa, a pH of 9, and an ethanal and ethanoate concentration of 20 mol m^–3. A particle size effect on the turnover frequency was observed but only for particle sizes smaller than 2 nm. Hence, the reaction shows a limited structure sensitivity.     

FA composition and regiospecific analysis of Acer saccharum (sugar maple tree) and Acer saccharinum (silver maple tree) seed oils

GC analysis was performed to determine regiospecific distribution and FA composition in seed oils of the Aceraceae species, Acer saccharum and A. saccharinum. The oil content in the seeds was low at 5.0% in A. saccharum and 5.8% in A. saccharinum, and the main FA were linoleic (30.8 and 29.4%), oleic (21.3 and 27.6%), palmitic (10.1 and 10.5%), and cis-vaccenic (9.4 and 7.9%) acids, respectively. In addition, both oils contained long-chain monoenes of the n−9 and n−7 groups, including 11-eicosenoic, 13-docosenoic, 15-tetracosenoic, 13-eicosenoic, and 15-docosenoic acids, whereas γ-linolenic acid accounted for 0.8% of total FA in A. saccharum, and 0.5% in A. saccharinum. Regiospecific analysis, performed using the methodology of dibutyroyl derivatives of MAG, indicated that linoleic, oleic, and linolenic acids were mainly esterified at the internal position of TAG in both seed oils, whereas long-chain monoenes of the n−7 group were almost exclusively esterified on the external positions.     

Electroantennographic and coupled gas chromatographic-electroantennographic responses of the mediterranean fruit fly,Ceratitis capitata,to male-produced volatiles and mango odor

We have identified five compounds from the headspace of calling male Mediterranean fruit flies (medfly),Ceratitis capitata (Wiedemann), and three compounds from the headspace of ripe mango (Mangifera indica L). using coupled gas chromatographic-electroantennographic (GC-EAG) recordings, coupled gas chromatographic-mass spectrometric (GC-MS) analysis, and electroantennographic (EAG) assays of standards. The male-produced volatiles eliciting responses from female antennae were ethyl-(E)-3-octenoate, geranyl acetate, (E,E)--farnesene, linalool, and indole. An EAG dose-response test of linalool enantiomers and indole with female medfly antennae showed relatively strong EAG activities, but no significant difference between (R)-(-)-linalool and (S)-(+)-linalool. The three mango volatiles were identified as (1S)-(-)--pinene, ethyl octanoate, and-caryophyllene. In addition, a strong antennal response was recorded from a contaminant,-copaene, present in a commercial sample of-caryophyllene. The EAG response amplitudes from both male and female antennae to the above three mango volatiles were significantly greater than to a hexanol control. For both male and female medfly antennae, the greatest EAG responses were elicited by-caryophyllene followed by ethyl octanoate. The mean EAG responses of female antennae to-caryophyllene and (1S)-(-)--pinene were significantly greater than those of male antennae.     

螺旋齿轮塑件注塑模设计

分析了斜齿轮塑件的工艺特性,给出了实用的注塑模结构,介绍了斜齿轮注塑模各系统的结构设计,论述了模具的工作原理。该模具利用定模推出机构和推管旋转脱模机构解决了螺旋齿轮脱模难的问题。模具结构紧凑,推出可靠,安装维修操作方便,成型塑件质量好,生产效率高。     

水中痕量芳烃化合物的富集及测定

研究采用ＧＤＸ－３０１多孔微球为吸附剂，环己烷为脱附剂，富集水中痕量芳烃的条件。富集后的洗脱液直接注入２．０％ＤＮＰ－２．５％的有机皂士／１０１白色担体柱中，用ＦＩＤ检测器，恒温下进行气相色谱分离。采用单点校正法进行定量。大大提高了方法的灵敏度，已成功地应用于水中痕量芳烃化合物的测定。本法简便、快速，适用于微量、痕量杂质的富集测定。     

螺旋槽管外含高浓度不凝组分蒸汽冷凝传热研究

分析了含高浓度不凝组分蒸汽在立式螺旋槽管表面强制对流冷凝的传热机理。在不凝性组分体积百分浓度超过９０％时，螺旋槽管的强化传热效果不明显，而含量为４４％～９０％时，螺旋槽管总换热系数比光滑管提高２０％～３５％。     

卷帘型干式气柜在瓦斯回收系统中的应用

比较了几种不同形式气柜的优缺点,中国石化沧州分公司炼油厂选用了卷帘型干式气柜对瓦斯气进行回收和储存。该气柜主要借助于一种柔性的橡胶密封材料将气柜侧板和活塞密封连接。介绍了该气柜的设计参数、结构和运行原理,详述了瓦斯自动放散管的作用。讨论分析了气柜运行事故隐患,并提出相应的防范措施,最后针对气柜运行过程中存在的问题提出了整改措施。     

流化床电化学反应器研究进展

流化床电化学反应器是一种三维颗粒电极反应器,以其比表面积大、传质速率高而备受关注。就流化床电化学反应器在导电机理、数学模型、结构放大以及应用领域的研究现状和进展进行了综述,阐明了该类反应器开发、设计和模型化方面存在的问题,并提出了研究方向。     

含氮氧化物(NOx)废气的处理方法

介绍了氮氧化物废气的产生原理、处理方法,并结合某厂硝化废气处理装置改造过程的实例,对加压水吸收处理氮氧化物废气的方法做了详细介绍,同时将该法与其他处理方法进行了比较.